Laser fluorescence determination of lead in geological samples when vaporized by pulsed laser light

1992 ◽  
Vol 56 (3) ◽  
pp. 235-238 ◽  
Author(s):  
O. N. Ezhov ◽  
B. R. Kano ◽  
S. V. Oshemkov ◽  
A. A. Petrov
Keyword(s):  
Laser Light ◽  
Pulsed Laser ◽  
Laser Fluorescence ◽  
Geological Samples ◽  
Fluorescence Determination

X-ray fluorescence determination of zinc sulfate in acidic zinc plating electrolyte

2020 ◽  
Vol 86 (10) ◽  
pp. 18-22
Author(s):  
K. N. Vdovin ◽  
K. G. Pivovarova ◽  
N. A. Feoktistov ◽  
T. B. Ponamareva
Keyword(s):  
Zinc Sulfate ◽  
Zinc Coating ◽  
Electrolyte Composition ◽  
Complexometric Titration ◽  
X Ray ◽  
Fluorescence Determination ◽  
Zinc Plating ◽  
Zinc Determination

Zinc sulfate is the main component in the composition of the acidic zinc plating electrolyte. Deviation in the electrolyte composition from the optimum content leads to destabilization of the electrolysis process and deteriorate the quality of the resulting zinc coating. The proper quality of a zinc coating obtained by galvanic deposition can be ensured only with timely monitoring and adjustment of the electrolyte composition. A technique of X-ray fluorescence determination of zinc (in terms of zinc sulfate) in an acidic zinc plating electrolyte is proposed. The study was carried out using an ARL Quant’X energy dispersive spectrometer (Thermo Fisher Scientific, USA) with a semiconductor silicon-lithium detector. The features of the spectrometer design are presented. The optimal parameters of excitation and detection of zinc radiation were specified when the electrolyte sample was diluted 1:1000. The ZnKα1 line was used as an analytical line. The plotted calibration graph is linear, the correlation coefficient being 0.999234. The results of zinc determination according to the developed method were compared with the data of the reference method of complexometric titration to prove the reliability of the procedure. The results are characterized by good convergence and accuracy. The proposed method of X-ray fluorescence zinc determination in a zinc plating electrolyte equals complexometric titration in the limiting capabilities and even exceeds the latter in terms of the simplicity of sample preparation and rapidity. The developed method of X-ray fluorescence determination of zinc is implemented in analysis of the electrolyte used in the continuous galvanizing unit at «METSERVIS LLC».

Holographic moving picture recording and observation of ultrashort pulsed laser light propagation

2008 ◽  
Vol 36 (Supplement) ◽  
pp. 201-202
Author(s):  
Yasuhiro Awatsuji ◽  
Kenzo Nishio ◽  
Shogo Ura ◽  
Toshihiro Kubota
Keyword(s):  
Light Propagation ◽  
Laser Light ◽  
Pulsed Laser ◽  
Ultrashort Pulsed Laser

X-Ray Fluorescence Determination of Ore Elements in Ferromanganese Formations

2020 ◽  
Vol 56 (14) ◽  
pp. 1423-1430
Author(s):  
V. M. Chubarov ◽  
A. A. Amosova ◽  
A. L. Finkelshtein
Keyword(s):  
X Ray ◽  
Fluorescence Determination

Highly selective and sensitive fluorescence determination of m-Phenylenediamine

2021 ◽  
Vol 167 ◽  
pp. 106283
Author(s):  
Shengli Zhang ◽  
Bofang Liu ◽  
Wei Li ◽  
Tong Lin ◽  
Hongwei Yang ◽  
...  
Keyword(s):  
Fluorescence Determination

scholarly journals Second derivative synchronous fluorescence determination of avanafil in the presence of its acid-induced degradation product aided by powerful Lean Six Sigma tools augmented with D-optimal design

RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 3834-3842
Author(s):  
Khalid A. M. Attia ◽  
Ahmad A. Mohamad ◽  
Mohamed S. Emara ◽  
Ahmed M. Abdel-Raoof ◽  
Mohamed A. Hasan ◽  
...  
Keyword(s):  
Optimal Design ◽  
Quantitative Determination ◽  
Degradation Product ◽  
Six Sigma ◽  
Lean Six Sigma ◽  
Synchronous Fluorescence ◽  
Second Derivative ◽  
Fluorescence Determination ◽  
Spectrofluorimetric Method

In this work, the quantitative determination of an erectile dysfunctional drug avanafil in the presence of its acid-induced degradation product was achieved via the application of a pre-optimized novel spectrofluorimetric method.

Electrolyzing synthesis of boron-doped graphene quantum dots for fluorescence determination of Fe3+ ions in water samples

Talanta ◽  
2017 ◽  
Vol 164 ◽  
pp. 100-109 ◽  
Author(s):  
Li Chen ◽  
Chuanli Wu ◽  
Pan Du ◽  
Xiaowei Feng ◽  
Ping Wu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Water Samples ◽  
Graphene Quantum Dots ◽  
Boron Doped ◽  
Fluorescence Determination ◽  
Doped Graphene

Low-Fluence Laser Induced Fragmentation and Desorption of 3,4,9,10-Perylenetetracarboxylic Dianhydride (PTCDA) Thin Film

2013 ◽  
Vol 543 ◽  
pp. 30-34 ◽  
Author(s):  
Aljona Ramonova ◽  
Tengiz Butkhuzi ◽  
Viktorija Abaeva ◽  
I.V. Tvauri ◽  
Soslan Khubezhov ◽  
...  
Keyword(s):  
Thin Film ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Kinetic Energy ◽  
Atomic Oxygen ◽  
Laser Light ◽  
Pulsed Laser ◽  
Molecular Fragmentation ◽  
Irradiation Pulse ◽  
Main Effect

Laser-induced fragmentation and desorption of fragments of PTCDA films vacuum-deposited on GaAs (100) substrate has been studied by time-of-flight (TOF) mass spectroscopy. The main effect caused by pulsed laser light irradiation (pulse duration: 10 ns, photon energy: 2.34 eV and laser fluence ranging from 0.5 to 7 mJ/cm2) is PTCDA molecular fragmentation and desorption of the fragments formed, whereas no desorption of intact PTCDA molecule was detected. Fragments formed are perylene core C20H8, its half C10H4, carbon dioxide, carbon monoxide and atomic oxygen. All desorbing fragments have essentially different kinetic energy. The mechanism of photoinduced molecular fragmentation and desorption is discussed.

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