scholarly journals Pore-Scale Transport and Two-Phase Fluid Structures in Fibrous Porous Layers: Application to Fuel Cells and Beyond

Author(s):  
Meisam Farzaneh ◽  
Henrik Ström ◽  
Filippo Zanini ◽  
Simone Carmignato ◽  
Srdjan Sasic ◽  
...  

AbstractWe present pore-scale simulations of two-phase flows in a reconstructed fibrous porous layer. The three-dimensional microstructure of the material, a fuel cell gas diffusion layer, is acquired via X-ray computed tomography and used as input for lattice Boltzmann simulations. We perform a quantitative analysis of the multiphase pore-scale dynamics, and we identify the dominant fluid structures governing mass transport. The results show the existence of three different regimes of transport: a fast inertial dynamics at short times, characterised by a compact uniform front, a viscous-capillary regime at intermediate times, where liquid is transported along a gradually increasing number of preferential flow paths of the size of one–two pores, and a third regime at longer times, where liquid, after having reached the outlet, is exclusively flowing along such flow paths and the two-phase fluid structures are stabilised. We observe that the fibrous layer presents significant variations in its microscopic morphology, which have an important effect on the pore invasion dynamics, and counteract the stabilising viscous force. Liquid transport is indeed affected by the presence of microstructure-induced capillary pressures acting adversely to the flow, leading to capillary fingering transport mechanism and unstable front displacement, even in the absence of hydrophobic treatments of the porous material. We propose a macroscopic model based on an effective contact angle that mimics the effects of the such a dynamic capillary pressure. Finally, we underline the significance of the results for the optimal design of face masks in an effort to mitigate the current COVID-19 pandemic.

2017 ◽  
Vol 21 (11) ◽  
pp. 5503-5515 ◽  
Author(s):  
Hiroyuki Hirashima ◽  
Francesco Avanzi ◽  
Satoru Yamaguchi

Abstract. The heterogeneous movement of liquid water through the snowpack during precipitation and snowmelt leads to complex liquid water distributions that are important for avalanche and runoff forecasting. We reproduced the formation of capillary barriers and the development of preferential flow through snow using a three-dimensional water transport model, which was then validated using laboratory experiments of liquid water infiltration into layered, initially dry snow. Three-dimensional simulations assumed the same column shape and size, grain size, snow density, and water input rate as the laboratory experiments. Model evaluation focused on the timing of water movement, thickness of the upper layer affected by ponding, water content profiles and wet snow fraction. Simulation results showed that the model reconstructs relevant features of capillary barriers, including ponding in the upper layer, preferential infiltration far from the interface, and the timing of liquid water arrival at the snow base. In contrast, the area of preferential flow paths was usually underestimated and consequently the averaged water content in areas characterized by preferential flow paths was also underestimated. Improving the representation of preferential infiltration into initially dry snow is necessary to reproduce the transition from a dry-snow-dominant condition to a wet-snow-dominant one, especially in long-period simulations.


2010 ◽  
Vol 86 (2) ◽  
pp. 495-515 ◽  
Author(s):  
Dmitriy Silin ◽  
Liviu Tomutsa ◽  
Sally M. Benson ◽  
Tad W. Patzek

Author(s):  
Anh Dinh Le ◽  
Biao Zhou

A single-phase, three-dimensional mathematical model has been constructed and implemented to simulate the fluid flow, heat transfer, species transport, electrochemical reaction, and current density distributions in a Proton Exchange Membrane Fuel Cell (PEMFC) stack with parallel-shaped channels. In this study, a complete PEMFC stack with 3 parallel single-cells including the membrane, gas diffusion layers (GDLs), catalyst layers, flow channels, and current collectors was taken into account. The reasonable numerical results show the detailed distributions of fluid flow and species concentrations in the channel and porous media, heat and current transports through the single cells in the stack. Furthermore, this successful modeling of a single-phase PEMFC stack would be a critical step to further develop a general two-phase PEMFC model that could investigate the water management and effects of liquid water on the performance of a fuel cell stack.


Georesursy ◽  
2020 ◽  
Vol 22 (1) ◽  
pp. 4-12
Author(s):  
Timur R. Zakirov ◽  
Maxim G. Khramchenkov

This paper presents the results of numerical simulations of two-phase flows in porous media under capillary forces dominance. For modeling of immiscible two-phase flow, the lattice Boltzmann equations with multi relaxation time operator were applied, and the interface phenomena was described with the color-gradient method. The objective of study is to establish direct links between quantitative characteristics of the flow and invasion events, using high temporal resolution when detecting simulation results. This is one of the few works where Haines jumps (rapid invasion event which occurs at meniscus displacing from narrow pore throat to its wide body) are considered in three-dimensional natural pore space, but the focus is also on the displacement mechanics after jumps. It was revealed the sequence of pore scale events which can be considered as a period of drainage process: rapid invasion event during Haines jump; finish of jump and continuation of uniform invasion in current pore; switching of mobile interfaces and displacement in new region. The detected interface change, along with Haines jump, is another distinctive feature of the capillary forces action. The change of the mobile interfaces is manifested in step-like behavior of the front movement. It was obtained that statistical distributions of pressure drops during Haines jumps obey lognormal law. When investigating the flow rate and surface tension effect on the pressure drop statistics it was revealed that these parameters practically don’t affect on the statistical distribution and influence only on the magnitude of pressure drops and the number of individual Haines jumps.


Author(s):  
Haipeng Zhang ◽  
Tomer Palmon ◽  
Seunghee Kim ◽  
Sangjin Ryu

Abstract Porous media compressed air energy storage (PM-CAES) is an emerging technology that stores compressed air in an underground aquifer during the off-peak periods, to mitigate the mismatch between energy supplies and demands. Thus, PM-CAES involves repeated two-phase fluid flow in porous media, and ensuring the success of PM-CAES requires a better understanding of repetitive two-phase fluid flow through porous media. For this purpose, we previously developed microfluidic channels that retain a two-dimensional (2D) pore network. Because it was found that the geometry of the pore structure significantly affects the patterns and occupational efficiencies of a non-wetting fluid during the drainage-imbibition cycles, a more realistic microfluidic model is needed to reflect the three-dimensional (3D) nature of pore structures in the underground geologic formation. In this study, we developed an easy-to-adopt method to fabricate a microfluidic device with a 3D random pore network using a sacrificial sugar template. Instead of using a master mold made in photolithography, a sacrificial mold was made using sugar grains so that the mold could be washed away after PDMS curing. First, we made sugar templates with different levels of compaction load, and found that the thickness of the templates decreased as the compaction load increased, which suggests more packing of sugar grains and thus lower porosity in the template. Second, we fabricated PDMS porous media using the sugar template as a mold, and imaged their pore structure using micro computed tomography (micro-CT). Pores within PDSM samples appeared more tightly packed as the compacting force increased. Last, we fabricated a prototype PDMS channel device with a 3D pore network using a sugar template, and visualized flow through the pore network using colored water. The flow visualization result shows that the water was guided by the random pores and that the resultant flow pattern was three dimensional.


Solid Earth ◽  
2016 ◽  
Vol 7 (3) ◽  
pp. 881-895 ◽  
Author(s):  
Lurdes Martinez-Landa ◽  
Jesús Carrera ◽  
Andrés Pérez-Estaún ◽  
Paloma Gómez ◽  
Carmen Bajos

Abstract. A method developed for low-permeability fractured media was applied to understand the hydrogeology of a mine excavated in a granitic pluton. This method includes (1) identifying the main groundwater-conducting features of the medium, such as the mine, dykes, and large fractures, (2) implementing this factors as discrete elements into a three-dimensional numerical model, and (3) calibrating these factors against hydraulic data . A key question is how to identify preferential flow paths in the first step. Here, we propose a combination of several techniques. Structural geology, together with borehole sampling, geophysics, hydrogeochemistry, and local hydraulic tests aided in locating all structures. Integration of these data yielded a conceptual model of the site. A preliminary calibration of the model was performed against short-term (< 1 day) pumping tests, which facilitated the characterization of some of the fractures. The hydraulic properties were then used for other fractures that, according to geophysics and structural geology, belonged to the same families. Model validity was tested by blind prediction of a long-term (4 months) large-scale (1 km) pumping test from the mine, which yielded excellent agreement with the observations. Model results confirmed the sparsely fractured nature of the pluton, which has not been subjected to glacial loading–unloading cycles and whose waters are of Na-HCO3 type.


2010 ◽  
Vol 46 (2) ◽  
Author(s):  
Majdi R. Abou Najm ◽  
Jalal D. Jabro ◽  
William M. Iversen ◽  
Rabi H. Mohtar ◽  
Robert G. Evans

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