475. Sorption kinetics of oxygen-containing gases at low pressures

Vacuum ◽  
1972 ◽  
Vol 22 (4) ◽  
pp. 162
Keyword(s):  
Sorption Kinetics ◽  
Low Pressures ◽  
Kinetics Of

Sorption kinetics of oxygen at very low pressures by zirconium

Vacuum ◽  
1973 ◽  
Vol 23 (2) ◽  
pp. 51-54 ◽  
Author(s):  
M Nagasaka ◽  
E Uyeda ◽  
T Yamashina
Keyword(s):  
Sorption Kinetics ◽  
Low Pressures ◽  
Kinetics Of

Modeling of sorption kinetics of U(VI) micro-quantities nanostructured materials with anatase mesoporous structures

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Veniamin Zheleznov ◽  
Aleksey Golikov ◽  
Tatiana Sokolnitskaya ◽  
Sergey Ivannikov
Keyword(s):  
Nanostructured Materials ◽  
Sorption Kinetics ◽  
Uranyl Ion ◽  
Competitive Sorption ◽  
Hydroxyl Groups ◽  
Complex Ions ◽  
The Stability ◽  
Kinetics Of ◽  
Mesoporous Structures ◽  
Ionic Forms

Abstract The sorption kinetics of uranyl ions micro-quantities from fluoride solutions by nanostructured materials with anatase mesoporous structures has been studied. Using the model of competitive sorption of ions and positively charged complexes of uranyl ion on deprotonated hydroxyl groups of an anatase, kinetic curves of changes in the ratio of ionic forms of uranium in solution were calculated. Modeling was carried out under the assumption of a two-stage mechanism of uranium complex ions sorption. The modeling considered the influence of the uranyl ion carbonate complexes formation. The shift in equilibrium among ionic forms of uranyl correlates with the stability of the complexes in solution.

Kinetics of the decomposition of ammonia on platinum at low pressures

1967 ◽  
Vol 63 ◽  
pp. 476 ◽  
Author(s):  
A. J. B. Robertson ◽  
E. M. A. Willhoft
Keyword(s):  
Low Pressures ◽  
Kinetics Of

Sorption Kinetics of High Pressure Gases in Polymeric Tubing Materials

2006 ◽  
Author(s):  
P. Jaeger ◽  
S. Buchner ◽  
R. Eggers
Keyword(s):  
Diffusion Coefficients ◽  
Gas Permeability ◽  
Gravimetric Method ◽  
Sorption Kinetics ◽  
Operating Pressure ◽  
Gas Solubility ◽  
Atmospheric Conditions ◽  
High Solubility ◽  
Industrial Practice ◽  
Kinetics Of

A gravimetric method was applied to determine the sorption kinetics of gases into polymers. Diffusivity as well as sorption capacity are determined directly. Data of gas permeability that are required for calculating leakage rates in polymeric flexile gas and oil ducts may be retrieved by multiplying the obtained diffusion coefficients and the gas solubility. In general carbon dioxide enters polymers to the highest extent. In industrial practice, the high solubility of CO2 e.g. may lead to explosive decompression of sealings once the operating pressure is reduced to atmospheric conditions. Diffusion coefficients are presented in the range of 75 to 130°C at 2 to 30 MPa.

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