Synthesis of bimetallic AuPt/CeO2 catalysts and their comparative study in CO oxidation under different reaction conditions

2019 ◽  
Vol 127 (1) ◽  
pp. 69-83 ◽  
Author(s):  
Pavel E. Plyusnin ◽  
Elena M. Slavinskaya ◽  
Roman M. Kenzhin ◽  
Anastasiya K. Kirilovich ◽  
Evgeniya V. Makotchenko ◽  
...  
2018 ◽  
Vol 428 ◽  
pp. 598-608 ◽  
Author(s):  
Shaikh Tofazzel Hossain ◽  
Yazeed Almesned ◽  
Kefu Zhang ◽  
Elizabeth T. Zell ◽  
David T. Bernard ◽  
...  

Tetrahedron ◽  
1996 ◽  
Vol 52 (38) ◽  
pp. 12597-12612 ◽  
Author(s):  
Anka Bojilova ◽  
R. Nikolova ◽  
Christo Ivanov ◽  
Nestor A. Rodios ◽  
A. Terzis ◽  
...  

2015 ◽  
Vol 93 (7) ◽  
pp. 696-701 ◽  
Author(s):  
Hui Li ◽  
Yuanbin She ◽  
Haiyan Fu ◽  
Meijuan Cao ◽  
Jing Wang ◽  
...  

The synergistic effect of cyclohexane and cyclohexanone promoted synthesis of adipic acid catalyzed by [MnIIIT(p-Cl)PP]Cl with cyclohexane and cyclohexanone as co-reactants. The results showed that the conversions of cyclohexane and cyclohexanone were significantly enhanced because of the cyclohexanone synergistic effect, and the higher selectivity to adipic acid was obtained with dioxygen as an oxidant. The studies indicated that the co-oxidation of cyclohexane and cyclohexanone was influenced by the initial molar ratio of cyclohexanone and cyclohexane, catalyst structure, catalyst concentrations, and reaction conditions. The preliminary mechanism of the co-oxidation reaction of cyclohexane and cyclohexanone using [MnIIIT(p-Cl)PP]Cl as the catalyst was proposed.


2006 ◽  
Vol 600 (18) ◽  
pp. 4221-4227 ◽  
Author(s):  
Kenji Nakao ◽  
Shin-ichi Ito ◽  
Keiichi Tomishige ◽  
Kimio Kunimori

2020 ◽  
Vol 46 (17) ◽  
pp. 27725-27733
Author(s):  
O.G. Ellert ◽  
A.V. Egorysheva ◽  
E. Yu Liberman ◽  
S.V. Golodukhina ◽  
O.V. Arapova ◽  
...  

2020 ◽  
Vol 493 ◽  
pp. 111086
Author(s):  
E. Gonzalez-A ◽  
R. Rangel ◽  
A. Solís-Garcia ◽  
A.M. Venezia ◽  
T.A. Zepeda

2020 ◽  
Vol 22 (15) ◽  
pp. 7738-7746
Author(s):  
Hui Zhou ◽  
Dong Wang ◽  
Xue-Qing Gong

In heterogeneous catalysis, surface hydroxylation is well recognized as a common phenomenon under realistic reaction conditions.


2019 ◽  
Vol 150 (3) ◽  
pp. 605-612 ◽  
Author(s):  
Y. Suchorski ◽  
I. Bespalov ◽  
J. Zeininger ◽  
M. Raab ◽  
M. Datler ◽  
...  

Abstract The catalytic CO oxidation reaction on stepped Rh surfaces in the 10−6 mbar pressure range was studied in situ on individual μm-sized high-Miller-index domains of a polycrystalline Rh foil and on nm-sized facets of a Rh tip, employing photoemission electron microscopy (PEEM) and field-ion/field-emission microscopy (FIM/FEM), respectively. Such approach permits a direct comparison of the reaction kinetics for crystallographically different regions under identical reaction conditions. The catalytic activity of the different Rh surfaces, particularly their tolerance towards poisoning by CO, was found to be strongly dependent on the density of steps and defects, as well as on the size (µm vs. nm) of the respective catalytically active surface. Graphic Abstract


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