Investigation of the relationship between rare earth elements, trace elements, and major oxides in soil geochemistry

Author(s):  
Alaaddin Vural
2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
S. O. Oni ◽  
A. S. Olatunji ◽  
O. A. Ehinola

Provenance analysis serves to reconstruct the predepositional history of a sediment/sedimentary rock. This paper focuses on the reconstruction of the provenance and tectonic settings of the Niger delta clastic facies using geochemical approach. The main types of geochemical tests include major, trace, and rare earth element (REE) tests. Twenty-one samples of shales and sandstones units were purposely collected from a depth between 1160 and 11,480 m, grinded, pulverized, and sieved with a <75 μm. About 5 g was packed and sent to Acme analytical Laboratory Ltd., Vancouver, Canada. The analyses were carried out by both induced coupled plasma-mass spectrometry (ICP-MS) and induced coupled plasma-emission spectrometry (ICP-ES). Bulk-rock geochemistry of major oxides, trace elements, and rare earth elements was utilized for the provenance and tectonic setting determination. Based on the discrimination diagram for major oxides, the probable provenance of the south eastern Delta clastic sediments was mainly of the active continental margins. The bivariate plots of La versus Th, La/Y versus Sc/Cr, and Ti/Zr versus La/Sc and the trivariate plots of La-Th-Sc, Th-Sc-Zr/10, and Th-Co-Zr/10 are all plotted on the fields of active continental margin sediments which is consistent with the known actively opening of a failed arm of triple junction. The trace elements and REE analysis indicates that they are virtually Fe-rich, lithic/quartz arkosic sandstones. The normalizing factors used for the REE are Wakita chondrite. Their rare earth elements (REE) pattern displays high light REE/heavy REE (LREE/HREE) ratio, flat HREE, and a significant negative Eu anomaly which correlate well with the UCC and PAAS average composition. The source area may have contained felsic igneous rocks.


2018 ◽  
Vol 10 (33) ◽  
pp. 4094-4103 ◽  
Author(s):  
Fernanda Pollo Paniz ◽  
Tatiana Pedron ◽  
Bruna Moreira Freire ◽  
Daiane Placido Torres ◽  
Fábio Ferreira Silva ◽  
...  

There are several international regulations regarding trace elements. The use of ICP-MS for their determination is usually a difficult task, especially when Hg is one of the target elements.


2012 ◽  
Vol 34 (6) ◽  
pp. 677-687 ◽  
Author(s):  
Eduardo De Miguel ◽  
Juan Mingot ◽  
Enrique Chacón ◽  
Susanne Charlesworth

Biology ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 1058
Author(s):  
Stefano Loppi ◽  
Riccardo Fedeli ◽  
Giulia Canali ◽  
Massimo Guarnieri ◽  
Stefano Biagiotti ◽  
...  

In the Valdichiana area (Tuscany, Italy) an ancient native landrace of elephant garlic (Allium ampeloprasum L.), locally known as “Aglione della Valdichiana”, has long been cultivated. The aim of this study was to check whether there are differences in the mineral and nutraceutical profiles of the Aglione della Valdichiana cultivated conventionally and organically. Based on the analysis by ICP-MS of a wide array of major, minor, essential, and non-essential trace elements as well as rare earth elements, and the evaluation of the content of polyphenols, flavonoids, antioxidants, soluble proteins, soluble sugars, and starch, as well as the weight and water content, it was concluded that differences in the mineral and nutraceutical profiles of organically and conventionally grown bulbs were very limited. Only a statistically (p < 0.05) higher concentration of Cd (+2620%), Co (+113%), Mn (+55%), Rb (+180%), and Sb (+180%), as well as glucose (+37%) in conventionally cultivated bulbs emerged. Cadmium was the only element slightly higher than in the “reference plant,” but with a negligible risk (three orders of magnitude lower) for human health based on consumption. It is concluded that we failed to find evidence of healthier food or a higher nutraceutical quality for organically cultivated elephant garlic.


2021 ◽  
Vol 1 (2) ◽  
Author(s):  
The Hung KHUONG ◽  
Phuong NGUYEN ◽  
Thi Cuc NGUYEN ◽  
Nhu Sang PHAM ◽  
Danh Tuyen NGUYEN

In northern Vietnam, the Tien Hai area is considered a high potential area of coal deposits. Twohundred fifty-six geochemical coal samples of 13 cores in the Tien Hai area investigate coal seams andcoal deposits to identify the correlation of coal seams. According to the statistical method and clusteranalysis of geochemical samples, the results indicate that the Mg, V, As, Ca, Zn, Cr, Co, K, Na, Sr, Fe,Ge, Re, U, Mo, Th, and Ga elements are good indicator elements of the major and trace elements in coal.Most of them comply with the normal or lognormal distribution rules. Besides, the Yb, Sc, Ho, Er, Tm,Lu, Y, Tb, Pr, Dy, and Sm elements are also good indicator elements for rare earth elements in the region.Therefore, the selected elements are used to identify the correlation of the coal seams in the Tien Hai area.Based on the similarity degree between studied objects, the results of grouping boreholes in coal seamsshow that the correlation of coal seam TV2-11 is suitable and acceptable, the coal seams TV3-6a, TV3-6b, and TV3-6c can be grouped into the coal seam TV3-6. These results present that the models can helpstudy geochemical coal samples and identify the correlation of the coal seams in the Tien Hai area.Additionally, the statistical analysis shows a remarkable degree to determine the correlation of the coalseams. Geochemical coal data can help to evaluate the indicator elements of the major, trace elements,and rare earth elements in coal seams and coal rashing of adjoining and pillar rocks in the Tien Hai area,northern Vietnam.


2021 ◽  
Author(s):  
Andres Cardenas Niño ◽  
Rosa Marques ◽  
Maria Dias ◽  
Catarina Diamantino ◽  
Edgar Carvalho

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