Characterization and Use of Coir, Almond, Apricot, Argan, Shells, and Wood as Reinforcement in the Polymeric Matrix in Order to Valorize These Products

Author(s):  
Abouelkacem Qaiss ◽  
Rachid Bouhfid ◽  
Hamid Essabir
Keyword(s):  
2021 ◽  
pp. 096739112110233
Author(s):  
Mohammad Hassan Shojaeefard ◽  
Abolfazl Khalkhali ◽  
Sharif Khakshournia

It has been demonstrated that adding a few percent of nanoscale reinforcements, leads to remarkable improvement in mechanical properties of the polymers such as stiffness, damping, and energy absorption. These lightweight materials are attractive substitutes for the heavy metallic structural parts in the automotive, military, aerospace and many other industries. However, due to complexity of these multiphase materials, accurate modeling of their behavior in real loading cases is still ambiguous. The impact simulation is a vital step in design procedure of a vehicle, where a strain rate-dependent model of its components is required. In this paper, an elasto-viscoplastic modeling procedure of the polymer-based nanocomposites, assuming the elastic behavior of the nano-phase is presented; whereas the polymeric matrix deformation is dependent to the loading rate and is characterized by the method of Genetic algorithm optimization-based fitting to the experimental observations. By introducing a modified Halpin-Tsai method, the nanocomposite is then modeled as a homogenized material where the modification algorithm is the main challenge. A combination of approaches including parametric analysis, central composite design of experiments and response surface method is proposed to modify the tangent modulus of the polymeric matrix to be passed as the input to the Halpin-Tsai equations. Finally, the procedure is implemented to a set of epoxy-GNP nanocomposites under unidirectional compressive loads with different rates and the stress-strain curves are predicted with a decent precision.


Author(s):  
Riccardo Caponetto ◽  
Salvatore Graziani ◽  
Emanuele Murgano

AbstractIn the paper, a fractional-order RLC circuit is presented. The circuit is realized by using a fractional-order capacitor. This is realized by using carbon black dispersed in a polymeric matrix. Simulation results are compared with the experimental data, confirming the suitability of applying this new device in the circuital implementation of fractional-order systems.


2021 ◽  
Vol 263 ◽  
pp. 113720
Author(s):  
Mohammad Amin Shahmohammadi ◽  
Mojtaba Azhari ◽  
Mohammad Mehdi Saadatpour ◽  
Hamzeh Salehipour ◽  
Ömer Civalek

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1388
Author(s):  
Kathryn E. O’Harra ◽  
Emily M. DeVriese ◽  
Erika M. Turflinger ◽  
Danielle M. Noll ◽  
Jason E. Bara

This work introduces a series of vinyl-imidazolium-based polyelectrolyte composites, which were structurally modified via impregnation with multivalent imidazolium-benzene ionic liquids (ILs) or crosslinked with novel cationic crosslinkers which possess internal imidazolium cations and vinylimidazolium cations at the periphery. A set of eight [C4vim][Tf2N]-based membranes were prepared via UV-initiated free radical polymerization, including four composites containing di-, tri-, tetra-, and hexa-imidazolium benzene ILs and four crosslinked derivatives which utilized tri- and tetra- vinylimidazolium benzene crosslinking agents. Structural and functional characterizations were performed, and pure gas permeation data were collected to better understand the effects of “free” ILs dispersed in the polymeric matrix versus integrated ionic crosslinks on the transport behaviors of these thin films. These imidazolium PIL:IL composites exhibited moderately high CO2 permeabilities (~20–40 Barrer), a 4–7× increase relative to corresponding neat PIL, with excellent selectivities against N2 or CH4. The addition of imidazolium-benzene fillers with increased imidazolium content were shown to correspondingly enhance CO2 solubility (di- < tri- < tetra- < hexa-), with the [C4vim][Tf2N]: [Hexa(Im+)Benz ][Tf2N] composite showing the highest CO2 permeability (PCO2 = 38.4 Barrer), while maintaining modest selectivities (αCO2/CH4 = 20.2, αCO2/N2 = 23.6). Additionally, these metrics were similarly improved with the integration of more ionic content bonded to the polymeric matrix; increased PCO2 with increased wt% of the tri- and tetra-vinylimidazolium benzene crosslinking agent was observed. This study demonstrates the intriguing interactions and effects of ionic additives or crosslinkers within a PIL matrix, revealing the potential for the tuning of the properties and transport behaviors of ionic polymers using ionic liquid-inspired small molecules.


Sign in / Sign up

Export Citation Format

Share Document