High-Temperature Oxidation of Stellite 12 Hardfacings: Effect of Mo on Characteristics of Oxide Scale

2018 ◽  
Vol 28 (1) ◽  
pp. 463-474 ◽  
Author(s):  
Amir Motallebzadeh ◽  
Shaikh Asad Ali Dilawary ◽  
Erdem Atar ◽  
Huseyin Cimenoglu
Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3764
Author(s):  
Krzysztof Aniołek ◽  
Adrian Barylski ◽  
Marian Kupka

High-temperature oxidation was performed at temperatures from 600 to 750 °C over a period of 24 h and 72 h. It was shown in the study that the oxide scale became more homogeneous and covered the entire surface as the oxidation temperature increased. After oxidation over a period of 24 h, the hardness of the produced layers increased as the oxidation temperature increased (from 892.4 to 1146.6 kgf/mm2). During oxidation in a longer time variant (72 h), layers with a higher hardness were obtained (1260 kgf/mm2). Studies on friction and wear characteristics of titanium were conducted using couples with ceramic balls (Al2O3, ZrO2) and with high-carbon steel (100Cr6) balls. The oxide films produced at a temperature range of 600–750 °C led to a reduction of the wear ratio value, with the lowest one obtained in tests with the 100Cr6 steel balls. Frictional contact of Al2O3 balls with an oxidized titanium disc resulted in a reduction of the wear ratio, but only for the oxide scales produced at 600 °C (24 h, 72 h) and 650 °C (24 h). For the ZrO2 balls, an increase in the wear ratio was observed, especially when interacting with the oxide films obtained after high-temperature oxidation at 650 °C or higher temperatures. The increase in wear intensity after titanium oxidation was also observed for the 100Cr6 steel balls.


2020 ◽  
Vol 1010 ◽  
pp. 65-70
Author(s):  
Zahraa Zulnuraini ◽  
Noraziana Parimin

This paper investigates the performance of Fe-33Ni-18Cr alloy at high temperature oxidation. The samples were isothermally oxidized at three different oxidation temperatures, namely, 600 °C, 800 °C and 1000 °C for 150 hours. This alloy was ground by using several grits of SiC paper as well as weighed by using analytical balance and measured by using Vernier caliper before oxidation test. The characterization was carried out using scanning electron microscope (SEM) equipped with energy dispersive x-ray (EDX) and x-ray diffraction (XRD). The results show that, the higher oxidation temperatures, the weight gain of the samples were increase. Sample of 1000 °C indicate more weight gain compared to samples oxidized at 600 °C and 800 °C. The kinetic of oxidation of all samples followed the parabolic rate law. The surface morphology of oxide scale at lower temperature is thin and form a continuous layer, while at high temperature, the oxide scale develops thick layer with angular oxide particles.


2011 ◽  
Vol 312-315 ◽  
pp. 1097-1105
Author(s):  
Hisao Fujikawa

Three studies on the oxidation behaviour of austenitic stainless steels were described in the present paper. (1) High temperature oxidation behaviour and its mechanism in austenitic stainless steels with high silicon: Sulfur contained as impurity in steel showed a harmful influence to the oxidation resistance of 19Cr-13Ni-3.5Si stainless steels. It was found that the abnormal oxidation was caused from the surroundings of MnS inclusions. (2) Effect of a small addition of yttrium on high temperature oxidation resistance of Si-containing austenitic stain less steels: The oxidation resistance of 19Cr-10Ni-1.5Si steels was improved remarkably even with only 0.01%Y addition, which is the same concentration as added for de-oxygenation. Y was enriched at the grain boundary of oxide scale and metal-oxide interface. It was suggested that Y-containing steels shoed good oxidation resistance, because the enriched Y at the grain boundary and metal-oxide interface prevented the diffusion of iron and oxygen ions through the oxide scale. (3) Effect of grain size on the oxidation behaviour of austenitic stainless steels: Type 304, 316 and 310 steels with finer grain size showed better oxidation resistance than those with coarser grain size at 850°C. The oxide scale of steels with coarser grain size easily spalled during the cooling process.


2007 ◽  
Vol 546-549 ◽  
pp. 1489-1494 ◽  
Author(s):  
Ai Qin Liu ◽  
Shu Suo Li ◽  
Lu Sun ◽  
Ya Fang Han

Nb-16Si-24Ti-6Cr-6Al-2Hf-xB(x=0, 0.5, 1, 2, 4, 6) in situ composites were prepared by arc-melting. Microstructure and the effect of boron on 1250C oxidation resistance of the composites were investigated by scanning electron microscopy(SEM) and X-ray energy disperse spectrum(EDS) as well as X-ray diffraction(XRD). The experimental results showed that the high temperature oxidation resistance of the alloy was remarkably improved by adding proper amount of boron. This may be resulted from several beneficial roles of boron, i.e., boron improves the resistance of Nb5Si3 by solid solution strengthening, inhibits the diffusion of oxygen in the matrix, improves the adherence between the oxide scale and the substrate and increases the cracking resistance of the oxide scale.


2013 ◽  
Vol 333 ◽  
pp. 149-155 ◽  
Author(s):  
H. Fujikawa ◽  
Y. Iijima

The effect of grain size on high temperature oxidation behaviour of 316 steels at 700º, 850º and 1000°C in air was studied. The results show that the mass gain increases with the increase of grain size. Particularly, the gradient of mass gain is severe in at lower oxidation temperatures. In the oxidation at temperatures of more than the solid solution temperature, the grain size before the oxidation changed to coarse grain size. Therefore, in this case, it is not enough to estimate the oxidation behaviour by the grain size before the oxidation. The exfoliation of oxide scale is severe in steel with coarse grains. Over 850°C, the exfoliation was observed in 316 steel with coarse grains. At 1000°C, the oxide scale of 316 steel was exfoliated, but it was extreme in the coarse grains. Cr, Mn and Si in the oxide scale were enriched in the oxide scale of the steel with fine grains. Particularly, Si was remarkably enriched at the metal-oxide interface and grain boundaries.


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