The effect of the nature of a modifying additive (Pt, Zn, Ga) on the activity of oxide and zeolite catalysts in ethane dehydrogenation and aromatization

1994 ◽  
Vol 43 (4) ◽  
pp. 555-558
Author(s):  
T. V. Vasina ◽  
O. V. Masloboyshchikova ◽  
O. V. Chetina ◽  
E. G. Khelkovskaya-Sergeeva

Author(s):  
G. McMahon ◽  
T. Malis

As with all techniques which are relatively new and therefore underutilized, diamond knife sectioning in the physical sciences continues to see both developments of the technique and novel applications.Technique Developments Development of specific orientation/embedding procedures for small pieces of awkward shape is exemplified by the work of Bradley et al on large, rather fragile particles of nuclear waste glass. At the same time, the frequent problem of pullout with large particles can be reduced by roughening of the particle surface, and a proven methodology using a commercial coupling agent developed for glasses has been utilized with good results on large zeolite catalysts. The same principle (using acid etches) should work for ceramic fibres or metal wires which may only partially pull out but result in unacceptably thick sections. Researchers from the life sciences continue to develop aspects of embedding media which may be applicable to certain cases in the physical sciences.



2017 ◽  
pp. 91-95
Author(s):  
E. I. Grushova ◽  
A. .. Al Razuqi ◽  
E. S. Chaiko ◽  
O. A. Miloserdova

IR spectroscopy investigated structural and group composition of base mineral oils isolated from the vacuum distillate by selective purification of N-methylpyrrolidone and the low temperature dewaxing in the presence of a solvent. The role of the latter was carried out by the systems acetone - toluene, acetone - methyl tertiary butyl ether, methyl ethyl ketone - toluene, acetone - toluene - modifying additive. It was shown that the chemical composition of the group of base oils and slack waxes is defined as the nature of the solvent to the dewaxing, and oils sequence of purification steps.



2019 ◽  
Vol 24 (94/4) ◽  
pp. 27-32
Author(s):  
T.S. Skoblo ◽  
I.N. Rybalko ◽  
A.V. Tihonov ◽  
T.V. Maltsev

The possibility of using a non-magnetic fraction of a detonation charge with a diamond fraction from the disposal of ammunition to modify the restoration coatings of a natural product – clay and secondary raw materials — was studied. Four different coating variants were investigated. For this, a T-620 electrode was used with its additional modification by coating with bentonite clay, as well as with a non-magnetic fraction of the detonation charge and applying it in the form of a slip coating on the cutting surface of the cultivator. It is shown that the use of such additives allows to increase the resistance of the working tool of agricultural machines, reduces its tendency to damage due to the minimum penetration of the thin-walled product of the hoe blade and a decrease in the cross section of the transition layer and the level of stress. Each modifier makes changes to increase the microhardness to varying degrees. An increase in microhardness is observed on the surface of the coating and its gradual decrease to the transition layer. The surface coating with the additional introduction of bentonite clay in a liquid bath has the highest microhardness. Its microhardness varies from HV-50-1009.7 to HV-50-615.2. Similarly, the effect of the modifying additive of the detonation charge, the microhardness varies from HV-50-969.6 to HV-50-633.26. When clay or a mixture is introduced into the restoration coating, the wear resistance increases by 1.3 - 2 times with respect to the deposited surfacing only by the electrode and by 2 - 3 times to the initial material of the cultivator. It was found that the lowest coefficient is characteristic for dry friction, as well as for hydroabrasive, for samples with additional modification with clay or a detonation charge



2017 ◽  
Vol 68 (1) ◽  
pp. 116-120
Author(s):  
Iuliean Vasile Asaftei ◽  
Neculai Catalin Lungu ◽  
Lucian Mihail Birsa ◽  
Ioan Gabriel Sandu ◽  
Laura Gabriela Sarbu ◽  
...  

The conversion of n-heptanes into aromatic hydrocarbons benzene, toluene and xylenes (BTX), by the chromatographic pulse method in the temperature range of 673 - 823K was performed over the HZSM-5 and Ag-HZSM-5 zeolites modified by ion exchange with AgNO3 aqueous solutions. The catalysts, HZSM-5 (SiO2/Al2O3 = 33.9), and Ag-HZSM-5 (Ag1-HZSM-5 wt. % Ag1.02, Ag2-HZSM-5 wt. % Ag 1.62; and Ag3-HZSM-5 wt. % Ag 2.05 having different acid strength distribution exhibit a conversion and a yield of aromatics depending on temperature and metal content. The yield of aromatic hydrocarbons BTX appreciably increased by incorporating silver cations Ag+ into HZSM-5.



Catalysts ◽  
2015 ◽  
Vol 5 (4) ◽  
pp. 2122-2133 ◽  
Author(s):  
Masakazu Iwamoto ◽  
Ryota Takezawa ◽  
Masao Morimoto


2014 ◽  
Vol 9 ◽  
pp. 139-150 ◽  
Author(s):  
Bambang Heru Susanto ◽  
Mohammad Nasikin ◽  
Sukirno ◽  
Andri Wiyo


2021 ◽  
Vol 19 (1) ◽  
pp. 745-754
Author(s):  
Khoirina Dwi Nugrahaningtyas ◽  
Eddy Heraldy ◽  
Rachmadani ◽  
Yuniawan Hidayat ◽  
Indriana Kartini

Abstract The properties of three types of CoMo/USY catalysts with different synthesized methods have been studied. The sequential and co-impregnation methods followed by activation using calcination and reduction process have been conducted. The properties of the catalysts were examined using Fourier-transform-infrared (FTIR) spectroscopy, X-ray diffraction (XRD) with refinement, and surface area analyzer (SAA). The FTIR spectrum study revealed the enhanced intensity of its Bronsted acid site, and the XRD diffractogram pattern verified the composition of pure metals, oxides, and alloys in the catalyst. The SAA demonstrated the mesoporous features of the catalyst. Scanning electron microscopy showed an irregular particle morphology. Additional analysis using the transmission electron microscopy indicated that the metal has successfully impregnated without damaging the USY structure.



Author(s):  
Guohua Jing ◽  
Johannes W. Schwank ◽  
Alexander J Hill ◽  
Huawang Zhao ◽  
Lei Ma ◽  
...  

Future emission standards are becoming increasingly stringent. Around 50% of targeted tailpipe emissions are emitted during the cold-start period, mainly due to the ineffectiveness of catalytic converters in the after-treatment...



2021 ◽  
Vol 47 (1) ◽  
pp. 397-418
Author(s):  
Karolina A. Chalupka ◽  
Renata Sadek ◽  
Lukasz Szkudlarek ◽  
Pawel Mierczynski ◽  
Waldemar Maniukiewicz ◽  
...  


2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Xiaoliang Liu ◽  
Jing Shi ◽  
Guang Yang ◽  
Jian Zhou ◽  
Chuanming Wang ◽  
...  

AbstractZeolite morphology is crucial in determining their catalytic activity, selectivity and stability, but quantitative descriptors of such a morphology effect are challenging to define. Here we introduce a descriptor that accounts for the morphology effect in the catalytic performances of H-ZSM-5 zeolite for C4 olefin catalytic cracking. A series of H-ZSM-5 zeolites with similar sheet-like morphology but different c-axis lengths were synthesized. We found that the catalytic activity and stability is improved in samples with longer c-axis. Combining time-resolved in-situ FT-IR spectroscopy with molecular dynamics simulations, we show that the difference in catalytic performance can be attributed to the anisotropy of the intracrystalline diffusive propensity of the olefins in different channels. Our descriptor offers mechanistic insight for the design of highly effective zeolite catalysts for olefin cracking.



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