scholarly journals Two-Dimensional Black Phosphorus: An Emerging Anode Material for Lithium-Ion Batteries

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
JiPing Zhu ◽  
GuangShun Xiao ◽  
XiuXiu Zuo

AbstractTwo-dimensional black phosphorus (2D BP), an emerging material, has aroused tremendous interest once discovered. This is due to the fact that it integrates unprecedented properties of other 2D materials, such as tunable bandgap structures, outstanding electrochemical properties, anisotropic mechanical, thermodynamic, and photoelectric properties, making it of great research value in many fields. The emergence of 2D BP has greatly promoted the development of electrochemical energy storage devices, especially lithium-ion batteries. However, in the application of 2D BP, there are still some problems to be solved urgently, such as the difficulty in the synthesis of large-scale high-quality phosphorene, poor environmental stability, and the volume expansion as electrode materials. Herein, according to the latest research progress of 2D BP in the field of energy storage, we systematically summarize and compare the preparation methods of phosphorene and discuss the basic structure and properties of BP, especially the environmental instability and passivation techniques. In particular, the practical application and challenges of 2D BP as anode material for lithium-ion batteries are analyzed in detail. Finally, some personal perspectives on the future development and challenges of BP are presented.

2020 ◽  
Vol 9 (1) ◽  
pp. 1610-1624
Author(s):  
Xinxia Yang ◽  
Yi Peng ◽  
Jia Hou ◽  
Yifan Liu ◽  
Xian Jian

Abstract As the most common energy storage technology on the market, lithium-ion batteries are widely used in various industries and have a profound impact on our daily lives, with the characteristics of high voltage, high capacity, good safety performance, and long cycle life. Lithium metal was first used in the anode of lithium-ion batteries. However, the inherent growth of lithium dendrites and the instability of the SEI film limit the practical application of lithium metal materials. Despite this, lithium metal is still an ideal anode material to meet the growing demands for electronic equipment and electric vehicles due to its extremely high theoretical specific capacity, low density, and the lowest negative electrochemical potential. With the urgent need to develop new energy storage technologies, the research on lithium metal anodes has once again received extensive attention. In this review, the research progress in the modification of composite lithium metal electrode materials is summarized, including lithium/alloy composite electrode, lithium/carbon-based materials composite electrode and artificial SEI film. The possible directions for future development of lithium metal electrode are also prospected.


2016 ◽  
Vol 1 (6) ◽  
pp. 496-501 ◽  
Author(s):  
Dai-Huo Liu ◽  
Hong-Yan Lü ◽  
Xing-Long Wu ◽  
Jie Wang ◽  
Xin Yan ◽  
...  

In this communication, in order to develop superior electrode materials for advanced energy storage devices, a new strategy is proposed and then verified by the (Si@MnO)@C/RGO anode material for lithium ion batteries.


2006 ◽  
Vol 972 ◽  
Author(s):  
Haiming Xie ◽  
Haiying Yu ◽  
Abraham F. Jalbout ◽  
Guiling Yang ◽  
Xiumei Pan ◽  
...  

AbstractWe design a way that the anode hosts provide lithium ion in lithium ion battery operation. If the limiting factors of the cathode materials are less, there will be more alternatives for it. It was proven to be successful by two kinds of test cells based on LixCn as anode material, and β-FeOOH or Cr8O21 as cathode materials. Their theoretical capacities are much higher than those present electrode materials. Unlike the lithium secondary batteries with lithium metal foil or lithium alloy as anode, this type of lithium ion batteries with LixCn as anode prohibit dendrite formation during charging-discharge process. The idea of lithium ion sources coming from the anode can come true successfully as a result that steady protecting solution be sought for LixCn.


2015 ◽  
Vol 3 (7) ◽  
pp. 3659-3666 ◽  
Author(s):  
Gang Wang ◽  
Jun Peng ◽  
Lili Zhang ◽  
Jun Zhang ◽  
Bin Dai ◽  
...  

Nanostructured electrode materials have been extensively studied with the aim of enhancing lithium ion and electron transport and lowering the stress caused by their volume changes during the charge–discharge processes of electrodes in lithium-ion batteries.


NANO ◽  
2019 ◽  
Vol 14 (02) ◽  
pp. 1930001 ◽  
Author(s):  
Xiaobei Zang ◽  
Teng Wang ◽  
Zhiyuan Han ◽  
Lingtong Li ◽  
Xin Wu

The upcoming energy crisis and the increasing power requirements of electronic devices have drawn enormous attention to research in the field of energy storage. Owing to compelling electrochemical and mechanical properties, two-dimensional nanomaterials can be used as electrodes on lithium-ion batteries to obtain high capacity and long cycle life. This review summarized the recent advances in the application of 2D nanomaterials on the electrode materials of lithium-ion batteries.


2018 ◽  
Vol 6 (25) ◽  
pp. 12029-12037 ◽  
Author(s):  
Wei Zhang ◽  
Jiuren Yin ◽  
Ping Zhang ◽  
Xianqiong Tang ◽  
Yanhuai Ding

Monolayer two-dimensional phosphorus carbide (γ-PC) has been intensively studied as a promising anode material for lithium-ion batteries with first-principles calculations.


2015 ◽  
Vol 1095 ◽  
pp. 333-340
Author(s):  
Chuan Ning Yang ◽  
Yong Quan Qing ◽  
Chang Sheng Liu

Graphene paper (GP) with layered structure and highly conductive network is fabricated by a facile technique of vacuum filtration and studied as a single-component and binder-free anode of lithium ion batteries (LIBs). The process of fabrication of GP without any binder and high-temperature treatment, in the meantime, great improvement in both the capacity and cycling performance of the GP electrodes have compared with other kinds of traditional graphite electrode materials. Given the simplifying anode fabrication, low manufacturing costs and many electrochemical properties of the GP anode, it is regarded as an excellent anode material of LIB with great promise for its both excellent cycling performance and electrochemical properties. The specific capacity can reach to over 200 mAhg-1after 60 charge-discharge cycles under the current rate of 50 mAg-1.


2017 ◽  
Vol 41 (22) ◽  
pp. 13553-13559 ◽  
Author(s):  
Jiakang Min ◽  
Krzysztof Kierzek ◽  
Xuecheng Chen ◽  
Paul K. Chu ◽  
Xi Zhao ◽  
...  

A facile and efficient method is used to synthesize porous iron oxide coated with graphene as electrode materials for lithium-ion batteries and supercapacitors.


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