Flame-retarded polyurethane foam conferred by a bio-based nitrogen‑phosphorus-containing flame retardant

2021 ◽  
pp. 105057
Author(s):  
Fuhao Dong ◽  
Yuqi Wang ◽  
Shibo Wang ◽  
Hiba Shaghaleh ◽  
Penghao Sun ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Phosphorus Containing ◽  
Flame Retarded ◽  
Nitrogen Phosphorus

scholarly journals Synthesis of a DOPO-triazine additive and its flame-retardant effect in rigid polyurethane foam

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 235-243 ◽  
Author(s):  
Lin Liu ◽  
Rui Lv
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Cell Structure ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Limiting Oxygen Index ◽  
Flame Retarded ◽  
Flame Retardant Properties ◽  
Mechanical Performances ◽  
Halogen Free

AbstractA DOPO (9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide)-based halogen-free flame retardant (ODOPM-CYC) was synthesized and incorporated in rigid polyurethane foam (RPUF). The structure of ODOPM-CYC was characterized by Fourier transform infrared spectra (FTIR), 1H NMR and 31P NMR. The effects of ODOPM-CYC on the flame resistance, mechanical performances, thermal properties and cell structure of RPUF were also investigated. The results showed that the incorporation of ODOPM-CYC strikingly enhanced flame retardant properties of RPUF. The flame retarded RPUF acquired a limiting oxygen index (LOI) value of 26% and achieved UL-94 V-0 rating with the phosphorus content of 3 wt%. The smoke production rate (SPR) also showed an obvious decrease and total smoke release (TSR) was 39.8% lower than that of neat RPUF. Besides, the results demonstrated that the incorporation of ODOPM-CYC provided RPUF better thermal stability but did not show any obvious influence on its thermal conductivity.

Infrared Analysis on Pyrolysis Products of Flame Retardant Rigid Polyurethane Foam

2014 ◽  
Vol 1033-1034 ◽  
pp. 900-906
Author(s):  
Ze Jiang Zhang ◽  
Li Jun Li ◽  
Feng Li ◽  
Jin He ◽  
Zi Qiong Gan
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Magnesium Hydroxide ◽  
Hydrogen Cyanide ◽  
Flame Retardants ◽  
Fire Retardant ◽  
Infrared Analysis ◽  
Antimony Trioxide ◽  
Stretching Vibration ◽  
Flame Retarded

Infrared spectra of the pyrolysis gases of polyurethane foam flame retarded by MPOP, MP, MC, magnesium hydroxide, or antimony trioxide flame retardants was analyzed online by FTIR method. At 600°C, the polyurethane foam flame retarded by MPOP, MP, MC, magnesium hydroxide or antimony trioxide flame retardants released more hydrogen cyanide than the pure polyurethane foam, proved that the MPOP, MP, MC and magnesium hydroxide flame retardants could change the law that the polyurethane released hydrogen cyanide. At 600 °C, the peak of C=O stretching vibration at 1730cm-1did not appear for the flame-retardant polyurethane, indicating that the flame retardants can make the polyurethane rapidly carbonize and the fewer C=O intermediate was produced. The absorbent peaks of the fire-retardant samples at 1604cm-1, 1538 cm-1, 1250 to 1230 cm-1and 1450cm-1implied that the flame retardants could delay the oxidative decomposition of the polyurethane component at 600 °C, so that more components may be carbonized. When increasing the pyrolysis temperature, the perlite would make polyurethane foam release fewer hydrogen cyanide.

Interaction of Flame-Retardant and Untreated Cotton Fabrics during Burning

1977 ◽  
Vol 47 (5) ◽  
pp. 351-360 ◽  
Author(s):  
Stanley R. Hobart ◽  
Charles H. Mack
Keyword(s):  
Flame Retardant ◽  
Cotton Fabric ◽  
Flame Retardancy ◽  
Oxygen Index ◽  
Cotton Fabrics ◽  
Transfer Effect ◽  
Geometrical Configuration ◽  
Untreated Cotton ◽  
Phosphorus Containing ◽  
Flame Retarded

Transfer of flame retardancy from fabric treated with THPOH-NH3 to untreated cotton fabric during burning was observed on fabric samples sewed together with glass thread. The transfer effect was evidenced by the development of substantial char and the presence of phosphorus and nitrogen in the char of the untreated fabric. Oxygen-index determinations on multilayered combinations of flame-retarded (FR) and untreated fabrics also supported this observation. The extent of FR transfer varied with the geometrical configuration of the layers and the FR add-on. Tests showed that smoke from combustion of THPOH-NH3-treated fabric, passed through untreated cotton fabric, was the means of transfer of phosphorus, nitrogen, and flame retardancy. The FR transfer effect was also demonstrated for several other phosphorus-containing flame-retardancy treatments.

Inherently Flame-Retardant Flexible Polyurethane Foam with Low Content of Phosphorus-Containing Cross-Linking Agent

2014 ◽  
Vol 53 (3) ◽  
pp. 1160-1171 ◽  
Author(s):  
Ming-Jun Chen ◽  
Chun-Rong Chen ◽  
Yi Tan ◽  
Jian-Qian Huang ◽  
Xiu-Li Wang ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Cross Linking ◽  
Phosphorus Containing ◽  
Flexible Polyurethane Foam ◽  
Flexible Polyurethane

scholarly journals Nitrogen/phosphorus synergistic flame retardant-filled flexible polyurethane foams: microstructure, compressive stress, sound absorption, and combustion resistance

RSC Advances ◽  
2019 ◽  
Vol 9 (37) ◽  
pp. 21192-21201 ◽  
Author(s):  
Ting-Ting Li ◽  
Mengfan Xing ◽  
Hongyang Wang ◽  
Shih-Yu Huang ◽  
Chengeng Fu ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Polyurethane Foam ◽  
Sound Absorption ◽  
Heat Insulation ◽  
Polyurethane Foams ◽  
Rigid Polyurethane Foam ◽  
Flexible Polyurethane Foam ◽  
Synergistic Flame Retardant ◽  
Flexible Polyurethane ◽  
Nitrogen Phosphorus

Compared with a rigid polyurethane foam, a flexible polyurethane foam (FPUF) has more diversified applications including filtration, sound absorption, vibration-proofing, decoration, packaging, and heat insulation.

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