Theoretical studies of fine-structure effects and long-range forces: approximating the reactive surface of O(3P)+OH(2Π)

1990 ◽  
Vol 174 (3-4) ◽  
pp. 287-293 ◽  
Author(s):  
M.M. Graff ◽  
A.F. Wagner
1990 ◽  
Vol 43 (5) ◽  
pp. 519 ◽  
Author(s):  
C Hitchen ◽  
S Thurgate ◽  
P Jennings

LEED fine structure features are due to an interference between the measured beam (usually the specular) and a pre-emergent beam. This pre-emergent beam is internally reflected at the surface potential barrier and is subsequently diffracted by the substrate into the same direction as the beam under observation. As a result of the long-range image nature of the barrier potential, a rydberg-like series of peaks, converging on the emergence energy of the pre-emergent beam, is produced. Fine structure features, or threshold effects, occur at very low incident beam energies (typically <40 eV) and are extremely sensitive to the surface order of the crystal. The changes that occur to the fine structure features when atoms are adsorbed onto the surface contain information regarding the nature of the chemisorption process. In some cases it is possible to infer adsorption sites. In this work measurements are made of the fine structure features for the (001) and (111) surfaces of copper as a function of oxygen exposure. Analysis of these data shows that oxygen adsorption on (u(111) takes place in a disordered manner and results in a roughening of the surface, while for (u(OOl) the adsorption produces an ordered overlayer with oxygen atoms in the 2-fold bridge sites.


2002 ◽  
Vol 239 (1-3) ◽  
pp. 57-59 ◽  
Author(s):  
Yuan-Jen Lee ◽  
Ching-Ray Chang ◽  
Tzay-Ming Hong ◽  
C.H. Ho ◽  
Minn-Tsong Lin

1985 ◽  
Vol 50 (2) ◽  
pp. 375-379 ◽  
Author(s):  
Thomas J. Grilliot

One long-range objective of logic is to find models of arithmetic with noteworthy properties, perhaps properties that imply some long-standing number theoretic conjectures. In areas of mathematics such as algebra or set theory, new models are often made by extending old models, that is, by adjoining new elements to already existing models. Usually the extension retains most of the characteristics of the old model with at least one exception that makes the new model interesting. However, such a scheme is difficult in the area of arithmetic. Many interesting properties of the fine structure of arithmetic are diophantine and hence unchangeable in extensions. For instance, one cannot change a prime number into a composite one by adjoining new elements.One could possibly get around this diophantine difficulty in one of two ways. One way is to change the usual language of addition and multiplication to an equivalent language that does not transmit so much information to extensions. For instance, multiplication is definable from the squaring function, as one sees from the identity 2xy = (x + y)2 − x2 − y2, and the squaring function in turn is definable either from the unary square predicate (as one sees from the fact that n = m2 if n and n + 2m + 1 are successive squares) or from the divisor relation (as one sees from the fact that n = m2 if n is the smallest number such that m divides n and m + 1 divides n + m). Either of these two alternatives to multiplication might make for interesting extensions.


Sign in / Sign up

Export Citation Format

Share Document