High performance sustainable materials for automotive applications: dream or reality?

Author(s):  
Philippe Godano ◽  
James Taylor ◽  
Pascaline Bregeon ◽  
Davide Caprioli ◽  
Luca Mazzarella ◽  
...  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Vânia G. Zuin ◽  
Luize Z. Ramin ◽  
Mateus L. Segatto ◽  
Aylon M. Stahl ◽  
Karine Zanotti ◽  
...  

AbstractIncreasing demands to obtain chemicals via greener and more sustainable materials and processes introduces concepts that should be considered and applied from lab to larger scales. Obtaining bioactive chemicals from agro-industrial non-food biomass waste can combine benign techniques and bio-circular economy to reach this goal. After extraction, evaluating profitability and environmental impacts to decide whether separation – and to what extent – is necessary or not is indispensable. This could be integrated into an approach known as sufficiency, as an important criterion for sustainability. From this perspective, Brazil’s annual generation of 8 million tons of orange waste is relevant, since citrus waste has large amounts of high-value compounds, such as pectin, d-limonene and flavonoids. This case study aimed at developing and comparing green and sustainable analytical methods to obtain flavonoids from orange peel. Homogenizer, ultrasound and microwave-assisted extractions were employed using chemometric tools, considering time, sample/solvent ratio, temperature and ethanol concentration as variables to obtain extracts containing hesperidin, naringenin, hesperetin and nobiletin. The bioactive flavonoids were determined by high-performance liquid chromatography (HPLC-UV). Microwave extraction was the most efficient method for obtaining the majority of flavonoids studied, six times more for hesperidin. Moreover, orange waste from different farming models showed diverse chemical profiles showing the importance of this alternative in natural product resources.


Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2648 ◽  
Author(s):  
Kuruma Malkappa ◽  
Jayita Bandyopadhyay ◽  
Suprakas Ray

Polylactide (PLA) is one of the most widely used organic bio-degradable polymers. However, it has poor flame retardancy characteristics. To address this disadvantage, we performed melt-blending of PLA with intumescent flame retardants (IFRs; melamine phosphate and pentaerythritol) in the presence of organically modified montmorillonite (OMMT), which resulted in nanobiocomposites with excellent intumescent char formation and improved flame retardant characteristics. Triphenyl benzyl phosphonium (OMMT-1)- and tributyl hexadecyl phosphonium (OMMT-2)-modified MMTs were used in this study. Thermogravimetric analysis in combination with Fourier transform infrared spectroscopy showed that these nanocomposites release a smaller amount of toxic gases during thermal degradation than unmodified PLA. Melt-rheological behaviors supported the conclusions drawn from the cone calorimeter data and char structure of the various nanobiocomposites. Moreover, the characteristic of the surfactant used for the modification of MMT played a crucial role in controlling the fire properties of the composites. For example, the nanocomposite containing 5 wt.% OMMT-1 showed significantly improved fire properties with a 47% and 68% decrease in peak heat and total heat release rates, respectively, as compared with those of unmodified PLA. In summary, melt-blending of PLA, IFR, and OMMT has potential in the development of high-performance PLA-based sustainable materials.


2001 ◽  
Author(s):  
F. J. Semel ◽  
Michael C. Baran ◽  
K. S. Narasimhan

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 1
Author(s):  
Zhiqiang Zhu ◽  
Erbing Zhang ◽  
Qinzhi Zeng ◽  
Jiuping Rao ◽  
Nairong Chen

With rising interior air pollution, health, and food shortage concerns, wood adhesives derived from non-food sustainable materials have therefore attracted considerable attention. Here we developed an eco-friendly cottonseed-lignin adhesive consisting of non-food defatted cottonseed flour (DCF), alkali lignin (AL), and graphene oxide (GO). The cation-π interaction, and hydrogen and covalent bonds between AL@GO and DCF collectively enhanced the cross-linking structure of the cured cottonseed-lignin adhesive, based on the Fourier-transform infrared spectroscopy, thermogravimetric analyses, scanning electron microscopy, and sol-gel tests. The high performance of the developed cottonseed-lignin adhesive was evidenced by its increased wet/dry shear strength and decreased rheological properties before curing and improved thermal stability and decreased soluble substances after curing. Particularly, the highest wet shear strength of poplar plywood bonded with cottonseed-lignin adhesive was 1.08 MPa, which increased by 74.2 and 54.3% as compared to the control and requirement of the Chinese standard GB/T 9846-2015 for interior plywood (≥0.7 MPa), respectively. The technology and resultant adhesives showed great potential in the preparation of green woody composites for many applications.


2021 ◽  
pp. 109963622110305
Author(s):  
Youming Chen ◽  
Raj Das

In this work, polymeric foam thermoforming, foam injection moulding, bead foaming and film foaming were reviewed in an effort to explore feasible processes to manufacture sandwich structures of complex geometry for automotive applications. Injection moulded foams generally suffer from high density, poor cell morphologies and unnecessary skin layers. Foamable films currently available are pressure-induced. In order for foamable films to produce foam, high uniformly-distributed pressure needs to be applied, which makes it difficult to manufacture foam parts of three-dimensional complex geometry with foamable films. The majority of commercial high-performance foam cores can be thermoformed. Ideally, thermoformed foam cores would have good mechanical properties if high-performance foam sheets are used. However, the mechanical properties of foams might be reduced during the process of thermoforming, especially around corners. Bead foaming offers a high level of freedom in foam geometry to be moulded, and inserts can be integrated into foam cores during the process of moulding. Moreover, foam cores with high density in high stressed areas and low density in low stressed areas can be manufactured with foam beads of different densities. However, due to nonhomogeneous degree of fusion and weak bonds and voids between beads, bead foams generally show mechanical properties lower than their block counterpart. Relatively speaking, thermoforming with high-performance foam sheets and moulding with high-performance foam beads hold great potentials for mass production of sandwich cores of complex geometry for automotive applications. However, further investigation on the mechanical properties of thermoformed foams and high-performance bead foams is still in need to confirm their suitability.


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