scholarly journals Effects of natural gas composition on ignition delay under diesel conditions

1994 ◽  
Vol 99 (2) ◽  
pp. 192-200 ◽  
Author(s):  
J.D. Naber ◽  
D.L. Siebers ◽  
S.S. Di Julio ◽  
C.K. Westbrook
2018 ◽  
Vol 20 (4) ◽  
pp. 405-423 ◽  
Author(s):  
Zhenkuo Wu ◽  
Christopher J Rutland ◽  
Zhiyu Han

Natural gas and diesel dual-fuel combustion is a promising technology for efficiently utilizing natural gas in a compression ignition engine. Natural gas composition varies depending on the geographical source, which affects engine performance. The methane number is an indicator of natural gas fuel quality to assess the variation in composition. In this study, the influences of methane number on natural gas/diesel dual-fuel combustion were numerically examined using computational fluid dynamic simulations. The differences between natural gases with the same methane number but different components were also compared. Two dual-fuel combustion strategies, diesel pilot ignition, and reactivity controlled compression ignition were evaluated. The results show that for both diesel pilot ignition and reactivity controlled compression ignition, the ignition delay increases and the combustion duration decreases as the methane number is increased. The retarded trend of ignition of reactivity controlled compression ignition is more significant than that of diesel pilot ignition, while the decreased trend in combustion duration is less significant. To understand this trend, a chemical kinetics study of ignition delay characteristic of natural gas and n-heptane mixture was conducted. The result reveals that introducing ethane, propane, or an ethane–propane mixture into pure methane shortens the ignition delay in the entire temperature range. However, for the methane and n-heptane mixture, adding ethane, or propane, or an ethane–propane mixture shortens the ignition delay in the high temperature range, while increases the ignition delay in the low temperature range. These observations in combination with the analysis of air–fuel mixture formation and combustion provide the evidence to interpret the different ignition and combustion behaviors between diesel pilot ignition and reactivity controlled compression ignition combustion. In addition, a temperature A-factor sensitivity study was carried out to explain the result of the chemical kinetics study. Furthermore, the responses of emissions to methane number were also investigated. The results show that for diesel pilot ignition, the hydrocarbon and carbon monoxide emissions decrease with the decreased methane number. However, for reactivity controlled compression ignition, the variations of hydrocarbon and carbon monoxide emissions with the methane number are not so obvious as for diesel pilot ignition combustion. For both diesel pilot ignition and reactivity controlled compression ignition combustion, the nitrogen oxides emissions show a strong dependence on combustion phasing rather than natural gas composition. Overall, to control diesel pilot ignition combustion, the methane number should be considered together with other parameters. However, attention should be paid to other control parameters for the reactivity controlled compression ignition combustion. The engine performance of reactivity controlled compression ignition is not sensitive to the variation of natural gas composition, so it can adapt to the natural gas from different sources.


2021 ◽  
Vol 143 (3) ◽  
Author(s):  
Serena Romano ◽  
Roberto Meloni ◽  
Giovanni Riccio ◽  
Pier Carlo Nassini ◽  
Antonio Andreini

Abstract This paper addresses the impact of natural gas composition on both the operability and emissions of lean premixed gas turbine combustion system. This is an issue of growing interest due to the challenge for gas turbine manufacturers in developing fuel-flexible combustors capable of operating with variable fuel gases while producing very low emissions at the same time. Natural gas contains primarily methane (CH4) but also notable quantities of higher order hydrocarbons such as ethane (C2H6) can also be present. A deep understanding of natural gas combustion is important to obtain the highest combustion efficiency with minimal environmental impact. For this purpose, Large Eddy Simulations of an annular combustor sector equipped with a partially premixed burner are carried out for two different natural gas compositions with and without including the effect of flame strain rate and heat loss resulting in a more adequate description of flame shape, thermal field, and extinction phenomena. Promising results, in terms of NOx, compared against available experimental data, are obtained including these effects on the flame brush modeling, enhancing the fuel-dependency under nonadiabatic condition.


2019 ◽  
Vol 42 (3) ◽  
pp. 690-698
Author(s):  
Steven Wang ◽  
Woo Jin Lee ◽  
Chao'en Li ◽  
Benny Kuan ◽  
Nick Burke ◽  
...  

2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Xiaoqin Si ◽  
Rui Lu ◽  
Zhitong Zhao ◽  
Xiaofeng Yang ◽  
Feng Wang ◽  
...  

AbstractNatural gas is one of the foremost basic energy sources on earth. Although biological process appears as promising valorization routes to transfer biomass to sustainable methane, the recalcitrance of lignocellulosic biomass is the major limitation for the production of mixing gas to meet the natural gas composition of pipeline transportation. Here we develop a catalytic-drive approach to directly transfer solid biomass to bio-natural gas which can be suitable for the current infrastructure. A catalyst with Ni2Al3 alloy phase enables nearly complete conversion of various agricultural and forestry residues, the total carbon yield of gas products reaches up to 93% after several hours at relative low-temperature (300 degrees Celsius). And the catalyst shows powerful processing capability for the production of natural gas during thirty cycles. A low-carbon footprint is estimated by a preliminary life cycle assessment, especially for the low hydrogen pressure and non-fossil hydrogen, and technical economic analysis predicts that this process is an economically competitive production process.


Author(s):  
Amrit Bikram Sahu ◽  
A. Abd El-Sabor Mohamed ◽  
Snehasish Panigrahy ◽  
Gilles Bourque ◽  
Henry Curran

Abstract New ignition delay time measurements of natural gas mixtures enriched with small amounts of n-hexane and n-heptane were performed in a rapid compression machine to interpret the sensitization effect of heavier hydrocarbons on auto-ignition at gas-turbine relevant conditions. The experimental data of natural gas mixtures containing alkanes from methane to n-heptane were carried out over a wide range of temperatures (840–1050 K), pressures (20–30 bar), and equivalence ratios (φ = 0.5 and 1.5). The experiments were complimented with numerical simulations using a detailed kinetic model developed to investigate the effect of n-hexane and n-heptane additions. Model predictions show that the addition of even small amounts (1–2%) of n-hexane and n-heptane can lead to increase in reactivity by ∼40–60 ms at compressed temperature (TC) = 700 K. The ignition delay time (IDT) of these mixtures decrease rapidly with an increase in concentration of up to 7.5% but becomes almost independent of the C6/C7 concentration beyond 10%. This sensitization effect of C6 and C7 is also found to be more pronounced in the temperature range 700–900 K compared to that at higher temperatures (> 900 K). The reason is attributed to the dependence of IDT primarily on H2O2(+M) ↔ 2ȮH(+M) at higher temperatures while the fuel dependent reactions such as H-atom abstraction, RȮ2 dissociation or Q.OOH + O2 reactions are less important compared to 700–900 K, where they are very important.


2019 ◽  
Vol 65 ◽  
pp. 25-31 ◽  
Author(s):  
K.M. Dąbrowski ◽  
Sz Kuczyński ◽  
J. Barbacki ◽  
T. Włodek ◽  
R. Smulski ◽  
...  

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