Stoichiometry Control in Organic Metals

1990 ◽  
pp. 349-352 ◽  
Author(s):  
K. Bechgaard ◽  
K. Lerstrup ◽  
M. Jørgensen ◽  
I. Johannsen ◽  
J. Christensen
Keyword(s):  
Organic Metals ◽  
Stoichiometry Control

Conducting charge-transfer and radical ion salts based on bitetrathiafulvalenes; an approach to organic metals using stoichiometry control

1999 ◽  
Vol 9 (2) ◽  
pp. 335-337 ◽  
Author(s):  
Masahiko Iyoda ◽  
Eiji Ogura ◽  
Kenji Hara ◽  
Yoshiyuki Kuwatani ◽  
Hiroyuki Nishikawa ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Organic Metals ◽  
Stoichiometry Control ◽  
Radical Ion Salts

TEM and cathodoluminescence of precipitates in II-VI semiconductors

1988 ◽  
Vol 46 ◽  
pp. 488-489
Author(s):  
Joanna L. Batstone
Keyword(s):  
Crystal Growth ◽  
Band Gap ◽  
Local Strain ◽  
Wide Band ◽  
Optoelectronic Device ◽  
Wide Band Gap ◽  
Bulk Crystal Growth ◽  
Transmission Electron ◽  
Device Applications ◽  
Stoichiometry Control

Interest in II-VI semiconductors centres around optoelectronic device applications. The wide band gap II-VI semiconductors such as ZnS, ZnSe and ZnTe have been used in lasers and electroluminescent displays yielding room temperature blue luminescence. The narrow gap II-VI semiconductors such as CdTe and HgxCd1-x Te are currently used for infrared detectors, where the band gap can be varied continuously by changing the alloy composition x.Two major sources of precipitation can be identified in II-VI materials; (i) dopant introduction leading to local variations in concentration and subsequent precipitation and (ii) Te precipitation in ZnTe, CdTe and HgCdTe due to native point defects which arise from problems associated with stoichiometry control during crystal growth. Precipitation is observed in both bulk crystal growth and epitaxial growth and is frequently associated with segregation and precipitation at dislocations and grain boundaries. Precipitation has been observed using transmission electron microscopy (TEM) which is sensitive to local strain fields around inclusions.

EFFECTS OF SOLVENTS AND CELL DESIGN FOR CRYSTAL GROWTH OF ORGANIC METALS

1983 ◽  
Vol 44 (C3) ◽  
pp. C3-1195-C3-1199
Author(s):  
H. Anzai ◽  
T. Moriya ◽  
K. Nozaki ◽  
T. Ukachi ◽  
G. Saito
Keyword(s):  
Crystal Growth ◽  
Cell Design ◽  
Organic Metals

Shubnikov–de Haas oscillations in organic metals

1992 ◽  
Vol 162 (10) ◽  
pp. 183 ◽  
Author(s):  
M.V. Kartsovnik ◽  
V.N. Laukhin ◽  
S.I. Pesotskii
Keyword(s):  
Organic Metals ◽  
Shubnikov De Haas Oscillations

scholarly journals Stoichiometry control and electronic and transport properties of pyrochlore Bi2Ir2O7 thin films

2018 ◽  
Vol 2 (11) ◽  
Author(s):  
W. C. Yang ◽  
Y. T. Xie ◽  
X. Sun ◽  
X. H. Zhang ◽  
K. Park ◽  
...  
Keyword(s):  
Thin Films ◽  
Transport Properties ◽  
Stoichiometry Control

Chemical Vapor Deposition of Sr1−xBaxNb2O6 Thin Films Using Metal Alkoxide Precursors

2000 ◽  
Vol 15 (8) ◽  
pp. 1702-1708
Author(s):  
Ruichao Zhang ◽  
Ren Xu
Keyword(s):  
Thin Films ◽  
Chemical Vapor Deposition ◽  
Vapor Deposition ◽  
Single Phase ◽  
Chemical Vapor ◽  
Deposition Process ◽  
Thin Layers ◽  
Metal Alkoxide ◽  
Stoichiometry Control ◽  
Alkoxide Precursors

A novel two-step metalorganic chemical vapor deposition process was used in this study to prepare Sr1−xBaxNb2O6 (SBN) thin films. Two thin layers of single-phase SrNb2O6 and BaNb2O6 were deposited alternately on a silicon substrate, and the solid solution of SBN was obtained by high-temperature annealing. The stoichiometry control of the SrNb2O6 and the BaNb2O6 thin films was achieved through deposition process control, according to the evaporation characteristics of double metal alkoxide. The evaporation behavior of double metal alkoxide precursors SrNb2(1-OC4H9)12 and BaNb2(1-OC4H9)12 was studied, and the results were compared with the evaporation of single alkoxide Nb(1-OC4H9)5.

scholarly journals X-Ray Investigations of the Low-Temperature Phases of the Organic Metals α- and β-(BEDT-TTF)2I3

1986 ◽  
Vol 41 (11) ◽  
pp. 1319-1324 ◽  
Author(s):  
H. Endres ◽  
H. J. Keller ◽  
R. Swietlik ◽  
D. Schweitzer ◽  
K. Angermund ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Differential Thermal Analysis ◽  
Room Temperature ◽  
Unit Cell Volume ◽  
Unit Cell ◽  
Slight Variation ◽  
X Ray ◽  
Organic Metals ◽  
Β Phase ◽  
Α Phase

The structure of single crystals of the organic metals α- and β-(BEDT-TTF)2I3* was determined at 100 K, well below the phase transitions indicated by resistivity and thermopower measurements as well as by differential thermal analysis. In the α-phase no unusual change of the room temperature unit cell but a slight variation in the triiodide network and especially a more pronounced dimerization in one of the two donor stacks have been found. The β-phase develops a superstructure with a unit cell volume three times as large as that at room temperature and with pronounced distortions of the I3--ions.

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