Gas diffusion in polymer nanocomposites: Role of defects and caves in fillers

2021 ◽  
Vol 28 (10) ◽  
Author(s):  
Jianfeng Wan ◽  
Wenyan Bi ◽  
Xiangbiao Liao ◽  
Hang Xiao ◽  
Xi Chen ◽  
...  
2014 ◽  
Vol 47 (15) ◽  
pp. 5246-5255 ◽  
Author(s):  
Nicolas Jouault ◽  
Dan Zhao ◽  
Sanat K. Kumar

Nanoscale ◽  
2021 ◽  
Author(s):  
Mahdi Zeidi ◽  
Chun Il Kim ◽  
Chul B B. Park

Interface plays a crucial role on the physical and functional properties of polymer nanocomposites, yet its effects have not been fully recognized in the setting of classical continuum-based modeling. In...


Author(s):  
N. Akhtar ◽  
P. J. A. M. Kerkhof

The role of gas diffusion media with differently structured properties have been examined with emphasis on the liquid water saturation within the cathode of a proton exchange membrane fuel cell (PEMFC). The cathode electrode consists of a gas diffusion layer (GDL), a micro-porous layer and a catalyst layer (CL). The liquid water saturation profiles have been calculated for varying structural and physical properties, i.e., porosity, permeability, thickness and contact angle for each of these layers. It has been observed that each layer has its own role in determining the liquid water saturation within the CL. Among all the layers, the GDL is the most influential layer that governs the transport phenomena within the PEMFC cathode. Besides, the thickness of the CL also affects the liquid water saturation and it should be carefully controlled.


2005 ◽  
Vol 11 (8-9) ◽  
pp. 567-586 ◽  
Author(s):  
C. Velasco-Santos ◽  
A. L. Martinez-Hernandez ◽  
V. M. Castano

2019 ◽  
Vol 16 (6) ◽  
pp. 1187-1209 ◽  
Author(s):  
Teamrat A. Ghezzehei ◽  
Benjamin Sulman ◽  
Chelsea L. Arnold ◽  
Nathaniel A. Bogie ◽  
Asmeret Asefaw Berhe

Abstract. Soil water status is one of the most important environmental factors that control microbial activity and rate of soil organic matter (SOM) decomposition. Its effect can be partitioned into effect of water energy status (water potential) on cellular activity, effect of water volume on cellular motility, and aqueous diffusion of substrate and nutrients, as well as the effect of air content and gas-diffusion pathways on concentration of dissolved oxygen. However, moisture functions widely used in SOM decomposition models are often based on empirical functions rather than robust physical foundations that account for these disparate impacts of soil water. The contributions of soil water content and water potential vary from soil to soil according to the soil water characteristic (SWC), which in turn is strongly dependent on soil texture and structure. The overall goal of this study is to introduce a physically based modeling framework of aerobic microbial respiration that incorporates the role of SWC under arbitrary soil moisture status. The model was tested by comparing it with published datasets of SOM decomposition under laboratory conditions.


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