The relative Lewis acidities of silicon tetrachloride, germanium tetrachloride and tin tetrachloride towards acetonitrile, acrylonitrile, ethyl acetate, diethyl ther and tetrahydrofuran; vapour pressure-composition studies

1980 ◽  
Vol 42 (5) ◽  
pp. 665-673 ◽  
Author(s):  
Paul G. Huggett ◽  
Kenneth Manning ◽  
Kenneth Wade
Keyword(s):  
Ethyl Acetate ◽  
Vapour Pressure ◽  
Composition Studies ◽  
Silicon Tetrachloride ◽  
Germanium Tetrachloride ◽  
Tin Tetrachloride

ADDITION COMPOUNDS OF THE GROUP IV HALIDES: II. ETHYLAMINE AND THE TETRACHLORIDES OF SILICON, GERMANIUM, TIN, AND TITANIUM

1952 ◽  
Vol 30 (11) ◽  
pp. 842-843 ◽  
Author(s):  
W. R. Trost
Keyword(s):  
Transition State ◽  
Silicon Germanium ◽  
Substitution Reaction ◽  
Titanium Tetrachloride ◽  
Group Iv ◽  
Silicon Tetrachloride ◽  
Addition Compound ◽  
Germanium Tin ◽  
Tin Tetrachloride

Aminates of tin tetrachloride and titanium tetrachloride are reported. On the bases of these compounds, and the recovery of a tetraminate, SiCl4•4EtNH2, from among the substitution products in the reaction of silicon tetrachloride with ethylamine at −78 °C., it is suggested that the transition state in the substitution reaction corresponds to an addition compound.

Study of adsorption on metals by the contact potential technique

1953 ◽  
Vol 6 (2) ◽  
pp. 109 ◽  
Author(s):  
JR Anderson ◽  
AE Alexander
Keyword(s):  
Ethyl Acetate ◽  
Hysteresis Loop ◽  
Work Function ◽  
Vapour Pressure ◽  
Physical Adsorption ◽  
Surface Preparation ◽  
Gold Surface ◽  
Contact Potential ◽  
Relative Vapour Pressure ◽  
Adsorption Of Water

The change in contact potential between metals due to physical adsorption of water vapour, isopropanol, and ethyl acetate has been studied. The plot of contact potential against relative vapour pressure showed a hysteresis loop, the behaviour varying for different methods of surface preparation. An initial irreversible potential change was always found, due to chemisorption. By studying the dependence of the contact potential on the temperature of one of the metal surfaces it has been possible to determine the change in work function of a gold surface due to physical adsorption.

scholarly journals CCLIV.—The vapour pressure of ethyl acetate from 0° to 100°

1912 ◽  
Vol 101 (0) ◽  
pp. 2438-2443 ◽  
Author(s):  
John Wade ◽  
Richard William Merriman
Keyword(s):  
Ethyl Acetate ◽  
Vapour Pressure
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