Synthesis, application, and flame-retardant mechanism of a novel phosphorus-containing plasticizer based on castor oil for polyvinyl chloride

2015 ◽  
Vol 120 (3) ◽  
pp. 1731-1740 ◽  
Author(s):  
Puyou Jia ◽  
Meng Zhang ◽  
Lihong Hu ◽  
Caiying Bo ◽  
Yong-hong Zhou
2018 ◽  
Vol 19 (5) ◽  
pp. 1057-1063 ◽  
Author(s):  
Fang Wang ◽  
Siyu Pan ◽  
Peikun Zhang ◽  
Haojun Fan ◽  
Yi Chen ◽  
...  

2017 ◽  
Vol 87 ◽  
pp. 209-220 ◽  
Author(s):  
Puyou Jia ◽  
Lihong Hu ◽  
Meng Zhang ◽  
Guodong Feng ◽  
Yonghong Zhou

2015 ◽  
Vol 32 (6) ◽  
pp. 1201-1206 ◽  
Author(s):  
Guodong Feng ◽  
Puyou Jia ◽  
Liqiang Zhang ◽  
Lihong Hu ◽  
Meng Zhang ◽  
...  

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.


1985 ◽  
Vol 27 (1) ◽  
pp. 105-111 ◽  
Author(s):  
M.I. Abdullin ◽  
A.F. Valeyev ◽  
V.P. Biryukov ◽  
G.M. Trosman ◽  
K.S. Minsker

Author(s):  
Fuhao Dong ◽  
Yuqi Wang ◽  
Shibo Wang ◽  
Hiba Shaghaleh ◽  
Penghao Sun ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30943-30954
Author(s):  
Wei Peng ◽  
Yu-xuan Xu ◽  
Shi-bin Nie ◽  
Wei Yang

Phosphorus-containing flame retardants have received huge interest for improving the flame retardant behavior of epoxy resins (EP) over the past few decades.


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