Thiophene-based conjugated microporous polymers: synthesis, characterization and efficient gas storage

2017 ◽  
Vol 60 (8) ◽  
pp. 1067-1074 ◽  
Author(s):  
Chao-Jing Sun ◽  
Xue-Qian Zhao ◽  
Peng-Fei Wang ◽  
Hua Wang ◽  
Bao-Hang Han
Keyword(s):  
Gas Storage ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Nitrogen-Rich Conjugated Microporous Polymers: Facile Synthesis, Efficient Gas Storage, and Heterogeneous Catalysis

2017 ◽  
Vol 9 (44) ◽  
pp. 38390-38400 ◽  
Author(s):  
Yaozu Liao ◽  
Zhonghua Cheng ◽  
Weiwei Zuo ◽  
Arne Thomas ◽  
Charl F. J. Faul
Keyword(s):  
Heterogeneous Catalysis ◽  
Gas Storage ◽  
Facile Synthesis ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Ferrocene-Based Conjugated Microporous Polymers Derived from Yamamoto Coupling for Gas Storage and Dye Removal

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 719 ◽  
Author(s):  
Zhiqiang Tan ◽  
Huimin Su ◽  
Yiwen Guo ◽  
Huan Liu ◽  
Bo Liao ◽  
...  
Keyword(s):  
Methyl Violet ◽  
Functional Materials ◽  
Gas Storage ◽  
Bet Surface Area ◽  
Energy And Environment ◽  
Microporous Polymers ◽  
Physicochemical Stability ◽  
High Efficient ◽  
Yamamoto Coupling ◽  
Conjugated Microporous Polymers

Conjugated microporous polymers (CMPs) have conjugated skeleton and permanent porosity, and exhibit huge potential in developing novel functional materials for resolving the challenging energy and environment issues. Metal-containing CMPs often exhibited unique properties. In the present manuscript, ferrocene-based conjugated microporous polymers (FcCMPs) were designed and synthesized with 1,1′-dibromoferrocene and 5,10,15,20-Tetrakis(4- bromophenyl) porphyrin (FcCMP-1) or Tetra (p-bromophenyl) methane (FcCMP-2) as building units via Yamamoto coupling. FcCMPs were amorphous, and exhibited excellent thermal and physicochemical stability. The BET surface area of FcCMP-1 and FcCMP-2 was 638 m2/g and 422 m2/g, respectively. In comparison with FcCMP-2, FcCMP-1 displayed better gas storage capacity due to higher porosity. FcCMPs were also used as an adsorbent for removal of methyl violet from aqueous solution, and exhibited excellent adsorption properties due to the interaction between electron-rich conjugated structure of the polymers and methyl violet with cationic groups. Moreover, FcCMPs could be extracted and regenerated by an eluent and then re-used for high efficient removal of methyl violet.

Synthesis of conjugated microporous polymers for gas storage and selective adsorption

2015 ◽  
Vol 50 (19) ◽  
pp. 6388-6394 ◽  
Author(s):  
Qian Shi ◽  
Hanxue Sun ◽  
Ruixia Yang ◽  
Zhaoqi Zhu ◽  
Weidong Liang ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Gas Storage ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Design, preparation and application of conjugated microporous polymers

2013 ◽  
Vol 63 (3) ◽  
pp. 381-392 ◽  
Author(s):  
Qingquan Liu ◽  
Zhe Tang ◽  
Minda Wu ◽  
Zhihua Zhou
Keyword(s):  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Impact of Chemical Structure on the Dynamics of Mass Transfer of Water in Conjugated Microporous Polymers: A Neutron Spectroscopy Study

2021 ◽  
Vol 3 (2) ◽  
pp. 765-776
Author(s):  
Anne A. Y. Guilbert ◽  
Yang Bai ◽  
Catherine M. Aitchison ◽  
Reiner Sebastian Sprick ◽  
Mohamed Zbiri
Keyword(s):  
Mass Transfer ◽  
Chemical Structure ◽  
Neutron Spectroscopy ◽  
Spectroscopy Study ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

scholarly journals Rational design of bifunctional conjugated microporous polymers

2021 ◽  
Author(s):  
Yanpei Song ◽  
Pui Ching Lan ◽  
Kyle Martin ◽  
Shengqian Ma
Keyword(s):  
Rational Design ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
First Report ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Conjugated microporous polymers (CMPs) are an emerging class of porous organic polymers that combine -conjugated skeletons with permanent micropores. Since their first report in 2007, the enormous exploration of linkage...

Sulfur-doped triazine-conjugated microporous polymers for achieving the robust visible-light-driven hydrogen evolution

2021 ◽  
Vol 421 ◽  
pp. 129825
Author(s):  
Ahmed M. Elewa ◽  
Ahmed F.M. EL-Mahdy ◽  
Mohamed Hammad Elsayed ◽  
Mohamed Gamal Mohamed ◽  
Shiao-Wei Kuo ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Microporous Polymers ◽  
Visible Light Driven ◽  
Conjugated Microporous Polymers

Selective adsorption of metronidazole on conjugated microporous polymers

2015 ◽  
Vol 58 (7) ◽  
pp. 1227-1234 ◽  
Author(s):  
Chunli Zheng ◽  
Miaomiao Du ◽  
Fei Li ◽  
Yue Qi ◽  
Jun Yi
Keyword(s):  
Selective Adsorption ◽  
Microporous Polymers ◽  
Conjugated Microporous Polymers

Pyrene-containing conjugated organic microporous polymers for photocatalytic hydrogen evolution from water

2021 ◽  
Author(s):  
Mohamed Gamal Mohamed ◽  
Mohamed Hammad Elsayed ◽  
Ahmed M. Elewa ◽  
Ahmed F. M. EL-Mahdy ◽  
Cheng-Han Yang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
High Stability ◽  
Photocatalytic Hydrogen Evolution ◽  
Microporous Polymers ◽  
Very High ◽  
Conjugated Microporous Polymers ◽  
Production Efficiencies

Pyrene based conjugated microporous polymers (CMPs) as photocatalysts with promising H2 production efficiencies and very high stability.

Structure–property–function relationship of fluorescent conjugated microporous polymers

2021 ◽  
Author(s):  
M. G. Monika Bai ◽  
H. Vignesh Babu ◽  
V. Lakshmi ◽  
M. Rajeswara Rao
Keyword(s):  
Long Range ◽  
Structure Property ◽  
Porous Organic Polymers ◽  
Aggregation Induced Emission ◽  
Microporous Polymers ◽  
Exciton Migration ◽  
Wide Range ◽  
Function Relationship ◽  
Relationship Of ◽  
Conjugated Microporous Polymers

Fluorescent porous organic polymers are a unique class of materials owing to their strong aggregation induced emission, long range exciton migration and permanent porosity, thus envisioned to possess a wide range of applications (sensing, OLEDs).

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