On the use of tapered channels gas distributors to promote convection in PEM Fuel Cells

Polymeric Exchange Membrane Fuel Cells (PEMFC) are promising power propulsion systems for the decarbonization of the transportation sector. Despite being a well-known method for the direct production of electric current from the reactants chemical energy, one of the major limitations to their large-scale industrial development are fluid dynamics and mass transport aspects, crucially limiting the electrochemistry rate under critical conditions. This is especially verified in PEMFC with serpentine-type gas distributors, for which such areas are identified in proximity of the gas channel bends where the dominant mechanism for species transport shifts from a convection-enhanced to a diffusion-limited one. An engineering method to enhance the convective transport in such deficient areas is the use of gas distributors with tapered channels, effectively forcing the flow in diffusive media and improving the reactants delivery rate and products removal. A numerical analysis is presented on a limited domain representing a section of a serpentine gas distributor. A multi-dimensional CFD study is carried out comparing conventional-type and tapered channel distributors, evaluating the combined effect of pressure losses, catalyst layers utilization, flow regime in anisotropic diffusion media and convection/diffusion balance via a non-dimensional analysis. The study covers various inlet Reynolds numbers and in-plane permeability of porous materials for two diffusion media thicknesses, with the aim to extend the generality of the study. Conclusions based on the simulation results outline channel tapering as a very effective way to improve the power density of PEMFC, although an energetic cost/benefit analysis indicates a reduced cell efficiency.

Optimization of Perfluoropolyether-Based Gas Diffusion Media Preparation for PEM Fuel Cells

A hydrophobic perfluoropolyether (PFPE)-based polymer, namely Fluorolink® P56, was studied instead of the commonly used polytetrafluoroethylene (PTFE), in order to enhance gas diffusion media (GDM) water management behavior, on the basis of a previous work in which such polymers had already proved to be superior. In particular, an attempt to optimize the GDM production procedure and to improve the microporous layer (MPL) adhesion to the substrate was carried out. Materials properties have been correlated with production routes by means of both physical characterization and electrochemical tests. The latter were performed in a single PEM fuel cell, at different relative humidity (namely 80% on anode side and 60%/100% on cathode side) and temperature (60 °C and 80 °C) conditions. Additionally, electrochemical impedance spectroscopy measurements were performed in order to assess MPLs properties and to determine the influence of production procedure on cell electrochemical parameters. The durability of the best performing sample was also evaluated and compared to a previously developed benchmark. It was found that a final dipping step into PFPE-based dispersion, following MPL deposition, seems to improve the adhesion of the MPL to the macro-porous substrate and to reduce diffusive limitations during fuel cell operation.