scholarly journals Kinetics of Isothermal Melt Crystallization in CaO-SiO2-CaF2-Based Mold Fluxes

2015 ◽  
Vol 46 (5) ◽  
pp. 2374-2383 ◽  
Author(s):  
Myung-Duk Seo ◽  
Cheng-Bin Shi ◽  
Ji-Yeon Baek ◽  
Jung-Wook Cho ◽  
Seon-Hyo Kim
2017 ◽  
Vol 48 (6) ◽  
pp. 2949-2960 ◽  
Author(s):  
Lejun Zhou ◽  
Huan Li ◽  
Wanlin Wang ◽  
Zhaoyang Wu ◽  
Jie Yu ◽  
...  

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1181 ◽  
Author(s):  
Chunmei Zhang ◽  
Qiaofeng Lan ◽  
Tianliang Zhai ◽  
Shengqiang Nie ◽  
Jun Luo ◽  
...  

Lactide-Caprolactone copolymer (LACL) was added to a Polylactide/Poly(ε-caprolactone) (PLA/PCL) blend as a compatibilizer through solution mixing and the casting method. The melt crystallization behavior and crystalline morphology of PLA, PLA/PCL, and PLA/PCL/LACL were investigated using differential scanning calorimeter (DSC) and polarized optical microscopy (POM), respectively. The temperature of the shortest crystallization time for the samples was observed at 105 °C. The overall isothermal melt crystallization kinetics of the three samples were further studied using the Avrami theory. Neat PLA showed a higher half-time of crystallization than that of the PLA/PCL and PLA/PCL/LACL blends, whereas the half-time of crystallization of PLA/PCL and PLA/PCL/LACL showed no significant difference. The addition of PCL decreased the spherulite size of crystallized PLA, and the nuclei density in the PLA/PCL/LACL blend was much higher than that of the PLA and PLA/PCL samples, indicating that LACL had a compatibilization effect on the immiscible PLA/PCL blend, thereby promoting the nucleation of PLA. The spherulites in the PLA/PCL and PLA/PCL/LACL blend exhibited a smeared and rough morphology, which can be attributed to the fact that PCL molecules migrated to the PLA spherulitic surface during the crystallization of PLA.


2008 ◽  
Vol 53 (2) ◽  
pp. 188-197 ◽  
Author(s):  
Wei Zeng ◽  
JiChun Liu ◽  
JunFeng Zhou ◽  
JinYong Dong ◽  
ShouKe Yan

2004 ◽  
Vol 23 (7) ◽  
pp. 817-826 ◽  
Author(s):  
Nattapol Apiwanthanakorn ◽  
Pitt Supaphol ◽  
Manit Nithitanakul

Polímeros ◽  
2019 ◽  
Vol 29 (1) ◽  
Author(s):  
Anna Raffaela Matos Costa ◽  
Edson Noryuki Ito ◽  
Laura Hecker Cavalho ◽  
Eduardo Luís Canedo

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74486-74498 ◽  
Author(s):  
Swarup Biswas ◽  
Bula Dutta ◽  
Subhratanu Bhattacharya

The dynamic melt crystallization kinetics of polyaniline (PAni)/poly(vinylidene fluoride) (PVDF) blends of different compositions has been investigated to understand the influence of PAni on the heterogeneous nucleation and phase transition of PVDF.


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