Bulk Geochemical Characterization and Classification of Organic Matter: Elemental Analysis and Pyrolysis

1995 ◽  
pp. 367-382
Author(s):  
Richard V. Tyson
2017 ◽  
Vol 5 (2) ◽  
pp. SF109-SF126 ◽  
Author(s):  
Yuxi Yu ◽  
Xiaorong Luo ◽  
Ming Cheng ◽  
Yuhong Lei ◽  
Xiangzeng Wang ◽  
...  

Shale oil and gas have been discovered in the lacustrine Zhangjiatan Shale in the southern Ordos Basin, China. To study the distribution of extractable organic matter (EOM) in the Zhangjiatan Shale ([Formula: see text] ranges from 1.25% to 1.28%), geochemical characterization of core samples of different lithologies, scanning electron microscope observations, low-pressure [Formula: see text] and [Formula: see text] adsorption, and helium pycnometry were conducted. The content and saturation of the EOM in the pores were quantitatively characterized. The results show that the distribution of the EOM in the shale interval is heterogeneous. In general, the shale layers have a higher EOM content and saturation than siltstone layers. The total organic content and the original storage capacity control the EOM content in the shale layers. For the siltstone layers, the EOM content is mainly determined by the original storage capacity. On average, 75% of the EOM occurs in the mesopores, followed by 14% in the macropores, and 11% in the micropores. The EOM saturation in the pores decreases with the increase in pore diameter. The distribution of EOM in the shale pores is closely related to the pore type. Micropores and mesopores developed in the kerogens and pyrobitumens and the clay-mineral pores coated with organic matter are most favorable for EOM retention and charging.


1980 ◽  
Vol 20 (1) ◽  
pp. 44 ◽  
Author(s):  
A.C. Hutton ◽  
A.J. Kantsler ◽  
A.C. Cook ◽  
D.M. McKirdy

The Tertiary oil-shale deposits at Rundle in Queensland and of the Green River Formation in the western USA, together with Mesozoic deposits such as those at Julia Creek in Queensland, offer prospects of competitive recovery cost through the use of large-scale mining methods or the use of in situ processing.A framework for the classification of oil shales is proposed, based on the origin and properties of the organic matter. The organic matter in most Palaeozoic oil shales is dominantly large, discretely occurring algal bodies, referred to as alginite A. However, Tertiary oil shales of northeastern Australia are chiefly composed of numerous very thin laminae of organic matter cryptically-interbedded with mineral matter. Because the present maceral nomenclature does not adequately encompass the morphological and optical properties of most organic matter in oil shales, it is proposed to use the term alginite B for finely lamellar alginite, and the term lamosites (laminated oil shales) for oil shales which contain alginite B as their dominant organic constituent. In the Julia Creek oil shale the organic matter is very fine-grained and contains some alginite B but has a higher content of alginite A and accordingly is assigned to a suite of oil shales of mixed origin.Petrological and chemical techniques are both useful in identifying the nature and diversity of organic matter in oil shales and in assessing the environments in which they were formed. Such an understanding is necessary to develop exploration concepts for oil shales.


1972 ◽  
Vol 12 (1) ◽  
pp. 125
Author(s):  
T.G. Powell ◽  
D.M. McKirdy

Australian oils are generally light by world standards. They have API gravities greater than 35°, low sulphur and asphalt contents, and are of paraffinic or naphthenic base. The geochemical similarity of oils from the Bowen-Surat Basin, with the notable exception of the Conloi crude, is most marked in the fraction boiling above 250 °C. Oils from the Cooper, Gippsland and Otway Basins are probably derived from terrestrial organic material, but differ in their degree of maturation as indicated by n-alkane patterns. Samples from the Perth Basin exhibit a similar variation in maturity. In the Carnarvon Basin, the Windalia crude differs from those in deeper reservoirs in containing a higher proportion of oxygen-bearing, nitrogen-bearing, and sulphur-bearing compounds, another sign of a less mature oil. The East Mereenie oil displays an odd-even predominance in its n-alkane distribution which is characteristic of some Lower Palaeozoic crudes. A Papuan Basin condensate is the only available sample produced from a limestone reservoir. This probably accounts for its higher sulphur content. Two seeps obtained from the Papuan Highlands are inspissated residues which may have suffered microbiological alteration.A major control of the composition of Australian crude oils appears to be the depositional environment of the source rock. Most of the oils show evidence of having been generated, at least in part, from terrestrial (as opposed to marine) organic matter. The location of all but one of the reservoirs within sequences dominated by the sandstone - shale association is consistent with the likely contribution of land plant detritus to their source environment. Likewise, low sulphur and asphalt values reflect the scarcity of favourable carbonate-evaporite source and reservoir situations in Australia.


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