Evolution and Li Mineralization of the No. 134 Pegmatite in the Jiajika Rare-Metal Deposit, Western Sichuan, China: Constrains from Critical Minerals

The Jiajika rare-metal deposit located in western Sichuan Province (China) is renowned as the largest lithium deposit in Asia, and the No. 134 pegmatite dike is the largest lithium pegmatite under mining conditions in the area. On the basis of a detailed characterization of textures and minerals in the Jiajika No. 134 pegmatite, two zones (the barren Zone Ⅰ and the spodumene Zone Ⅱ) and three subzones (Zone Ⅱ was subdivided into microcrystalline, medium-fine grained and coarse-grained spodumene zones) have been identified. The detailed mineralogical characteristics of lithium minerals and other indicator minerals from each zone were evaluated by EPMA for illustrating the magmatic–hydrothermal evolution and the cooling path of the Jiajika No. 134 pegmatite. From the outer zone inwards, grain size gradually increased, the typical graphic pegmatite zone was absent, and spodumene randomly crystallized throughout nearly the whole pegmatite body. This evidence indicated a Li-saturated melt prior to pegmatite crystallization, which could be the main cause of the super-large-scale Li mineralization of the Jiajika No. 134 pegmatite. A comparison of the Cs content between primary beryl in the Jiajika No. 134 pegmatite and other important Li-Cs-Ta pegmatites in the world indicates that No. 134 pegmatite shows a high degree of fractional crystallization. The evolution of mica species from muscovite to Li-micas from Zone Ⅰ to Zone Ⅱ marks the transition from the magmatic to the hydrothermal stage in pegmatite evolution. The absence of individual lepidolite and the relatively limited scale of alteration of spodumene (<10 vol%) suggest that the activity of the hydrothermal fluids in the system is limited, which contributes to the preservation of the easily altered Li ores and is also an important controlling factor of the super-large-scale Li mineralization of the pegmatite. Spodumene–quartz intergrowth (SQI) usually occurs partly along the rims of the spodumene grains in the Jiajika No. 134 pegmatite. Combined with the pegmatite mineral equilibria, the results of fluid inclusion studies of the pegmatite and the metamorphic conditions in the area, a constrained P-T path of the magmatic–hydrothermal crystallization of the Jiajika No. 134 pegmatite is proposed. The unusual steeply sloped cooling path of the No. 134 pegmatite could be attributed to the fast pressure drop triggered by the intrusion of a pegmatitic melt along the fractures surrounding the Majingzi granite, which could also be the dominant evolution process for other spodumene pegmatites with similar SQI features in the world. The feature of limited internal geochemical fractionation suggested by mineral-scale geochemical analyses of spodumene and micas, combined with the clear textural zoning of the No. 134 pegmatite, can best be ascribed to the effect of undercooling during pegmatite formation. This effect might be one of the non-negligible rules of pegmatite petrogenesis, and would significantly upgrade the potential of Li mineralization by minimizing diffusional Li transfer to the country rocks.

Peculiarities of Stratigraphic Distribution and Paleoecology of Jurassic Bivalve Mollusks of the Pre-Сarpathian Foredeep

Pre-Carpathian region is one of the oldest oil and gas producing regions of our country, which is attracting more and more attention of scientists. In the Outer zone of the Pre-Carpathian Foredeep, Jurassic deposits occur at considerable depths (up to 3,000 m), so we obtain almost all geological information about them exclusively during the study of core material selected during drilling. A comprehensive and detailed study of the Jurassic deposits of this zone during exploration drilling in the 1950s contributed to the discovery of the Kokhanivske and Sudovovyshnianske oil deposits and Rudkivske gas deposit, as well as a number of oil and gas manifestations. After that, the interest in the conditions of formation and stratification of Jurassic deposits increased. Researchers have begun to treat them as the promising objects for oil and gas exploration. Jurassic deposits in the Pre-Сarpathian Foredeep fill a single depression – the Stryi Jurassic deflection, covered by a thick layer of Cretaceous and Neogene rocks. The study of their geology and stratigraphy has acquired important applied and scientific significance, because stratigraphic research serves as a basis for clarifying the history of geological development of the region, performing tectonic constructions, reconstruction of paleogeographic and paleoecological conditions, comparison of productive horizons and specification of their stratigraphic position, search for new objects promising for hydrocarbons. Extremely rare finds of paleontological remains (which are not always well preserved) do not allow to unambiguously determining the age of the host rocks. It is still not always possible to clearly stratigraphically distinguish and correlate these rocks due to weak paleontological study and partial uncertainty in the interpretation of the geological structure of these strata. Despite the significant amount of research we have done, there are some debatable issues regarding the completeness of the section of these rocks and the presence of separate stratigraphic units in them. For many years, we have studied in detail and comprehensively bivalve mollusks found in the core of wells drilled in the Outer zone of the Pre-Carpathian Foredeep. As a result, the age of the host strata was specified and confirmed, as well as the thickness of individual stratigraphic units.

The effect of various fluoride products on dentine lesions during pH-cycling

This study compared the effect of topically applied fluoride products on dentine lesions in an in vitro experiment. Demineralized bovine dentine specimens were treated once with either SDF solution (35,400 ppm F), NaF varnish (22,600 ppm F), TiF4 solution (9,200 ppm F), SnF2 gel (1,000 ppm F), no treatment (control) or preserved as baseline lesions. After the application and subsequent removal of the fluoride products, the specimens were subjected to pH-cycling. Calcium loss and uptake in the de- and remineralization buffers were assessed daily. Fluoride release into the buffers was analyzed on day 1, 2, 3, 5, 8 and 13. After the pH-cycling period, mineral distribution throughout the lesion depth was analyzed using transversal microradiography (TMR). X-ray energy-dispersive spectroscopy (EDS) examined the deposition of silver, titanium and tin after application of SDF, TiF4, and SnF2, respectively. Overall, calcium loss and uptake analysis in the de- and remineralization buffers revealed that the SDF product was the most effective in inhibiting lesion progression, followed by the TiF4, NaF, and SnF2 products. Fluoride analysis disclosed a steep reduction of the amount of fluoride released into de- and remineralization buffers with time. The fluoride effects on de- and remineralization continued beyond the days that fluoride was released into the buffers. TMR analysis showed significant remineralization in the outer zone of the dentine lesions for all fluoride products, with SDF giving hyper-mineralization in this zone. In the inner zone, lesions developed in all fluoride groups, with the smallest in the SDF group. EDS showed silver and titanium deposition in depth up to 85 μm and 8 μm, respectively, while no tin deposition was observed. The silver in the dentine lesions did not contribute significantly to the density of the TMR profiles in the SDF group. In conclusion, all topical fluoride products protected the dentine lesions against lesion progression, but at different degrees. SDF showed a superior effect in protection against further demineralization and enhancement of remineralization. This was probably attributed to its fluoride concentration that was the highest among the fluoride products.

Improvement in the Resistance to Wear of Work-Rolls Used in Finishing Stands of the Hot Strip Mills

Work-rolls manufactured through the Indefinite Chill Double Poured (ICDP) method present an exterior work layer manufactured in a martensitic white cast iron alloyed with 4.5 %Ni, 1.7 %Cr, and 0.7 %Nb (wt.%). In its microstructure, there are abundant carbides of the type M3C and MC, which give high resistance to wear, and graphite particles which improve the service behaviour of the rolls against thermal cycling. The core of the rolls is manufactured in grey cast iron of pearlitic matrix and spheroidal graphite. These work-rolls are used in the finishing stands in Hot Strip Mills for rolling slabs proceeding from continuous casting at 1200 °C. Through the application of a Design of Experiments (DoE), an attempt has been made to identify those manufacturing factors which have a significant effect on resistance to wear of these rolls and to find an optimal combination of levels of these factors which allow for improvement in resistance to wear. To increase resistance to wear, it is recommended to situate, simultaneously, the liquidus temperature and the percentage of Si in the respective ranges of 1250–1255 °C and 1.1–1.15 (wt.%). Higher liquidus temperatures favour the presence of the pro-eutectic constituent rather than the eutectic constituent. The outer zone of the work layer, in contact with the metal sheet, which is being rolled, does not show the graphitising effect of Si (0.8–1.15 wt.%). On the contrary, it confirms the hardening effect of the Si in solid solution of the ferrite. The addition of 0.02% of Mg (wt.%) and the inoculation of 6 kg/T of FeB tend to eliminate the graphitising effect of the Si, thus favouring that the undissolved carbon in the austenite is found to form carbides in contrast to the majority formation of graphite.

Testing Hypoxia in Pig Meniscal Culture: Biological Role of the Vascular-Related Factors in the Differentiation and Viability of Neonatal Meniscus

Menisci play an essential role in shock absorption, joint stability, load resistance and its transmission thanks to their conformation. Adult menisci can be divided in three zones based on the vascularization: an avascular inner zone with no blood supply, a fully vascularized outer zone, and an intermediate zone. This organization, in addition to the incomplete knowledge about meniscal biology, composition, and gene expression, makes meniscal regeneration still one of the major challenges both in orthopedics and in tissue engineering. To overcome this issue, we aimed to investigate the role of hypoxia in the differentiation of the three anatomical areas of newborn piglet menisci (anterior horn (A), central body (C), and posterior horn (P)) and its effects on vascular factors. After sample collection, menisci were divided in A, C, P, and they were cultured in vitro under hypoxic (1% O2) and normoxic (21% O2) conditions at four different experimental time points (T0 = day of explant; T7 = day 7; T10 = day 10; T14 = day 14); samples were then evaluated through immune, histological, and molecular analyses, cell morpho-functional characteristics; with particular focus on matrix composition and expression of vascular factors. It was observed that hypoxia retained the initial phenotype of cells and induced extracellular matrix production resembling a mature tissue. Hypoxia also modulated the expression of angiogenic factors, especially in the early phase of the study. Thus, we observed that hypoxia contributes to the fibro-chondrogenic differentiation with the involvement of angiogenic factors, especially in the posterior horn, which corresponds to the predominant weight-bearing portion.

Wave–particle interaction effects in the Van Allen belts

Discovering such structures as the third radiation belt (or “storage ring”) has been a major observational achievement of the NASA Radiation Belt Storm Probes program (renamed the “Van Allen Probes” mission in November 2012). A goal of that program was to understand more thoroughly how high-energy electrons are accelerated deep inside the radiation belts—and ultimately lost—due to various wave–particle interactions. Van Allen Probes studies have demonstrated that electrons ranging up to 10 megaelectron volts (MeV) or more can be produced over broad regions of the outer Van Allen zone on timescales as short as a few minutes. The key to such rapid acceleration is the interaction of “seed” populations of ~ 10–200 keV electrons (and subsequently higher energies) with electromagnetic waves in the lower band (whistler-mode) chorus frequency range. Van Allen Probes data show that “source” electrons (in a typical energy range of one to a few tens of keV energy) produced by magnetospheric substorms play a crucial role in feeding free energy into the chorus waves in the outer zone. These chorus waves then, in turn, rapidly heat and accelerate the tens to hundreds of keV seed electrons injected by substorms to much higher energies. Hence, we often see that geomagnetic activity driven by strong solar storms (coronal mass ejections, or CMEs) commonly leads to ultra-relativistic electron production through the intermediary step of waves produced during intense magnetospheric substorms. More generally, wave–particle interactions are of fundamental importance over a broad range of energies and in virtually all regions of the magnetosphere. We provide a summary of many of the wave modes and particle interactions that have been studied in recent times.

Dry wear behavior of A356-SiCp functionally graded composite in unidirectional and reciprocating contacts

Purpose The purpose of this study is to distinguish the difference in tribological behavior of functionally graded composites in two sliding modes, namely, unidirectional and reciprocating. Design/methodology/approach A356-(10 Wt.%)SiCp functionally graded composite material (FGM) was prepared by vertical centrifugal casting and then a comparison was made between the tribological characteristics using pin-on-disk and pin-on-reciprocating plate configurations under identical operating conditions (sliding distance (s): 350 m; load (W): 30 = W = 120 N, in steps of 30 N; and velocity (v): 0.2 = v = 1.2 m/s, in steps of 0.2 m/s). Two types of test pins were considered, namely, a test pin taken from the outer zone of the FGM with maximum particle concentration and a test pin taken from the inner zone of the FGM in a matrix-rich region. Findings The study revealed that, for the test pin taken from the outer zone of the FGM in the low-velocity range (0.2–0.4 m/s), the reciprocating wear of the friction pair was dominant, while unidirectional wear was dominant in the velocity range of 0.6–0.8 m/s for the entire load range investigated. However, when the velocity was increased from 1.0 to 1.2 m/s, conflicting nature of dominancy in the wear characteristics of the friction pair was observed, depending on the loading condition. In addition, the inner zone FGM pin underwent seizure in the reciprocating mode, whereas this phenomenon was not seen in the unidirectional mode. Originality/value Differences in wear and friction characteristics of FGM friction pairs in two different sliding modes were investigated over a wide range of operating parameters.

Selection of Highly Proliferative and Multipotent Meniscus Progenitors through Differential Adhesion to Fibronectin: A Novel Approach in Meniscus Tissue Engineering

Meniscus injuries can be highly debilitating and lead to knee osteoarthritis. Progenitor cells from the meniscus could be a superior cell type for meniscus repair and tissue-engineering. The purpose of this study is to characterize meniscus progenitor cells isolated by differential adhesion to fibronectin (FN-prog). Human osteoarthritic menisci were digested, and FN-prog were selected by differential adhesion to fibronectin. Multilineage differentiation, population doubling time, colony formation, and MSC surface markers were assessed in the FN-prog and the total meniscus population (Men). Colony formation was compared between outer and inner zone meniscus digest. Chondrogenic pellet cultures were performed for redifferentiation. FN-prog demonstrated multipotency. The outer zone FN-prog formed more colonies than the inner zone FN-prog. FN-prog displayed more colony formation and a higher proliferation rate than Men. FN-prog redifferentiated in pellet culture and mostly adhered to the MSC surface marker profile, except for HLA-DR receptor expression. This is the first study that demonstrates differential adhesion to fibronectin for the isolation of a progenitor-like population from the meniscus. The high proliferation rates and ability to form meniscus extracellular matrix upon redifferentiation, together with the broad availability of osteoarthritis meniscus tissue, make FN-prog a promising cell type for clinical translation in meniscus tissue-engineering.