Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over Ga2O3-CeO2-ZrO2 catalysts prepared by a single-step sol-gel method: Effect of acidity and basicity of the catalysts

2012 ◽  
Vol 29 (8) ◽  
pp. 1019-1024 ◽  
Author(s):  
Hye Jin Lee ◽  
Wangrae Joe ◽  
Ji Chul Jung ◽  
In Kyu Song
2021 ◽  
Vol 219 (1) ◽  
pp. 233-246
Author(s):  
Jing Yang ◽  
Gaofei Zhang ◽  
Ruifeng Zhang ◽  
Yingming Guo ◽  
Bo Li

2017 ◽  
Vol 42 (26) ◽  
pp. 16459-16475 ◽  
Author(s):  
Wenqing Hou ◽  
Yuqi Wang ◽  
Yukun Bai ◽  
Wen Sun ◽  
Weijian Yuan ◽  
...  

2009 ◽  
Vol 2009 ◽  
pp. 1-8 ◽  
Author(s):  
Nor Hafizah ◽  
Iis Sopyan

NanosizedTiO2powder was synthesized via sol-gel method using titanium tetraisopoxide (TPT) as the precursor. Mol ratios of water to TPT were varied from 1 (Powder A), 2 (Powder B), 3 (Powder C), and 4 (Powder D) to evaluate effect of hydrolysis degree. TG/DTA curves showed that amorphous phase turned to anatase crystal structure at ca. 415, 337, 310, and339∘C for Powders A, B, C, and D, respectively. XRD analysis showed that all the synthesizedTiO2powders were 100% in anatase form with Powders B and C showing considerably higher crystallinities. The powders obtained at lower water to TPT mol ratios were spherical in shape and they became bar-like shapes higher mol ratios. The lower hydrolysis degree led to higher surface area of the Powder A (24.8 m2/g) compared to Powder B (14.6 m2/g). From phenol photocatalytic measurement, Powder B was the most efficient attributed to its higher crystallinity.


Author(s):  
M.Rahim Uddin ◽  
Maksudur R. Khan ◽  
M. Wasikur Rahman ◽  
Chin Kui Cheng ◽  
Abu Yousuf

The present work is a significant approach to explore the photo-conversion of carbon dioxide (CO2) into methanol on Bi2S3/Cds photocatalyst under visible light irradiation. In this perspective, Bi2S3 nanoparticles have been successfully synthesized via corresponding salt and thiourea assisted sol-gel method. An innovative hetero-system Bi2S3/CdS has been proposed to achieve methanol photo evolution and its photocatalytic activities have been investigated.


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