Experimental investigation on low-degree dehydration partial melting of biotite gneiss and phengite-bearing eclogite at 2 GPa

2011 ◽  
Vol 22 (6) ◽  
pp. 677-687 ◽  
Author(s):  
Qiang Liu ◽  
Yao Wu ◽  
Junfeng Zhang
Solid Earth ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 23-36
Author(s):  
Tomoaki Morishita ◽  
Naoto Hirano ◽  
Hirochika Sumino ◽  
Hiroshi Sato ◽  
Tomoyuki Shibata ◽  
...  

Abstract. We present geochemical and 40Ar∕39Ar age data for a peridotite xenolith-bearing basalt dredged from the Seifu Seamount (SSM basalt) in the northeast Tsushima Basin, southwest Sea of Japan. An 40Ar∕39Ar plateau age of 8.33±0.15 Ma (2σ) was obtained for the SSM basalt, indicating that it erupted shortly after the termination of back-arc spreading in the Sea of Japan. The SSM basalt is a high-K to shoshonitic alkali basalt that is characterized by light rare earth element enrichment. The trace element features of the basalt are similar to those of ocean island basalt, although the Yb content is much higher, indicating formation by the low-degree partial melting of spinel peridotite. The Nd, Sr, and Pb isotopic compositions of the SSM basalt differ from those of back-arc basin basalts in the Sea of Japan. The Sr–Nd isotopic composition of the SSM basalt suggests its source was depleted mid-ocean ridge mantle containing an enriched mantle (EM1) component. The SSM basalt was formed in a post-back-arc extension setting by the low-degree partial melting of an upwelling asthenosphere that had previously been associated with the main phase of back-arc magmatism.


2021 ◽  
Author(s):  
Bing Zhao ◽  
Xijun Liu ◽  
Zhenglin Li ◽  
Wenmin Huang ◽  
Chuan Zhao

<p>The Emeishan flood basalts are part of an important large igneous province along the western margin of the Yangtze Block, Southwest China. The western Guangxi region in southwestern China is geologically a part of the Yangtze Block. Mafic rocks, comprising mainly lavas and dykes in western Guangxi belong to the outer part of the ~260 Ma Emeishan Large Igneous Province (ELIP). Here we present a systematic study of platinum-group elements (PGEs) combined with the LA-ICP-MS zircon U–Pb age, whole-rock geochemical and isotopic data of the lavas and dykes in the Longlin area of outer zone of ELIP to constraints on their origin. On the basis of petrography and major elements characteristics, mafic lavas and dykes display an enrichment of LREE, LILE, HFSE, high (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> ratios (0.704227~0.705754), low ε<sub>Nd</sub><sub>(t)</sub> values(0.42~0.99), high ε<sub>Hf</sub><sub>(t)</sub> values(5.19~6.04), they are similar to those of Permian Emeishan high-Ti basalts and Ocean island basalts (OIB) features. The Longlin mafic rocks was formed in the Late Permian with the zircon U-Pb dated age of 256.3± 1.7 Ma. The age of the Longlin mafic rocks is close to the formation age of the ELIP large-scale magmatism, suggesting that these lavas and dykes probably belongs to part of the ELIP large-scale magmatism. The Longlin mafic rocks have low total PGE contents ranging from 1.56×10<sup>-9 </sup>to 2.28×10<sup>-9</sup>, with Os, Ir, Ru, Rh, Pt and Pd contents of 0.040~0.076, 0.046~0.076, 0.027~0.079, 0.037~0.056, 0.6374~1.053 and 0.715~1.021ppb, respectively. They show left-leaning primitive mantle-normalized PGE patterns with depletion in Iridium group(IPGE) and enrichment in Palladium group, which also have lower contents than mafic rocks from the inner zone of the ELIP, suggesting that a low degree of partial melting of the mantle source plays an important role. The Longlin mafic rocks exhibit a marked increase in Cu/Pd ratios (>10<sup>5</sup>,84655 to 174785) albeit with a narrow range of lower Pd/Ir ratios (<50,13.4 to 18.7), different from the PGE-enriched basalts of the Siberian Traps, Emeishan Large Igneous Province (ELIP), East Greenland CFBs and Deccan Traps, indicating that their parent magmas was significantly depleted in chalcophile elements. Calculations based on the available trace element geochemistry reveal that the basalts were originated by low degree of partial melting(<5%),with sulfides remain in the mantle during partial melting. Sulfide segregation could not happen during the evolution of the Longlin mafic rocks, due to the fact that neither significant fractional crystallization nor crustal contamination has been involved in their formation. Overall, mafic rocks from the outer zone of the ELIP show lower PGE contents than those in the inner zones, we find that the PGE contents in igneous rocks are related with the degrees of partial melting in the mantle source and the removal of sulfides before their emplacement.</p><p>This study was financially supported by the Guangxi Natural Science Foundation for Distinguished Young Scholars (2018GXNSFFA281009) and the Fifth Bagui Scholar Innovation Project of Guangxi Province (to XU Ji-feng).</p>


2014 ◽  
Vol 152 (2) ◽  
pp. 210-224 ◽  
Author(s):  
WEN-JUN HU ◽  
HONG ZHONG ◽  
WEI-GUANG ZHU ◽  
XIAO-HU HE

AbstractThe Early Palaeozoic Shuanggou ophiolite is the best-preserved part of the Ailaoshan ophiolite belt. The microgabbros (basaltic dykes) and basalts (basaltic lavas) show distinct characteristics in geochemistry, implying that their genetic mechanisms are different. With Al2O3 contents ranging from 14.7% to 17.0%, the microgabbros belong to low-alumina type. They exhibit normal mid-ocean-ridge basalt (N-MORB) -like trace elemental characteristics with positive εNd(t) values (9.7–11.6) and slightly variable (87Sr/86Sr)i ratios (0.7036–0.7046). In contrast, the basalts have high Al2O3 contents (19.5–23.2%), therefore belonging to high-alumina type. A plagioclase-accumulation model is used to account for the high alumina contents. Moreover, the basalts have enriched MORB (E-MORB) -like trace element characteristics with lower εNd(t) values (6.4–8.0) and (87Sr/86Sr)i ratios (0.7032–0.7036). Their incompatible element ratios exhibit linear correlation with the isotopic data, which is probably related to the contribution of a mixed lithosphere–asthenosphere source. In summary, a two-stage model is proposed to explain the formation of the Shuanggou ophiolite: (1) at the continent–ocean transition stage, the basalts were generated by low-degree partial melting of the mixed mantle near a slow-spreading embryonic centre; and (2) at the mature stage of the Ailaoshan Ocean, the microgabbros were produced by moderate-degree partial melting of the depleted asthenospheric mantle.


2021 ◽  
Author(s):  
◽  
Christopher Edward Conway

<p>The Macquarie Ridge Complex (MRC) forms the submarine expression of the Australia‐Pacific plate boundary south of New Zealand, comprising a rugged bathymetry made up of numerous seamounts along its length. Tectonic plate reconstructions show that the plate boundary evolved from divergent to transpressional relative plate motion from ca. 40 – 6 Ma. However, only limited geological observation of the products of past seafloor spreading and present transpressional deformation has been achieved. This study presents new high-resolution multibeam, photographic, petrologic and geochemical data for 10 seamounts located along the MRC in order to elucidate the current nature and evolution of the plate boundary. Seamounts are oriented parallel to the plate boundary, characterized by elongate forms, and deformed by transform faulting. Three guyot‐type seamounts display summit plateaux that were formed by wave and current erosion. MRC seafloor is composed of alkaline to sub‐alkaline basaltic pillow, massive and sheet lava flows, lava talus, volcaniclastic breccia, diabase and gabbro. This oceanic crust was formed during effusive mid‐ocean ridge volcanism at the relic Macquarie spreading centre and has since been sheared, accreted and exhumed along the modern transpressional plate boundary. Major element systematics indicate samples originated from spatially distinct magmatic sources and have since been juxtaposed at seamounts due to transpressional relative plate motion. MRC seamounts have formed as discrete elevations as a result of dip‐slip and strike‐slip faulting of the ridge axis. Thus, MRC seamounts are volcanic in origin but are now the morphological manifestations of tectonic and geomorphic processes. Petrologic and geochemical characteristics of volcanic glass samples from the MRC indicate that both effusive and explosive eruption styles operated at the relic Macquarie spreading centre. Primitive and sub‐alkaline to transitional basaltic magma that rose efficiently to the seafloor was erupted effusively and cooled to form lava flows with low vesicle and phenocryst contents or was granulated on contact with seawater to form hyaloclasts deposited in volcaniclastic breccias. More alkaline magmas that underwent crystal fractionation and volatile exsolution in shallow reservoirs were fragmented and erupted during submarine hawaiian‐type eruptions. Such a scenario is likely to have occurred during the final stages of magmatism at the Australia‐Pacific plate boundary south of New Zealand when seafloor spreading was ultraslow or had ceased, which induced low degrees of partial melting and retarded magma ascent rates. All MRC samples display enriched mid‐ocean ridge basalt (E‐MORB) trace element characteristics. The sample suite can be divided into two groups, with Group 1 samples distinguished from Group 2 samples by their lower concentrations of highly incompatible trace elements, flatter LREE slopes, higher MgO contents and lower alkali element contents. Group 1 basalts were derived from low degree partial melting of spinel lherzolite generated during the late stages of mid‐ocean ridge volcanism at the plate boundary when seafloor spreading rates were slow to ultraslow (full spreading rate < 20 mm yr⁻¹). Group 2 basalts were derived from low degree partial melting of spinel lherzolite, mixed with small amounts of very low degree partial melting of garnet lherzolite, during post‐spreading volcanism at the MRC. Remnant heat from previous seafloor spreading induced buoyant ascent of the sub‐ridge mantle and enriched heterogeneities were preferentially tapped by the ensuing low melt fractions. Magma ascent was stalled due to the cessation of extension at the ridge and the melts underwent crystal fractionation prior to eruption, which accounts for the lower MgO contents of Group 2 basalts. The pervasive incompatible element‐enrichment of MRC basalts and similarity to lavas from fossil spreading ridges in the eastern Pacific Ocean may reflect regional enrichment of the Pacific upper mantle.</p>


2009 ◽  
Vol 73 (5) ◽  
pp. 797-816 ◽  
Author(s):  
F. Kaminsky ◽  
R. Wirth ◽  
S. Matsyuk ◽  
A. Schreiber ◽  
R. Thomas

AbstractNyerereite and nahcolite have been identified as micro- and nano-inclusions in diamond from the Juina area, Brazil. Alongside them are Sr- and Ba-bearing calcite minerals from the periclase-wiistite series, wollastonite II (high), Ca-rich garnet, spinels, olivine, phlogopite and apatite. Minerals of the periclase- wustite series belong to two separate groups: wustite and Mg-wustite with Mg# = 1.9—15.3, and Fe- periclase and periclase with Mg# = 84.9—92.1. Wollastonite-II (high, with Ca:Si = 0.992) has a triclinic structure. Two types of spinel were distinguished among mineral inclusions in diamond: zoned magnesioferrite (with Mg# varying from 13.5—90.8, core to rim) and Fe spinel (magnetite). Olivine (Mg# = 93.6), intergrown with nyerereite, forms an elongate, lath-shaped crystal and most likely represents a retrograde transformation of ringwoodite or wadsleyite. All inclusions are composed of poly-mineralic solid mineral phases. Together with previously found halides, sulphates and other mineral inclusions in diamond from Juina, they form a carbonatitic-type mineral paragenesis in diamond which may have originated in the lower mantle and/or transition zone. Wustite inclusions with Mg# = 1.9—3.4, according to experimental data, may have formed in the lowermost mantle. The source for the observed carbonatitic-type mineral association in diamond is lower-mantle natrocarbonatitic magma. This magma may represent a juvenile mantle melt, or be the result of low-degree partial melting of deeply-subducted carbonated oceanic crust. This magma was rich in volatiles, such as Cl, F and H, which played an important role in the formation of diamond.


2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
Abdel-Aal M. Abdel-Karim ◽  
El-Nuri M. Ramadan ◽  
Mohamed R. Embashi

Al-Haruj basalts that represent the largest volcanic province in Libya consist of four lava flow phases of varying thicknesses, extensions, and dating. Their eruption is generally controlled by the larger Afro-Arabian rift system. The flow phases range from olivine rich and/or olivine dolerites to olivine and/or normal basalts that consist mainly of variable olivine, clinopyroxene, plagioclase, and glass. Olivine, plagioclase, and clinopyroxene form abundant porphyritic crystals. In olivine-rich basalt and olivine basalt, these minerals occur as glomerophyric or seriate clusters of an individual mineral or group of minerals. Groundmass textures are variably intergranular, intersertal, vitrophyric, and flow. The pyroclastic, clastogenic flows and/or ejecta of the volcanic cones show porphyritic, vitrophric, pilotaxitic, and vesicular textures. They are classified into tholeiite, alkaline, and olivine basalts. Three main groups are recorded. Basalts of phase 1 are generated from tholeiitic to alkaline magma, while those of phases 3 and 4 are derived from alkaline magma. It is proposed that the tholeiitic basalts represent prerift stage magma generated by higher degree of partial melting (2.0–3.5%) of garnet-peridotite asthenospheric mantle source, at shallow depth, whereas the dominant alkaline basalts may represent the rift stage magma formed by low degree of partial melting (0.7–1.5%) and high fractionation of the same source, at greater depth in an intra-continental plate with OIB affinity. The melt generation could be also attributed to lithosphere extension associated with passive rise of variable enriched mantle.


2021 ◽  
Author(s):  
Alexis Plunder ◽  
Eric Gloaguen ◽  
Saskia Erdmann ◽  
Fabrice Gaillard ◽  
Josselyn Garde ◽  
...  

&lt;p&gt;Rare metal (HFSE such Sn, W, Ta, Nb and LILLE such Li, Rb) granite represent the most enriched magmatic rocks on Earth. This is especially true for some elements that belongs either to the European list of critical raw materials and/or the conflict minerals (eg. Li, Sn, W, Nb, Ta). Rare metal granites generally emplace in the vincinity of S-type granites during late orogenic stages. The fraction crystallisation mechanism is postulated to be the unique way to produce enriched silicate melt that later leads to ore deposits due to a combination of magmatic/hydrothermal processes. However, some problems persist in the explanation of the genesis of rare metal granite: crystal fractionation alone does not lead to the very high rare metal concentrations; field discrepancies exist between rare metal granites and their supposed parent peraluminous granites that in some cases are unknown. An alternative model - based on the integration of geochemical, experimental, paleogeographical and structural studies &amp;#8211; suggests that low degree partial melting could be an efficient mechanism to produce critical metals enriched silicate melts enriched. To test whether this hypothesis makes sense, we present a study of the behaviour of W, Sn, Nb and Ta in metamorphic minerals from various metapelitic rocks. The selected samples do not present anomalous bulk concentrations of these elements with respect to an average continental crust. They formed at different pressure temperature conditions, in different orogenic belts. The rock collection comprises (i) amphibolite-facies staurolite bearing rocks, (ii) sillimanite-bearing rocks and (iii) granulite-facies orthopyroxene-bearing rocks. These samples represent the three main stages of the classical evolution of a collisional gradient leading to partial melting: they respectively belong to the muscovite + biotite domain, the muscovite-out reaction and the biotite-out reaction. We first estimate pressure-temperature conditions of formation of the rocks using pseudosection modelling. We then expose a set of LA-ICP-MS data to identify the critical metal carriers minerals in our samples. Meanwhile, we investigate the behaviour of W, Sn, Nb and Ta during the muscovite out reaction with two piston cylinder experiments (a partial melting experiment and a crystallization experiment). The protolith consists of a staurolite-bearing metapelite that did not suffer partial melting. In the light of these new data, we discuss the framework of the production of critical metal enriched silicate melts. We show that the main carrier of W is muscovite (up to 30 ppm) and that biotite handle Sn at high temperature (up to 40ppm). Using both the data from the natural sample and the experiments, we highlight that muscovite releases W during its destabilisation ant that Sn enters in biotite until the mineral breaks. We finally discuss the implication of multiple low degree partial melting / melt extraction as efficient way to produce enriched silicate melts.&lt;/p&gt;


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