Green route synthesis of K2SiF6:Mn4+ red phosphor through a brief one-step co-precipitation method for warm white light LEDs

Author(s):  
Jingshan Hou ◽  
Jingzhu Chen ◽  
Meiqing Hu ◽  
Yongzheng Fang ◽  
Ganghua Zhang ◽  
...  
RSC Advances ◽  
2015 ◽  
Vol 5 (72) ◽  
pp. 58136-58140 ◽  
Author(s):  
Zhengliang Wang ◽  
Yong Liu ◽  
Yayun Zhou ◽  
Qiang Zhou ◽  
Huiying Tan ◽  
...  

Red hexafluoride phosphors were synthesized by a simple co-precipitation method. WLEDs fabricated with as-prepared phosphors emit intense warm white-light under 20 mA current excitation. Therefore, they may find application in warm WLEDs.


2019 ◽  
Vol 807 ◽  
pp. 101-109
Author(s):  
Di Wu ◽  
Xin Yu Ye ◽  
Lin Sheng Wang ◽  
Qing Hua Zeng

A novel red-emitting K2SiF6:Mn4+ phosphors with different Mn4+ doping mole fraction were synthesized by co-precipitation method. X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR) and fluorescence spectrometer were used to characterize the properties of K2SiF6:Mn4+ phosphors. As-prepared K2SiF6:Mn4+ phosphors have cubic crystal structure. Under excitation at 450 nm, an intense red emission peak around 632 nm corresponding to the 2Eg-4A2 transition of Mn4+ was observed for 8.37 mol% K2SiF6:Mn4+ phosphors and was used as the optimum doping concentration. The excellent luminescent properties make the phosphor K2SiF6:Mn4+ a candidate for applications in InGaN-YAG:Ce3+ type LEDs for high color rendering. “A warm” white light LED with an efficiency of 147 lm/w and a color rendering index of 87.4 at a color temperature of 2864K has been obtained by fabricating YAG:Ce3+ with K2SiF6:Mn4+ on an InGaN chip.


2018 ◽  
Vol 6 (11) ◽  
pp. 2741-2746 ◽  
Author(s):  
Ziyang Hou ◽  
Xueyuan Tang ◽  
Xuefang Luo ◽  
Tianliang Zhou ◽  
Lin Zhang ◽  
...  

A green synthetic route to the highly efficient K2SiF6:Mn4+narrow-band red phosphor for warm white light-emitting diodes.


2021 ◽  
Author(s):  
Jiao Wu ◽  
Bo Wang ◽  
Zhiyuan Liu ◽  
Kang Zhang ◽  
Xiaoshuang Li ◽  
...  

Mn4+-activated oxidefluoride phosphors are attractive for application in wide solid-state lighting devices because of its distinct red emission at about 630 nm and the abundant storage of Mn4+ ion. However,...


2015 ◽  
Vol 36 (12) ◽  
pp. 1402-1408 ◽  
Author(s):  
罗 洋 LUO Yang ◽  
江建青 JIANG Jian-qing ◽  
侯得健 HOU De-jian ◽  
游维雄 YOU Wei-xiong ◽  
叶信宇 YE Xin-yu

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 874
Author(s):  
Haifeng Wang ◽  
Jianwei Lu ◽  
Ruoxuan Wang ◽  
Yungu Dong ◽  
Linfeng Ding

The synthesis process has a significant influence on the properties of Ca1-xTiO3:Eu3+x phosphors; thus, an optimized process will lead to a better performance of the Ca1-xTiO3:Eu3+x phosphors. In this work, the feasibility of synthesizing the Ca1-xTiO3:Eu3+x phosphor with a good luminescent performance by combining the chemical co-precipitation method and microwave-assisted sintering was studied. The precursor of Ca1-xTiO3:Eu3+x phosphors were prepared by the chemical co-precipitation method. To find an optimized process, we applied both of the traditional (furnace) sintering and the microwave-assisted sintering to synthesize the Ca1-xTiO3:Eu3+x phosphors. We found out that a sintering power of 528 W for 50 min (temperature around 950 °C) by a microwave oven resulted in similar emission intensity results compared to traditional furnace sintering at 900 °C for 2.5 h. The synthesized Ca1-xTiO3:Eu3+x phosphors has an emission peak at 617 nm (5D0→7F2), which corresponds to the red light band. This new synthesized method is an energy efficient, time saving, and environmentally friendly means for the preparation of Ca1-xTiO3:Eu3+x red phosphor with good luminescent performance.


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