Isothermal cold crystallization kinetics and properties of thermoformed poly(lactic acid) composites: effects of talc, calcium carbonate, cassava starch and silane coupling agents

2020 ◽  
Vol 29 (2) ◽  
pp. 103-116 ◽  
Author(s):  
Chutimar Deetuam ◽  
Chavakorn Samthong ◽  
Suphattra Choksriwichit ◽  
Anongnat Somwangthanaroj
Keyword(s):  
Lactic Acid ◽  
Calcium Carbonate ◽  
Crystallization Kinetics ◽  
Cassava Starch ◽  
Cold Crystallization ◽  
Coupling Agents ◽  
Poly Lactic Acid ◽  
Silane Coupling Agents ◽  
Silane Coupling

scholarly journals Nonisothermal Cold Crystallization Kinetics of Poly(lactic acid)/Bacterial Poly(hydroxyoctanoate) (PHO)/Talc

2019 ◽  
Vol 17 (1) ◽  
pp. 1266-1278
Author(s):  
Omaima Alhaddad ◽  
Safaa H. El-Taweel ◽  
Yasser Elbahloul
Keyword(s):  
Thermal Stability ◽  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Crystallization Rate ◽  
Cold Crystallization ◽  
Poly Lactic Acid ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Kinetics Of ◽  
Thermal Stability Of

AbstractThe effects of bacterial poly(hydroxyoctanoate) (PHO) and talc on the nonisothermal cold crystallization behaviours of poly(lactic acid) (PLA) were analysed with differential scanning calorimetry (DSC), and the thermal stability of the samples was observed with thermal gravimetric analysis (TGA). The modified Avrami’s model was used to describe the nonisothermal cold crystallization kinetics of neat PLA and its blends. The activation energies E for nonisothermal cold crystallization were calculated by the isoconversional method of Kissinger-Akahira-Sunose (KAS). The DSC results showed that the PLA/PHO blends were immiscible in the whole studied range, and as the PHO and talc content increased, the crystallization rate of PLA accelerated, and the crystallinity of PLA in the PLA samples increased. The values of the Avrami exponent indicated that the nonisothermal cold crystallization of the neat PLA and its blends exhibited heterogeneous, three-dimensional spherulitic growth. The E values were strongly dependent on PHO and talc. The TGA results showed that the presence of PHO and talc slightly influenced the thermal stability of PLA.

Isothermal cold crystallization kinetics of borassus powder/poly(lactic acid) biocomposites

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Yogesh Nana Marathe ◽  
Chellaswamy Ramesh ◽  
Manohar Virupax Badiger
Keyword(s):  
Lactic Acid ◽  
Crystallization Kinetics ◽  
Cold Crystallization ◽  
Poly Lactic Acid ◽  
Kinetics Of

Functionalization of Porous Clay Heterostructures with Silane Coupling Agents

2017 ◽  
Vol 54 (2) ◽  
pp. 341-344
Author(s):  
Anda Ionelia Mihai (Voicu) ◽  
Sorina Alexandra Garea ◽  
Eugeniu Vasile ◽  
Cristina Lavinia Nistor ◽  
Horia Iovu
Keyword(s):  
Pore Volume ◽  
Total Pore Volume ◽  
Coupling Agents ◽  
Silane Coupling Agents ◽  
Porous Clay Heterostructures ◽  
Bet Analysis ◽  
Silane Coupling ◽  
Ftir Spectrometry ◽  
Textural Parameters ◽  
Epoxy Groups

The goal of this paper was to study the modification of porous clay heterostructures (PCHs) with various silane coupling agents. Two commercial coupling agents (3-aminopropyl-triethoxysilane (APTES) and 3-glycidoxypropyl-trimethoxysilane (GPTMS)) with different functional groups (amine and epoxy groups) were used as modifying agents for the PCHs functionalization. The functionalization of PCH with APTES and GPTMS was evaluated by Fourier transform infrared (FTIR) spectrometry, thermogravimetric analysis (TGA), X-Ray Diffractions (XRD) and BET Analysis. FTIR spectra of modified PCHs confirmed the presence of characteristic peaks of silane coupling agents. TGA results highlighted an increase of weight loss for the modified PCHs that was assigned to the degradation of silane coupling agents (APTES and GPTMS) attached to the PCHs. The XRD results showed that the structure of modified PCHs was influenced by the type of the silane coupling agent. The functionalization of PCHs with silane coupling agents was also confirmed by BET analysis. Textural parameters (specific surface area (SBET), total pore volume (Vt )) suggested that the modified PCHs exhibit lower values of SBET and a significant decrease of total pore volume than unmodified PCHs.

Selection and Optimization of Silane Coupling Agents to Develop Durable Functional Cotton Fabrics Using TiO2 Nanoparticles

2021 ◽  
Vol 22 (1) ◽  
pp. 109-122
Author(s):  
S. Riaz ◽  
M. Ashraf ◽  
T. Hussain ◽  
M. T. Hussain ◽  
A. Younus ◽  
...  
Keyword(s):  
Tio2 Nanoparticles ◽  
Cotton Fabrics ◽  
Coupling Agents ◽  
Silane Coupling Agents ◽  
Silane Coupling

Effect of Silane Coupling Agents on Flowability and Compressibility of the Compound for Bonded NdFeB Magnet

2021 ◽  
Author(s):  
Xiaowei Zhang ◽  
Zilong Wang ◽  
Tianhao Li ◽  
Shengjie Zhu ◽  
Dunbo Yu ◽  
...  
Keyword(s):  
Coupling Agents ◽  
Silane Coupling Agents ◽  
Ndfeb Magnet ◽  
Silane Coupling
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