scholarly journals High Temperature Oxidation of Metals (2) -Formation of Protective Oxide Scale

1995 ◽  
Vol 44 (7) ◽  
pp. 416-417 ◽  
Author(s):  
Toshio Maruyama
Author(s):  
I. G. Wright ◽  
V. K. Sethi ◽  
V. Nagarajan

The rate of wastage of an alloy surface subjected to erosion under conditions where high-temperature oxidation can occur can be significantly greater than that arising from erosion alone. This is because the erosion conditions can act to accelerate the oxidation process by causing regular shedding of the otherwise protective oxide scale. It is suggested that an important parameter in determining the rate of erosion-oxidation is the erodent flux, since the time available for oxide growth (or regrowth) in a given area is determined by the interval between successive erodent impacts. Using this simple premise, an approach is suggested by which the rate of erosion-oxidation can be related to the factors that control the alloy oxidation process, and those that describe the erosive environment. The assumptions made are examined, and some of the implications of this approach are discussed.


1991 ◽  
Vol 113 (4) ◽  
pp. 616-620 ◽  
Author(s):  
I. G. Wright ◽  
V. K. Sethi ◽  
V. Nagarajan

The rate of wastage of an alloy surface subjected to erosion under conditions where high-temperature oxidation can occur can be significantly greater than that arising from erosion alone. This is because the erosion conditions can act to accelerate the oxidation process by causing regular shedding of the otherwise protective oxide scale. It is suggested that an important parameter in determining the rate of erosion-oxidation is the erodent flux, since the time available for oxide growth (or regrowth) in a given area is determined by the interval between successive erodent impacts. Using this simple premise, an approach is suggested by which the rate of erosion-oxidation can be related to the factors that control the alloy oxidation process, and those that describe the erosive environment. The assumptions made are examined, and some of the implications of this approach are discussed.


2012 ◽  
Vol 557-559 ◽  
pp. 100-107 ◽  
Author(s):  
Akbar Kaderi ◽  
Hanafi Ani Mohd ◽  
Sukreen Hana Herman ◽  
Raihan Othman

Fe - 9 to 12%Cr alloys are a material for the thick sections boiler components and steam lines of a power plant. The role Fe - 9 to 12%Cr alloys is becoming more prominent in the development of a new generation of Ultra-Supercritical (USC) Power Plant due to the target operating temperature is reaching 620 °C (893 K), in 100% steam condition as well as pressure in excess of 300 bar (30 × 106 Pa). In such condition, the integrity of Fe - 9 to 12%Cr alloys relies on the oxide scale formed during the time of exposure. However due to the high temperature and water vapor condition, it is a well known fact that, the formation of oxide scale is accelerated thus depleting the structural integrity of the Fe - 9 to 12%Cr alloys over the time. Studies show that not only the formation of protective oxide scale was suppressed but the formation of non-protective oxide scale was accelerated instead. Decades of studies done by various groups around the globe has yet to have consensual on the exact mechanism of this phenomenon. Initial stage oxidation of these alloys plays great roles in hope to understand the formation of oxide scale in water vapor condition at high temperature. This paper reviews previous research works to understand the initial stage oxidation of Fe - 9 to 12%Cr alloys at high temperature in water vapor condition.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3764
Author(s):  
Krzysztof Aniołek ◽  
Adrian Barylski ◽  
Marian Kupka

High-temperature oxidation was performed at temperatures from 600 to 750 °C over a period of 24 h and 72 h. It was shown in the study that the oxide scale became more homogeneous and covered the entire surface as the oxidation temperature increased. After oxidation over a period of 24 h, the hardness of the produced layers increased as the oxidation temperature increased (from 892.4 to 1146.6 kgf/mm2). During oxidation in a longer time variant (72 h), layers with a higher hardness were obtained (1260 kgf/mm2). Studies on friction and wear characteristics of titanium were conducted using couples with ceramic balls (Al2O3, ZrO2) and with high-carbon steel (100Cr6) balls. The oxide films produced at a temperature range of 600–750 °C led to a reduction of the wear ratio value, with the lowest one obtained in tests with the 100Cr6 steel balls. Frictional contact of Al2O3 balls with an oxidized titanium disc resulted in a reduction of the wear ratio, but only for the oxide scales produced at 600 °C (24 h, 72 h) and 650 °C (24 h). For the ZrO2 balls, an increase in the wear ratio was observed, especially when interacting with the oxide films obtained after high-temperature oxidation at 650 °C or higher temperatures. The increase in wear intensity after titanium oxidation was also observed for the 100Cr6 steel balls.


2018 ◽  
Vol 28 (1) ◽  
pp. 463-474 ◽  
Author(s):  
Amir Motallebzadeh ◽  
Shaikh Asad Ali Dilawary ◽  
Erdem Atar ◽  
Huseyin Cimenoglu

2008 ◽  
Vol 595-598 ◽  
pp. 1127-1134 ◽  
Author(s):  
Frédéric Riffard ◽  
Henri Buscail ◽  
F. Rabaste ◽  
Eric Caudron ◽  
Régis Cueff ◽  
...  

Chromia-forming steels are excellent candidates to resist to high temperature oxidizing atmospheres because they form protective oxide scales. The oxide scale growth mechanisms are studied by exposing AISI 304 stainless steel to high temperature conditions in air, and the analyses were carried out by means of thermogravimetry and in situ X-rays diffraction. The in situ XRD analyses carried out during high temperature AISI 304 steel oxidation in air reveals the accelerated growth of iron-containing oxides such as hematite Fe2O3 and iron-chromite FeCr2O4, when the initial germination of the oxide layer contains the presence of a manganese-containing spinel compound (1000°C). When the initial growth shows the only chromia formation (800°C), hematite formation appears differed in time. Protection against corrosion is thus increased when the initial germination of manganese-containing spinel oxide is inhibited in the oxide scale.


Sign in / Sign up

Export Citation Format

Share Document