Recycled Polyethylene Modified Asphalt Binders and Mixtures: Performance Characteristics and Environmental Impact

This study addresses the effects of recycled polyethylene (RPE) on the performances of both asphalt binders and asphalt mixtures. Whether using RPE in an asphalt mixture might leach harmful chemicals into rainwater or melted snow was also determined. Two processes, wet and dry, were used to formulate the RPE modified asphalt binders and mixtures. In the wet process, RPE was added to asphalt binder. In the dry process, it was added to heated aggregates. RPE from two sources and PG 64-22 virgin asphalt binders from two sources were used in this study. In conclusion, RPE improved the rutting resistance of the asphalt binders and asphalt mixtures. However, it had adverse effects on their resistance to intermediate-temperature and non-load associated cracking. The dry process could produce a mixture with a higher RPE dosage compared with the wet process using one virgin asphalt binder but not the other; thus, the virgin asphalt binder source was a significant factor for the dry process. Based on an embryotoxicity test, it was found that RPE can be used by the asphalt paving industry without creating any significant environmental risks.

ASSESSMENT OF THE DEGREE AND SOURCE OF POLYOLEFIN RECYCLATES CONTAMINATION

This study has the aim of analysing the degree of contamination of recycled polyolefin purchased from the market by focusing on the content of polycyclic aromatic hydrocarbons (PAHs). Additionally, the impact of the mechanical recycling process on the polyolefin chemical quality was investigated. Results indicated that recycled polyethylene (PE) had higher PAHs concentrations by 10 to 20 folds in comparison to the pristine PE. Similarly, recycled polypropylene (PP) indicated higher PAHs concentrations in comparison to the virgin polypropylene, yet with lower degree of difference. Analysing the 8 indicators assigned by the Regulation EU 1272/2013 amending REACH Annex XVII, all recycled specimens showed concentrations lower than the limit of 0.5 mg kg-1, which indicates that there is no restriction in material’s utilisation. This study functioned as a preliminary assessment to check the suitability of recycled plastics for their further utilisation. Additionally, the study indicates that polyolefin can experience quality deterioration when uncontrolled recycling conditions are applied.

Morphology, Rheological and Mechanical Properties of Isotropic and Anisotropic PP/rPET/GnP Nanocomposite Samples

The effect of graphene nanoplatelets (GnPs) on the morphology, rheological, and mechanical properties of isotropic and anisotropic polypropylene (PP)/recycled polyethylene terephthalate (rPET)-based nanocomposite are reported. All the samples were prepared by melt mixing. PP/rPET and PP/rPET/GnP isotropic sheets were prepared by compression molding, whereas the anisotropic fibers were spun using a drawing module of a capillary viscometer. The results obtained showed that the viscosity of the blend is reduced by the presence of GnP due to the lubricating effect of the graphene platelets. However, the Cox–Merz rule is not respected. Compared to the PP/rPET blend, the GnP led to a slight increase in the elastic modulus. However, it causes a slight decrease in elongation at break. Morphological analysis revealed a poor adhesion between the PP and PET phases. Moreover, GnPs distribute around the droplets of the PET phase with a honey-like appearance. Finally, the effect of the orientation on both systems gives rise not only to fibers with higher modulus values, but also with high deformability and a fibrillar morphology of the dispersed PET phase. A fragile-ductile transition driven by the orientation was observed in both systems.