Electrochemical studies on pitting corrosion on Cr13 steel exposed to CO2 and artificial brine with high chloride concentration

Author(s):  
Oleksandra Yevtushenko ◽  
Ralph Bäßler
2011 ◽  
Vol 356-360 ◽  
pp. 1642-1646
Author(s):  
Xue Qiang Zhu ◽  
Bao Ping Han ◽  
Guo Jun Wu ◽  
Xiao Qing Zhang

The effects of individual inorganic anions (nitrate and chloride) on the reactivity of granular iron were investigated using plexiglass columns packed with granular iron. The results show that TCE removal decreases apparently with increasing nitrate concentration due to competition for reactive sites. Chloride exhibits dual-effect on the TCE removal by Fe0. In the studied condition, the TCE dechlorination is enhanced at the low chloride concentration due to pitting corrosion and is dampened at the high chloride concentrations such as 59.98 and 110.45 mg/L as Cl-.


2012 ◽  
Vol 577 ◽  
pp. 109-114
Author(s):  
Shan Chen ◽  
Guo Ming Li ◽  
Xiao Yan Wang ◽  
Xue Qun Chen

This study focused on the effect of antimony on the corrosion resistance of low alloy steel using electrochemical techniques such as dynamic scanning and EIS and immersion test in an acid solution with high chloride concentration. The potentiodynamic test showed the anodic and cathodic corrosion behavior of all specimens and the corrosion rate decreased with increasing antimony addition. EIS showed that the antimony-containing steels had higher rust layer resistance. These test results showed the addition of antimony was convenient to the enhancement of corrosion resistance of the steel in the acid solution with high chloride concentration. The tests proved that the content of antimony controlled to 0.12% in the steel showed the best corrosion resistance.


1999 ◽  
Vol 40 (4-5) ◽  
pp. 443-450 ◽  
Author(s):  
A. Cassano ◽  
R. Molinari ◽  
E. Drioli

Some results on pressure-driven membrane operations able to improve chromium recovery from spent chromium tanning baths and to desalinate water discharged from filterpress after Cr(III) precipitation are reported. Nanofiltration was employed to concentrate chromium(III) using a spiral-wound module. Chromium concentration and COD in permeate were respectively about zero and 2–3 g/l as compared to initial feed values of 2.8 and 5.2 g/l; the high chloride concentration in the permeate suggested to reuse this solution in the pickling step saving fresh water and salts. The concentrate solution presented a higher chromium purification with respect to initial feed. It was tested in retanning, and after further concentration by chemical precipitation-dissolution method, in tanning operations. Chemical and physical analyses on leather treated with these solutions showed similar characteristics with respect to use of traditional chromium solution. Reverse osmosis was employed to reduce the high salt content in waste water from filter pressing of chromium hydroxide panels. Good rejection of reverse osmosis membrane to chloride and sulphate ions suggested the use of this operation for obtaining water, to be used in washings, or to sent to biological treatment of final waste water.


2012 ◽  
Vol 6 (2) ◽  
pp. 33-36
Author(s):  
Helda Handayani

Suli hot springs area has a low level of acidity or neutral pH ranges (7,2–7,7). It is also supported by a high chloride concentration value, which ranges (208,87-226,27) ppm. Thisshows that the area on station 1, 2, 3, and 4 are located in areas with water flow into the upper reservoir (upflow) and belongs to hot water domination reservoir tipe (water heatedreservoir). Reservoir temperature is calculated by the formula geotermometer (SiO2)p considered whether applied in the four kinds geotermometer equation because it gives the calculation results are not much different temperature and has a value of rms-error is less than 2%. Reservoir temperature at a hot springs station Suli possible temperature (161 ± 0,9)oC. Reservoir temperature at station 2 hot spring Suli possible hot water temperature (172 ± 1,0)oC. Reservoir temperature at station 3 hot springs Suli possible temperature (171 ±0,9)oC. Reservoir temperature at station 4 hot springs Suli possible temperature (169 ± 1,0)oC.


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