Structure analysis of high reactive metal catalysts intermediates by a combination of mass spectrometry and photodetachment-ZEKE-photoelectron spectroscopy

1995 ◽  
Vol 348 ◽  
pp. 337-340 ◽  
Author(s):  
G. Drechsler ◽  
C. Bäßmann ◽  
U. Boesl ◽  
E.W. Schlag
Langmuir ◽  
2012 ◽  
Vol 28 (47) ◽  
pp. 16306-16317 ◽  
Author(s):  
Yolanda S. Hedberg ◽  
Manuela S. Killian ◽  
Eva Blomberg ◽  
Sannakaisa Virtanen ◽  
Patrik Schmuki ◽  
...  

1996 ◽  
Vol 11 (1) ◽  
pp. 229-235 ◽  
Author(s):  
E. Cattaruzza ◽  
R. Bertoncello ◽  
F. Trivillin ◽  
P. Mazzoldi ◽  
G. Battaglin ◽  
...  

Silica glass was implanted with chromium at the energy of 35 and 160 keV and at fluences varying from 1 × 1016 to 11 × 1016 ions cm−2. In a set of chromium-implanted samples significant amounts of carbon were detected. Samples were characterized by x-ray photoelectron spectroscopy, x-ray-excited Auger electron spectroscopy, secondary ion mass spectrometry, and Rutherford backscattering spectrometry. Chromium silicide and chromium oxide compounds were observed; the presence of carbon in the implanted layers induces the further formation of chromium carbide species. Thermodynamic considerations applied to the investigated systems supply indications in agreement with the experimental evidences.


1994 ◽  
Vol 49 (12) ◽  
pp. 1256-1258 ◽  
Author(s):  
G. Drechsler ◽  
C. Bäßmann ◽  
U. Boesl ◽  
E. W. Schlag

Abstract Zero-kinetic-energy (ZEKE) photoelectron spectra of metalcarbide anions are presented, allowing a high resolu­tion spectroscopic access to intermediates in catalytic reac­tions of hydrocarbons on metal surfaces. As a first compound, FeC2 (an intermediate of the iron/acetylene system) has been chosen. Important for successful ZEKE spectroscopy was a special anion source and the selection by time-of-flight mass spectrometry. In addition, conventional laser induced photo­ detachment photoelectron spectroscopy in combination with our anion source and mass analyzer delivered valuable new information.


2008 ◽  
Vol 57 (4) ◽  
pp. 265-271 ◽  
Author(s):  
Shigehiro Asai ◽  
Kenichi Fujita ◽  
Masayuki Kubota ◽  
Michiko Kanai ◽  
Hideya Kawasaki ◽  
...  

Biochemistry ◽  
2001 ◽  
Vol 40 (32) ◽  
pp. 9725-9733 ◽  
Author(s):  
Pierre Chaurand ◽  
Beverly B. DaGue ◽  
Shuguang Ma ◽  
Susan Kasper ◽  
Richard M. Caprioli

Sign in / Sign up

Export Citation Format

Share Document