Lignin-derived Zn single atom/N-codoped porous carbon for α-alkylation of aromatic ketones with alcohols via borrowing hydrogen strategy

Nano Research ◽  
2021 ◽  
Author(s):  
Xueping Zhang ◽  
Guo-Ping Lu ◽  
Kun Wang ◽  
Yamei Lin ◽  
Pengcheng Wang ◽  
...  
2021 ◽  
pp. 2103533
Author(s):  
Rui Liu ◽  
Zhichao Gong ◽  
Jianbin Liu ◽  
Juncai Dong ◽  
Jiangwen Liao ◽  
...  

Author(s):  
Lin Gong ◽  
Ji Sun ◽  
Yousong Liu ◽  
Guangcheng Yang

The use of solar energy to drive efficient CO2 cycloaddition conversion under mild reaction conditions is highly desired but remains a significant challenge. In this communication, a Zn single-atoms-loaded N-doped...


2020 ◽  
Vol 8 (19) ◽  
pp. 9981-9990 ◽  
Author(s):  
Cheng Du ◽  
Yijing Gao ◽  
Jianguo Wang ◽  
Wei Chen

A promising “confined recrystallization” method is developed for the fabrication of an Fe single-atom bifunctional catalyst for flexible rechargeable Zn–air batteries.


2020 ◽  
Vol 8 (33) ◽  
pp. 17136-17149 ◽  
Author(s):  
Hong Li ◽  
Kai Du ◽  
Chensheng Xiang ◽  
Pengfei An ◽  
Xinxin Shu ◽  
...  

Porous carbon with Fe-single-atom nanoclusters was obtained for the ORR by controlled chelation between tannic acid and Fe precursors.


2019 ◽  
Vol 7 (46) ◽  
pp. 26358-26363 ◽  
Author(s):  
Yanming Liu ◽  
Qi Xu ◽  
Xinfei Fan ◽  
Xie Quan ◽  
Yan Su ◽  
...  

Co single atom embedded N-doped porous carbon is energy efficient for electrochemical reduction of N2 to NH3 with a high yield.


2020 ◽  
Vol 8 (4) ◽  
pp. 2131-2139 ◽  
Author(s):  
Yanqiu Wang ◽  
Baoying Yu ◽  
Kang Liu ◽  
Xuetao Yang ◽  
Min Liu ◽  
...  

A scalable Co single-atom catalyst was fabricated by a biomass complexation strategy, and exhibits high cycle efficiency in a Zn–air battery.


2021 ◽  
Author(s):  
Won-Gwang Lim ◽  
Cheol-Young Park ◽  
Hyeonjung Jung ◽  
Seoa Kim ◽  
Seok Hun Kang ◽  
...  

Abstract High-energy lithium-sulfur (Li-S) pouch cell are limited by the insufficient capacities and stabilities of their cathodes under practical electrolyte/sulfur (E/S), electrolyte/capacity (E/C), and negative/positive (N/P) ratios. Herein, we fabricated an advanced cathode comprising highly active Fe single atom catalysts (SACs) and porous carbon to attain 361.8 W h kg−1 Li-S pouch cells satisfying low E/S (2.0), E/C (1.9), and N/P (2.3) ratios with high sulfur loadings (8.4 mg cm−2). We designed high-activity Fe SACs by manipulating their local environments using electron exchangeable binding (EEB) sites. Introducing EEB sites composed of two different types of S species, namely, thiophene-like-S and oxidized-S, adjacent to Fe SACs, promoted the kinetics of the Li2S redox reaction by providing additional binding sites and modulating the Fe d-orbital levels via electron exchange with Fe. This desirable cathode electrocatalysis is maximized by the intimate contact of Fe SACs with the S species, confined together into porous carbon.


Author(s):  
Pingbo Li ◽  
Xueqiang Qi ◽  
Lei Zhao ◽  
Junjie Wang ◽  
Meng Wang ◽  
...  

Here, we report a highly efficient ORR electrocatalyst with Fe-N4 active sites uniformly dispersed on a three-dimensional (3D) interconnected porous nitrogen-doped carbon network by pyrolyzing SiO2@ZIF-8 composites loaded with iron...


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