Fluid inclusions in high-pressure granulites of the Pan-African belt in Tanzania (Uluguru Mts): a record of prograde to retrograde fluid evolution

1998 ◽  
Vol 130 (3-4) ◽  
pp. 199-212 ◽  
Author(s):  
Petra Herms ◽  
Volker Schenk
2006 ◽  
Vol 70 (2) ◽  
pp. 141-158 ◽  
Author(s):  
Ye. Vapnik ◽  
I. Moroz ◽  
M. Roth ◽  
I. Eliezri

AbstractKianjavato emerald (Mananjary deposits, East coast of Madagascar) was formed during metasomatic processes at the contact between pegmatites and hornblendites. The metasomatic exchange was related to a Pan-African tectonometamorphic event.Fluid inclusions in the Kianjavato emerald and quartz were studied by means of microthermometry and Raman probe analysis. Three main types of inclusions were revealed: CO2-rich, CH4-rich and aqueous-rich, with a salinity of ∼2 wt.% NaCl equiv. The inclusions occurred along the same primary and pseudosecondary trails and were considered to be formed simultaneously. Based on fluid-inclusion data, the conditions of emerald growth were 250°C < T < 450°C and P = 1.5 kbar.The fluid inclusion data for Kianjavato emerald were compared to the data for another Madagascar emerald, Ianapera. The latter is of similar age, but its genesis was determined by a shearing event. Our fluid inclusion data suggested that shearing was also important as a mechanism of introducing CO2-rich fluid for the genesis of the Kianjavato emerald.


Geofluids ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-25
Author(s):  
Lu Zhang ◽  
Shao-Yong Jiang ◽  
Suo-Fei Xiong ◽  
Deng-Fei Duan

The Fuzishan Cu-Mo deposit is located in the Edong district of the Middle-Lower Yangtze River Metallogenic Belt, China. The orebodies mainly occurred as lenticular and bedded shapes in the skarn zone between the Lower Permian Qixia Formation carbonate rocks and the quartz diorite. Four paragenetic stages have been recognized based on petrographic observations: (1) prograde skarn stage, (2) retrograde skarn stage, (3) quartz-sulfide stage, and (4) carbonate stage. Six fluid inclusion types were recognized: S1(vapor + liquid + halite ± other daughter minerals), S2(vapor + liquid + daughter minerals except halite), LV(rich liquid + vapor), VL(rich vapor + liquid), V (vapor), and L (liquid) types. Fluid inclusion studies show distinct variations in composition, final homogenization temperature, and salinity in four stages. Daughter minerals of the primary fluid inclusions include chalcopyrite, molybdenite, hematite, anhydrite, calcite, and halite in the prograde skarn stage and hematite, calcite, and sulfide (?) in the retrograde skarn stage. No daughter minerals occurred in the quartz-sulfide and carbonate stages. Final homogenization temperatures recorded in these stages are from 405 to >550°C, from 212 to 498°C, from 150 to 485°C, and from 89 to 223°C, respectively, while salinities are from 3.7 to 42.5, from 2.6 to 18.5, from 2.2 to 17.9, and from 0.2 to 11.5 wt.% NaCl equivalent, respectively. The coexisting VLand S1type fluid inclusions show similar homogenization temperature of 550 to about 650°C in the prograde skarn stage, indicating that immiscibility occurred at lithostatic pressure of 700 bars to perhaps 1000 bars, corresponding to a depth of 2.6 km to about 3.7 km. The coeval VLand LVtypes fluid inclusions with homogenization temperature of 350 to 400°C in the late retrograde skarn and quartz-sulfide stages suggest that boiling occurred under hydrostatic pressure of 150 to 280 bars, equivalent to a depth of 1.5 to 2.8 km. Mo mineralization in the retrograde stage predated Cu mineralization which mainly occurred in the quartz-sulfide stage. Fluid compositions indicate that ore-forming fluid has highfO2and rich Cu and Mo concentration in the early stage, while relatively lowerfO2and poor Cu and Mo concentration in the middle to late stages. Microthermometric data show a decreasing trend in temperature and salinity in the fluid evolution process. Decreasing temperature and boiling event may be the main factors that control the ore precipitation.


2020 ◽  
Vol 55 (4) ◽  
pp. 2591-2614 ◽  
Author(s):  
Bingbing Shi ◽  
Xiangchun Chang ◽  
Youde Xu ◽  
Lixin Mao ◽  
Jianhua Zhang ◽  
...  

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