Water injection increases reservoir pressure in enhanced oil recovery (EOR). Among other oilfield performance chemicals, an EOR polymer is added to the injection water to provide the viscosity necessary for effective displacement of viscous crude oil from the reservoir formation. However, these organic macromolecules may be degraded by microbes downhole, causing undesirable viscosity loss. The organic carbon utilization by the microbes promotes microbial metabolism, thus potentially exacerbating microbiologically influenced corrosion (MIC). In this preliminary laboratory investigation, 3,000 ppm (w/w) carboxymethyl cellulose sodium (CMCS), a commonly used EOR polymer, was found to be utilized by an oilfield biofilm consortium. This oilfield biofilm consortium consisted of bacteria (including that can degrade large organic molecules), sulfate-reducing bacteria (SRB), and other microorganisms. A 30-day incubation in 125 mL anaerobic vials was conducted with an artificial seawater medium without yeast extract and lactate supplements at 37°C. The polymer biodegradation led to 16% viscosity loss in the broth and a 30× higher SRB sessile cell count. Slightly increased MIC weight loss and pitting corrosion were observed on C1018 carbon steel coupons. Thus, the use of CMCS in EOR should take into the consideration of microbial degradation and its impact on MIC.
Bulk phase resource ratio alters carbon steel corrosion rates and endogenously produced extracellular electron transfer mediators in a sulfate-reducing biofilm
