Predicting the Master Curve of Bituminous Mastics with Micromechanical Modelling

2021 ◽  
pp. 1473-1479
Author(s):  
Hassan Fadil ◽  
Denis Jelagin ◽  
Manfred N. Partl
Keyword(s):  
Master Curve ◽  
Micromechanical Modelling

Integration of Atomistic Simulation with Experiment Using Time−Temperature Superposition for a Cross-Linked Epoxy Network

2019 ◽  
Author(s):  
Ketan Khare ◽  
Frederick R. Phelan Jr.
Keyword(s):  
Master Curve ◽  
Glassy State ◽  
Superposition Principle ◽  
Quantitative Comparison ◽  
Time Shift ◽  
Data Sets ◽  
Epoxy Network ◽  
Temperature Superposition ◽  
Time Temperature Superposition ◽  
Time Temperature Superposition Principle

<a></a><a>Quantitative comparison of atomistic simulations with experiment for glass-forming materials is made difficult by the vast mismatch between computationally and experimentally accessible timescales. Recently, we presented results for an epoxy network showing that the computation of specific volume vs. temperature as a function of cooling rate in conjunction with the time–temperature superposition principle (TTSP) enables direct quantitative comparison of simulation with experiment. Here, we follow-up and present results for the translational dynamics of the same material over a temperature range from the rubbery to the glassy state. Using TTSP, we obtain results for translational dynamics out to 10<sup>9</sup> s in TTSP reduced time – a macroscopic timescale. Further, we show that the mean squared displacement (MSD) trends of the network atoms can be collapsed onto a master curve at a reference temperature. The computational master curve is compared with the experimental master curve of the creep compliance for the same network using literature data. We find that the temporal features of the two data sets can be quantitatively compared providing an integrated view relating molecular level dynamics to the macroscopic thermophysical measurement. The time-shift factors needed for the superposition also show excellent agreement with experiment further establishing the veracity of the approach</a>.

Modeling the Tensile Behaviour of a SiC/SiC Composite by Master Curves

2000 ◽  
Author(s):  
J. Shi
Keyword(s):  
Master Curve ◽  
Ceramic Matrix Composites ◽  
Test Material ◽  
Tensile Behaviour ◽  
Matrix Composites ◽  
Test Results ◽  
Master Curves ◽  
The Past ◽  
Test Parameters ◽  
Tensile Data

Scatter in test results is common for relatively brittle materials such as ceramic matrix composites. The scatter may come from differences in material processing conditions, specimen machining/handling and from variations in test parameters for nominally the same test material. Large scatter in test results makes material modeling difficult. In the past, master curve concepts have been proposed to reduce scatter in tensile data and to interpret fatigue/creep results. In this paper, one such concept is examined in detail by applying it to the recent tensile test results of a SiC/SiC composite. It was found that the way to construct master curves did not apply to the CMC studied and thus a new master curve was developed to better represent the tensile data. In addition, the test data were analysed statistically based on the new master curve.

scholarly journals Astral hydrogels mimic tissue mechanics by aster-aster interpenetration

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Qingqiao Xie ◽  
Yuandi Zhuang ◽  
Gaojun Ye ◽  
Tiankuo Wang ◽  
Yi Cao ◽  
...  
Keyword(s):  
Common Core ◽  
Self Assembly ◽  
Master Curve ◽  
Soft Tissues ◽  
Tissue Mechanics ◽  
Fresh Perspective ◽  
Single Master Curve ◽  
Unique Mechanism ◽  
Gel Network

AbstractMany soft tissues are compression-stiffening and extension-softening in response to axial strains, but common hydrogels are either inert (for ideal chains) or tissue-opposite (for semiflexible polymers). Herein, we report a class of astral hydrogels that are structurally distinct from tissues but mechanically tissue-like. Specifically, hierarchical self-assembly of amphiphilic gemini molecules produces radial asters with a common core and divergently growing, semiflexible ribbons; adjacent asters moderately interpenetrate each other via interlacement of their peripheral ribbons to form a gel network. Resembling tissues, the astral gels stiffen in compression and soften in extension with all the experimental data across different gel compositions collapsing onto a single master curve. We put forward a minimal model to reproduce the master curve quantitatively, underlying the determinant role of aster-aster interpenetration. Compression significantly expands the interpenetration region, during which the number of effective crosslinks is increased and the network strengthened, while extension does the opposite. Looking forward, we expect this unique mechanism of interpenetration to provide a fresh perspective for designing and constructing mechanically tissue-like materials.

The Brazilian Reliability Test and Micromechanical Modelling for Channelled Cylinders of Multiphased Porous Ceramics

2007 ◽  
Vol 280-283 ◽  
pp. 1731-1738 ◽  
Author(s):  
Frédéric Osterstock ◽  
Ioannis St. Doltsinis ◽  
Olivier Vansse
Keyword(s):  
Mechanical Model ◽  
Weibull Modulus ◽  
Porous Ceramics ◽  
Brazilian Test ◽  
Micromechanical Modelling ◽  
Multimodal Distributions ◽  
The Mean ◽  
Model Structures ◽  
Good Homogeneity ◽  
Equal Thickness

Channelled hollow ceramic cylinders have been sliced into discs of equal thickness and submitted to an adapted diametral compression, or brazilian, test such as to evaluate their reliability. The mean Weibull modulus, of m » 18, is representative of a rather good homogeneity of the ceramic material. The shapes of the distributions reveal a probable multimodality. This is analyzed in superimposing possible unimodal distributions of given characteristic value, Weibull modulus and number of items, and comparing to the experimental plot. Iterative modifications are made until a convincing superposition is attained. Complementary numerical simulations on “thermomechanically equivalent microstructures” have been created on the computer observing actual stereological data. The micro-mechanical model accounts for cracking of grain interfaces until specimen separation. Weibull plots for model structures under pore pressure suggest multimodal distributions with moduli ranging as in the measurements. The larger scatter at higher rupture pressures may indicate a varying degree of quasi-brittleness.

scholarly journals Non-Isothermal Kinetic Analysis of the Crystallization of Metallic Glasses Using the Master Curve Method

Materials ◽  
2011 ◽  
Vol 4 (12) ◽  
pp. 2231-2243 ◽  
Author(s):  
Joan Torrens-Serra ◽  
Shankar Venkataraman ◽  
Mihai Stoica ◽  
Uta Kuehn ◽  
Stefan Roth ◽  
...  
Keyword(s):  
Kinetic Analysis ◽  
Metallic Glasses ◽  
Master Curve ◽  
Master Curve Method ◽  
Curve Method ◽  
Isothermal Kinetic Analysis ◽  
Isothermal Kinetic

Universality of fractal aggregates as probed by light scattering

1989 ◽  
Vol 423 (1864) ◽  
pp. 71-87 ◽  
Keyword(s):  
Light Scattering ◽  
Dynamic Light Scattering ◽  
Master Curve ◽  
Rotational Diffusion ◽  
Fractal Dimensions ◽  
Scattering Data ◽  
Diffusion Limited ◽  
Single Master Curve ◽  
Using Data ◽  
Dynamic Light Scattering Data

Fractal colloid aggregates are studied with both static and dynamic light scattering. The dynamic light scattering data are scaled onto a single master curve, whose shape is sensitive to the structure of the aggregates and their mass distribution. By using the structure factor determined from computer-simulated aggregates, and including the effects of rotational diffusion, we predict the shape of the master curve for different cluster distributions. Excellent agreement is found between our predictions and the data for the two limiting régimes, diffusion-limited and reaction-limited colloid aggregation. Furthermore, using data from several completely different colloids, we find that the shapes of the master curves are identical for each régime. In addition, the cluster fractal dimensions and the aggregation kinetics are identical in each régime. This provides convincing experimental evidence of the universality of these two régimes of colloid aggregation.

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