Thermochemical Transformation of Residual Avocado Seeds: Torrefaction and Carbonization

2016 ◽  
Vol 8 (7) ◽  
pp. 2495-2510 ◽  
Author(s):  
F. Sánchez ◽  
K. Araus ◽  
M. P. Domínguez ◽  
G. San Miguel
Processes ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 30
Author(s):  
María González Martínez ◽  
Estéban Hélias ◽  
Gilles Ratel ◽  
Sébastien Thiéry ◽  
Thierry Melkior

Biomass preheating in torrefaction at an industrial scale is possible through a direct contact with the hot gases released. However, their high water-content implies introducing moisture (around 20% v/v) in the torrefaction atmosphere, which may impact biomass thermochemical transformation. In this work, this situation was investigated for wheat straw, beech wood and pine forest residue in torrefaction in two complementary experimental devices. Firstly, experiments in chemical regime carried out in a thermogravimetric analyzer (TGA) showed that biomass degradation started from lower temperatures and was faster under a moist atmosphere (20% v/v water content) for all biomass samples. This suggests that moisture might promote biomass components’ degradation reactions from lower temperatures than those observed under a dry atmosphere. Furthermore, biomass inorganic composition might play a role in the extent of biomass degradation in torrefaction in the presence of moisture. Secondly, torrefaction experiments on a lab-scale device made possible to assess the influence of temperature and residence time under dry and 100% moist atmosphere. In this case, the difference in solid mass loss between dry and moist torrefaction was only significant for wheat straw. Globally, an effect of water vapor on biomass transformation through torrefaction was observed (maximum 10%db), which appeared to be dependent on the biomass type and composition.


2012 ◽  
Vol 27 (1) ◽  
pp. 285-293 ◽  
Author(s):  
Jun Hu ◽  
Dekui Shen ◽  
Rui Xiao ◽  
Shiliang Wu ◽  
Huiyan Zhang

2020 ◽  
Vol 49 (9) ◽  
pp. 2811-2818
Author(s):  
Guangyong Shi ◽  
Wei Xu ◽  
Jichao Wang ◽  
Nikom Klomkliang ◽  
Bibimaryam Mousavi ◽  
...  

An environmentally friendly and economical route for the synthesis of zeolitic imidazole frameworks (ZIFs) was developed based on the thermal treatment of mixed solid precursors in the absence of solvent and additive compounds.


2008 ◽  
Vol 343 (5) ◽  
pp. 848-854 ◽  
Author(s):  
Masahide Sasaki ◽  
Kenji Takahashi ◽  
Yui Haneda ◽  
Hiroe Satoh ◽  
Akiyoshi Sasaki ◽  
...  

BioFactors ◽  
2000 ◽  
Vol 13 (1-4) ◽  
pp. 257-263 ◽  
Author(s):  
Hiroyuki Nishimura ◽  
Tomonari Takahashi ◽  
C. Hanny Wijaya ◽  
Atsushi Satoh ◽  
Toyohiko Ariga

2011 ◽  
Vol 134 (1) ◽  
Author(s):  
Sophia Haussener ◽  
Iwan Jerjen ◽  
Peter Wyss ◽  
Aldo Steinfeld

The effective heat and mass transport properties of a porous packed bed of particles undergoing a high-temperature solid–gas thermochemical transformation are determined. The exact 3D geometry of the reacting porous media is obtained by high-resolution computed tomography. Finite volume techniques are applied to solve the governing conservation equations at the pore-level scale and to determine the effective transport properties as a function of the reaction extent, namely, the convective heat transfer coefficient, permeability, Dupuit–Forchheimer coefficient, tortuosity, and residence time distributions. These exhibit strong dependence on the bed morphological properties (e.g., porosity, specific surface area, particle size) and, consequently, vary with time as the reaction progresses.


2010 ◽  
Vol 132 (6) ◽  
Author(s):  
Sophia Haussener ◽  
Wojciech Lipiński ◽  
Peter Wyss ◽  
Aldo Steinfeld

A reacting packed-bed undergoing a high-temperature thermochemical solid-gas transformation is considered. The steam- and dry-gasification of carbonaceous materials to syngas is selected as the model reaction. The exact 3D digital geometrical representation of the packed-bed is obtained by computer tomography and used in direct pore-level simulations to characterize its morphological and radiative transport properties as a function of the reaction extent. Two-point correlation functions and mathematical morphology operations are applied to calculate porosities, specific surfaces, particle-size distributions, and representative elementary volumes. The collision-based Monte Carlo method is applied to determine the probability distribution of attenuation path length and direction of incidence at the solid-fluid boundary, which are linked to the extinction coefficient, scattering phase function, and scattering albedo. These effective properties can be then incorporated in continuum models of the reacting packed-bed.


Author(s):  
Kenichi Yakushido ◽  
Yuichi Kobayashi ◽  
Hitoshi Kato

Molecules ◽  
2020 ◽  
Vol 25 (14) ◽  
pp. 3167
Author(s):  
Sheng Cheng ◽  
Tao Chen ◽  
Wenbin Xu ◽  
Jian Huang ◽  
Shaojun Jiang ◽  
...  

Soil contamination by heavy metals threatens the quality of agricultural products and human health, so it is necessary to choose certain economic and effective remediation techniques to control the continuous deterioration of land quality. This paper is intended to present an overview on the application of biochar as an addition to the remediation of heavy-metal-contaminated soil, in terms of its preparation technologies and performance characteristics, remediation mechanisms and effects, and impacts on heavy metal bioavailability. Biochar is a carbon-neutral or carbon-negative product produced by the thermochemical transformation of plant- and animal-based biomass. Biochar shows numerous advantages in increasing soil pH value and organic carbon content, improving soil water-holding capacity, reducing the available fraction of heavy metals, increasing agricultural crop yield and inhibiting the uptake and accumulation of heavy metals. Different conditions, such as biomass type, pyrolysis temperature, heating rate and residence time are the pivotal factors governing the performance characteristics of biochar. Affected by the pH value and dissolved organic carbon and ash content of biochar, the interaction mechanisms between biochar and heavy metals mainly includes complexation, reduction, cation exchange, electrostatic attraction and precipitation. Finally, the potential risks of in-situ remediation strategy of biochar are expounded upon, which provides the directions for future research to ensure the safe production and sustainable utilization of biochar.


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