Review of the Incidence of the Sulphate Attack in Spain. Evaluation of Field Concrete Cases

Author(s):  
E. Menéndez ◽  
R. García-Rovés ◽  
B. Aldea ◽  
Y. Salem
Keyword(s):  
2020 ◽  
Vol 14 (1) ◽  
pp. 289-301
Author(s):  
Daniel Oni ◽  
John Mwero ◽  
Charles Kabubo

Background: Concrete is a common material used in the construction of marine structures, such as bridges, water treatment plants, jetties, etc. The use of concrete in these environment exposes it to attack from chemicals like sulphates, chlorides and alkaline, thereby causing it to deteriorate, and unable to perform satisfactorily within its service life. Hence, the need to investigate the durability properties of concrete has become necessary especially when admixtures are used to modify some of its properties. Objective: This research work investigates the effect of Cassava Starch (CS) on the durability characteristics of concrete. Methods: The durability properties investigated in this work are water absorption, sorptivity, resistance to sulphates, sodium hydroxides and chloride penetration. The specimens were prepared by adding CS by weight of cement at 0.4, 0.8, 1.2, 1.6 and 2.0% respectively. The concrete specimens were cured for 28 days, tested for compressive strength before ponding in ionic solutions of sodium hydroxide, sulphuric acid and sodium chloride. Six (6) concrete mixes were prepared, five of which were used to evaluate the effect of CS on the durability characteristics of concrete. Results: The slump values reduced with the increasing dosage of CS due to the viscous nature of the CS paste. Generally, the addition of CS in concrete tends to improve the resistance of concrete to sulphate and chloride attack due to the ability of the muddy-like starch gel to block the pore spaces of hardened concrete, hence, reduces the rate at which water and other aggressive chemicals penetrate the concrete. In addition, the retarding ability of CS impedes the formation of mono-sulphate aluminates during cement hydration, thereby making the concrete less susceptible to sulphate attack. Conclusion: The addition of CS to concrete by weight of cement generally improved the durability characteristics of concrete, while the relative performances of the concrete mixes showed that CS 2.0 gave a better resistance to chloride penetration and sulphate attack.


2021 ◽  
Vol 11 (15) ◽  
pp. 7029
Author(s):  
Carlos Thomas ◽  
José Sainz-Aja ◽  
Israel Sosa ◽  
Jesús Setién ◽  
Juan A. Polanco ◽  
...  

The high consumption of natural resources in the industrial sector makes it necessary to implement measures that enable the reuse of the waste generated, seeking to achieve circular economy. This work assesses the viability of an alternative to the use of CEM III B 32.5 R cement in mortars for the internal coating of centrifugally spun cast iron pipes for water piping. The proposal is to reuse the slag generated in the casting process after being finely ground, as an addition mixed with CEM I 52.5 R cement, which is basically Portland clinker. In order to analyse this possibility, an extensive experimental campaign was carried out, including the analysis of the cupola slag (micro-structural and chemical composition, leachates, setting time, vitrification, puzzolanicity and resistance to sulphate) and regarding the mortars (workability and mechanical properties). The experimental programme has shown that the optimum substitution is achieved with a replacement percentage of 20% of the cement, with which similar workability, superior mechanical properties and guaranteed resistance to sulphate attack are obtained. In addition, both economic and environmental savings are achieved by not having to transport or landfill the waste. In addition, the new cement is cheaper than the cement currently used.


2021 ◽  
Vol 898 ◽  
pp. 27-33
Author(s):  
Petr Figala ◽  
Rostislav Drochytka ◽  
Vit Černý ◽  
Radek Hermann ◽  
Jiří Kolísko

This paper deals with the study of chemical resistance of new cement-based grout for invert grouting. The aim of this work is to verify new mixtures with specific admixtures. The study monitors resistance to external sulphate attack. Specimens were placed into sulphate solution 29.8 g∙l-1 (44 g∙l-1 Na2SO4) according to DIN19753 standard. Based on the results gained, new mixtures will be designed and optimized by addition of suitable secondary raw materials (fly ash, waste foundry sand, waste glass, waste filers).


2007 ◽  
Vol 13 (1) ◽  
pp. 69-80 ◽  
Author(s):  
Enrico Fodde
Keyword(s):  

2005 ◽  
Vol 23 (1-2) ◽  
pp. 93-116 ◽  
Author(s):  
G. Rajasekaran ◽  
S. Narasimha Rao
Keyword(s):  

2021 ◽  
Author(s):  
Giri Raj Adhikari

Blended cements were studied for their efficacy against sulphate attack and alkali-silica reaction using six different types of fly ashes, a slag, a silica fume and four types of General Use Portland cement of different alkalinity. The study results showed that low calcium fly ash, silica fume and ground granulated blast furnace slag enhanced the sulphate resistance of cement with increased efficacy with the increase in the replacement level. However, slag and silica fume, especially at low replacement levels, exhibited increased rate of expansion beyond the age of 78 weeks. On the contrary, high calcium fly ashes showed reduced resistance to sulphate attack with no clear trend between the replacement level and expansion. Ternary blends consisting of silica fume, particulary in the amount of 5%, high calcium fly ashes and General Use (GU) cement provided high sulphate resistance, which was attributable to reduced permeability. In the same way, some of ternary blends consisting of slag, high calcium fly ash and GU cement improved sulphate resistance. Pre-blending optimum amount of gypsum with high calcium fly ash enhanced the latter's resistance to sulphate attack by producing more ettringite at the early stage of hydration. In the context of alkali-silica reaction permeability was found to be a contributing factor to the results of the accelerated mortar bar test. High-alkali, high-calcium fly ash was found to worsen the alkali silica reaction when used in concrete containing some reactive aggregates. Ternary blend of slag with high calcium fly ash was found to produce promising results in terms of counteracting alkali-silica reaction.


Author(s):  
M. Preethi ◽  
Md. Hamraj ◽  
Ashveen Kumar

The present study focuses on the preparation of M30 grade concrete by replacing fine aggregate with 0%,5%,10%,15%,20%,25% of vermiculite and cement with 0% and 10% of constant silica fume to improve the performance of concrete. Via experimentation, the impact of acid exposure on concrete strength and weight is investigated in the current report. Concrete cubes of different mixes(12no.’s) are casted and exposed to Sulphuric acid of (pH=3). Cubes with dimensions of 100mm x 100mm x 100mm are cast with M30 concrete and then immersed (cured) in water for 28 days. The cubes are then soaked in 4 percent concentrated Sulphuric acid for 7 days. The compressive strength of the cured cubes is then measured using a compressive measuring machine.


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