Adsorption properties of carbon adsorbents Communication 2. Adsorption properties of active carbons with respect to benzene and nitrogen vapors

Author(s):  
M. M. Dubinin ◽  
E. G. Zhukovskaia
2021 ◽  
Vol 1045 ◽  
pp. 117-126
Author(s):  
Olena Svietkina ◽  
Olga Netiaga ◽  
Hanna Tarasova ◽  
Ievgenii Ustymenko ◽  
Edgar Caseres Cabana

The variety of practical problems solved in recent years with the help of sorption methods requires expanding the range of used adsorbents. Active carbons are very promising porous adsorbents. Due to a whole complex of valuable properties of a highly developed porous structure, a variety of the chemical nature of the surface, special electrophysical properties, as well as chemical, thermal and radiation resistance, various active carbons are widely used for the absorption of gaseous and dissolved substances. The peculiar nature of carbon adsorbents contributes to the fact that solutes on coal can be adsorbed by completely different; mechanisms, their sorption may be due to the different nature of the forces involved in the adsorption process. The purpose of the work is to obtain multipurpose sorbents; to study methods of modification of carbonaceous sorbents from ash waste, as well as their physicochemical properties


1995 ◽  
Vol 12 (4) ◽  
pp. 267-277 ◽  
Author(s):  
A.M. Puziy ◽  
R. Leboda ◽  
V.I. Bogillo ◽  
V.P. Shkilev ◽  
A. Lodyga

The porous structures of synthetic active carbons have been examined in detail on the basis of nitrogen adsorption isotherms at 77 K using the αS method, the Dubinin–Stoeckli approach and the regularization technique. Analysis of the porosity of synthetic active carbons shows that carbons obtained under identical conditions have dissimilar adsorption properties depending on the size of the granule. The application of the Dubinin–Stoeckli equation for the characterization of strongly heterogeneous carbons overestimates the maximum amount adsorbed in the micropores. In contrast to the Dubinin–Stoeckli equation, the regularization method gives a two-peak micropore size distribution and enables adsorbents with a bimodal porous structure to be estimated.


Author(s):  
A. Zukal ◽  
M. M. Dubinin ◽  
O. Kadlets ◽  
Yu. S. Lezin

1993 ◽  
Vol 10 (1-4) ◽  
pp. 211-220 ◽  
Author(s):  
I.A. Bardina ◽  
E.V. Kalashnikova ◽  
N.V. Kovaleva ◽  
T.A. Rudnitskaya ◽  
N.K. Shonya

Gas chromatography has been used to determine the initial low-coverage heats of adsorption of C2–C6 hydrocarbons and their derivatives on active carbon and graphitized carbon black. The porous structure of the active carbon has been determined from the adsorption isotherms of benzene measured at 25°C by a vacuum static method. The isotherms have been analyzed with the help of the BET and Dubinin–Radushkevich theories.


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