scholarly journals Optical absorption of electronic Fe–Ti charge-transfer transition in natural andalusite: the thermal stability of the charge-transfer band

2010 ◽  
Vol 38 (3) ◽  
pp. 215-222 ◽  
Author(s):  
Michail N. Taran ◽  
Monika Koch-Müller
2020 ◽  
Vol 8 (26) ◽  
pp. 8876-8886
Author(s):  
Henning Maximilian Sturmeit ◽  
Iulia Cojocariu ◽  
Matteo Jugovac ◽  
Albano Cossaro ◽  
Alberto Verdini ◽  
...  

The strong molecule-surface interaction, followed by charge transfer at the interface, plays a fundamental role in the thermal stability of the layer by rigidly anchoring the porphyrin molecules to the copper substrate.


1979 ◽  
Vol 57 (2) ◽  
pp. 128-131 ◽  
Author(s):  
V. S. Sivasankar ◽  
P. W. Whippey

Single crystals of sodium chlorate have been exposed to X-rays, at 77 K. Thermoluminescence glow curves of the irradiated crystals have been recorded from 77 to 400 K. Optical absorption spectra and electron spin resonance spectra of the crystals subjected to radiation damage have also been recorded as a function of radiation dose, and at different stages of thermal annealing between 77 and 400 K. Using the optical and ESR data, the glow peaks at 173, 185, and 249 K have been identified as due to O2− in the vicinity of ClO3, ClO3, itself, and O2− adjacent to ClO2, respectively. The trapping parameters for these centers have been determined.


1976 ◽  
Vol 19 (6) ◽  
pp. 780-782
Author(s):  
V. G. Zubov ◽  
N. G. Kirillova ◽  
N. D. Kundikova ◽  
L. P. Osipova

2020 ◽  
Vol 128 (2) ◽  
pp. 211
Author(s):  
Д.В. Ананченко ◽  
С.В. Никифоров ◽  
Г.Р. Рамазанова ◽  
Р.И. Баталов ◽  
Р.М. Баязитов ◽  
...  

Luminescence and thermal stability of defects formed in alpha-Al2O3 single crystals under pulsed ion beam treatment (C+/H+ ions with an energy 300 keV, pulse duration 80 ns) were investigated. This type of irradiation leads to the intensive generation of both single F- and F+-centers and more complex defects (F2-type aggregate centers or vacancy-impurity complexes) in alpha-Al2O3. It was confirmed by the results of optical absorption, photoluminescence, and pulsed cathodoluminescence measurements. The thermal stability of F-type defects formed in alpha-Al2O3 under the pulsed ion beam treatment is comparable to the stability of radiation-induced defects in neutron-irradiated samples.


2017 ◽  
Vol 5 (45) ◽  
pp. 23662-23670 ◽  
Author(s):  
Carr Hoi Yi Ho ◽  
Huanyang Cao ◽  
Yong Lu ◽  
Tsz-Ki Lau ◽  
Sin Hang Cheung ◽  
...  

Charge transfer interaction of a donor polymer with an appropriate 9-fluorenylidene malononitrile derivative in the active layer leads to profoundly enhanced thermal stability of fullerene-based bulk heterojunction organic solar cells.


1994 ◽  
Vol 346 ◽  
Author(s):  
John G. Darabi ◽  
W. R. Schmidt ◽  
G. Schwenke ◽  
R. K. MacCrone

ABSTRACTThe dyes oxazine 725, 7-acetoxy-4-methyl coumarin, O-4-methylcoumarinyl-N-[3-(triethoxysilyl)-propyl] carbamate and 2′,7′-dichlorofluorescein were introduced during the acid-catalyzed cohydrolysis of various molar ratios of tetraethoxysilane (TEOS) and the gel modifers, diethoxydimethylsilane (DEDMS) or diethoxymethylvinylsilane (DEMVS). The morphological features and optical absorption spectra of the resulting dye doped gels were followed during subsequent drying and heating. For DEDMS-TEOS molar ratios less than 1.375, gel cracking during drying was a problem. DEDMS-TEOS molar ratios greater than 2.750 yielded optically transparent monoliths, but did not allow for sufficient incorporation of dye to be useful. However, the functionalized dye, 0-4-methylcoumarinyl-N-[3-(triethoxysilyl)-propyl] carbamate, appeared to be significantly more soluble in such a highly modified matrix. Compared to matrices derived from pure TEOS the DEDMS or DEMVS modified matrices provided oxazine 725 doped with improved thermal stabilities. Finally, the 2′,7′-dichlorofluorescein doped dimethylsiloxane-oxide matrix showed good thermal stability in its optical properties, having significant optical absorption and little change in the wavelength of the absorption maximum after heating to 300°C.


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