Evaluation of some bipyridinium dihalides as inhibitors for low carbon steel corrosion in sulfuric acid solution

2008 ◽  
Vol 38 (9) ◽  
pp. 1301-1311 ◽  
Author(s):  
M. S. Morad ◽  
A. A. Hermas ◽  
A. Y. Obaid ◽  
A. H. Qusti
2013 ◽  
Vol 734-737 ◽  
pp. 2269-2272
Author(s):  
Hong Mei Zhu ◽  
Shu Mei Lei ◽  
Tong Chun Kuang

In this paper, a low carbon steel was used as the substrate to prepare the carbon nanostructural materials by the oxygen-acetylene flame method. The experimental results show that the composite products including nodular carbon nanoparticles and amorphous carbon were obtained on the substrate after a mechanical polishing pretreatment. Comparatively, the short tubular carbon nanofibers with the diameter of around 100 nm were deposited on the substrate pretreated by dipping in the concentrated nitric acid solution. The possible mechanism for the growth of such carbon nanofibers was discussed.


MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.


Author(s):  
Ya.G. Avdeev ◽  
◽  
A.V. Panova ◽  
T.E. Andreeva ◽  
Yu.I. Kuznetsov ◽  
...  

Corrosion of 08PS low-carbon steel was studied in a wide temperature range t = 25—100 °C in 1 M H2SO4 + 1 M H3PO4, 2 M H2SO4 и 2 M H3PO4, inhibited by the binary mixture IFKhAN-92 + KNCS (a molar ratio of components 9:1) and a three-component mixture IFKhAN-92 + KNCS + urotropine (9:1:400), in the presence of high concentrations of Fe(III) and Fe(II) salts, as well as in their joint presence. It is shown that under experimental conditions the corrosion inhibitors under study provide effective protection of steel in 1 M H2SO4 + 1 M H3PO4 even in the presence of Fe(III), Fe(II) salts or their mixtures. The highest protective effects are provided by a three-component inhibitor mixture. Under similar conditions in individual 2 M H3PO4 and, especially, 2 M H2SO4, the protective effects of inhibitors are lower. A stronger deceleration of steel corrosion by composite inhibitors based on IFKhAN-92 in H2SO4 + H3PO4 solutions containing Fe(III) salts in comparison with similar solutions of individual H2SO4, is largely due to the binding of Fe(III) cations by phosphate anions into complexes, that significantly reduces their chemical activity and, as a result the corrosion rate of steel.


Sign in / Sign up

Export Citation Format

Share Document