1H NMR and spectrophotometric study of alkaline metal ion complexes with N-dansyl aza-18-crown-6
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AbstractFormation of complexes of A18C6-Dns and metal cations (Ca2+, Sr2+, Ba2+ and Mg2+) in acetonitrile has been studied by NMR, absorption and fluorescence spectroscopy and PM5 semi-empirical methods. A18C6-Dns forms stable complexes with Ca2+, Sr2+ and Ba2+ cations. The stability constants of various complexes are determined by different methods and their structures are visualised by the PM5 semi-empirical calculations.
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2018 ◽
Vol 127
(1A)
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pp. 67
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2008 ◽
Vol 27
(2)
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pp. 157
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1979 ◽
Vol 44
(2)
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pp. 321-327
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