Kinetics of the oxidation of some polycyclic aromatic hydrocarbons by lead tetraacetate in aqueous acetic acid and perchloric acid medium

1985 ◽  
Vol 29 (1) ◽  
pp. 195-201
Author(s):  
P. S. Radhakrishnamurti ◽  
K. S. Tripathy
Keyword(s):  
Acetic Acid ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Acid Medium ◽  
Perchloric Acid ◽  
Aromatic Hydrocarbons ◽  
Lead Tetraacetate ◽  
Aqueous Acetic Acid ◽  
Polycyclic Aromatic ◽  
Kinetics Of

Oxidation kinetics of polycyclic aromatic hydrocarbons by permanganate

Chemosphere ◽  
2010 ◽  
Vol 79 (6) ◽  
pp. 628-636 ◽  
Author(s):  
Steven P. Forsey ◽  
Neil R. Thomson ◽  
James F. Barker
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Oxidation Kinetics ◽  
Polycyclic Aromatic ◽  
Kinetics Of

scholarly journals Kinetics of Oxidation of Some Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium

2004 ◽  
Vol 1 (2) ◽  
pp. 127-131 ◽  
Author(s):  
N. A. Mohamed Farook ◽  
R. Prabaharan ◽  
S. Rahini ◽  
R. Senthil Kumar ◽  
G. Rajamahendran ◽  
...  
Keyword(s):  
Amino Acids ◽  
Acetic Acid ◽  
Acid Medium ◽  
Hypochlorous Acid ◽  
Activation Parameters ◽  
Slow Step ◽  
Aqueous Acetic Acid ◽  
Acetic Acid Medium ◽  
Kinetics Of Oxidation ◽  
Kinetics Of

The kinetics of oxidation of some amino acids namely, glycine, alanine, aspartic acid, arginine, and histidine, (AA) byN-chlorosaccharin (NCSA) in aqueous acetic acid medium in the presence of perchloric acid have been investigated. The observed rate of oxidation is first order in [AA], [NCSA] and of inverse fractional order in [H+]. The main product of the oxidation is the corresponding aldehyde. The ionic strength on the reaction rate has no significant effect. The effect of changing the dielectric constant of the medium on the rate indicates the reaction to be of dipole-dipole type. Hypochlorous acid has been postulated as the reactive oxidizing species. The reaction constants involved in the mechanism are derived. The activation parameters are computed with respect to slow step of the mechanism.

Insights into the mechanism and kinetics of the gas-phase atmospheric reaction of 9-chloroanthracene with NO3 radical in the presence of NOx

RSC Advances ◽  
2015 ◽  
Vol 5 (102) ◽  
pp. 84066-84075 ◽  
Author(s):  
Juan Dang ◽  
Xiangli Shi ◽  
Qingzhu Zhang ◽  
Jingtian Hu ◽  
Wenxing Wang
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Gas Phase ◽  
Aromatic Hydrocarbons ◽  
Important Member ◽  
No3 Radical ◽  
Polycyclic Aromatic ◽  
Mechanism And Kinetics ◽  
Kinetics Of ◽  
Atmospheric Reaction

9-Chloroanthracene (9-ClAnt), an important member of the chlorinated polycyclic aromatic hydrocarbons (ClPAHs).

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