Determination of oligomers in virgin and recycled polyethylene terephthalate (PET) samples by UPLC-MS-QTOF

2018 ◽  
Vol 410 (9) ◽  
pp. 2377-2384 ◽  
Author(s):  
Sara Ubeda ◽  
Margarita Aznar ◽  
Cristina Nerín
2020 ◽  
Vol 993 ◽  
pp. 1511-1517
Author(s):  
Shan Shan Liu ◽  
Ye Chen ◽  
Yu Hui Wang ◽  
Ling Ling Gao ◽  
Fu You Ke ◽  
...  

A method to determine the volatile organic compounds (VOCs) in the recycled polyethylene terephthalate fiber was presented by using the headspace sampling-gas chromatography coupled to flame ionization detector (HS-GC-FID), in order to evaluate the level of VOC contamination. The extraction variables, such as the incubation temperature, the pre-incubation time and the size of the vial, were also studied. The effects on the determination of VOC were also compared using two type chromatographic columns. The optimal conditions were found using a headspace sampling for 20 min at 100 °C, where 120 mL vials and TM-1 column were prior to analysis of benzene compounds in PET(polyethylene terephthalate) fibers. The results can be used in analysis of VOC from recycled PET fibers.


Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.


2020 ◽  
Vol 6 (12) ◽  
pp. 2416-2424
Author(s):  
Erniati Bachtiar ◽  
Mustaan Mustaan ◽  
Faris Jumawan ◽  
Meldawati Artayani ◽  
Tahang Tahang ◽  
...  

This study aims to examine the effect of recycled Polyethylene Terephthalate (PET) artificial aggregate as a substitute for coarse aggregate on the compressive strength and flexural strength, and the volume weight of the concrete. PET plastic waste is recycled by heating to a boiling point of approximately 300°C. There are five variations of concrete mixtures, defined the percentage of PET artificial aggregate to the total coarse aggregate, by 0, 25, 50, 75 and 100%. Tests carried out on fresh concrete mixtures are slump, bleeding, and segregation tests. Compressive and flexural strength tests proceeded based on ASTM 39/C39M-99 and ASTM C293-79 standards at the age of 28 days. The results showed that the use of PET artificial aggregate could improve the workability of the concrete mixture. The effect of PET artificial aggregate as a substitute for coarse aggregate on the compressive and flexural strength of concrete is considered very significant. The higher the percentage of PET plastic artificial aggregate, the lower the compressive and flexural strength, and the volume weight, of the concrete. Substitution of 25, 50, 75 and 100% of PET artificial aggregate gave decreases in compressive strength of 30.06, 32.39, 41.73 and 44.06% of the compressive strength of the standard concrete (18.20 MPa), respectively. The reductions in flexural strength were by respectively 19.03, 54.50, 53.95 and 61.00% of the standard concrete's flexural strength (3.59 MPa). The reductions in volume weight of concrete were by respectively 8.45, 17.71, 25.07 and 34.60% of the weight of the standard concrete volume of 2335.4 kg/m3 Doi: 10.28991/cej-2020-03091626 Full Text: PDF


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