Influence of heat-treatment on the selective adsorption of CO2 in a model natural gas over molecular sieve carbons

1996 ◽  
Vol 37 (3) ◽  
pp. 180
Author(s):  
I. Mochida
Carbon ◽  
1995 ◽  
Vol 33 (11) ◽  
pp. 1611-1619 ◽  
Author(s):  
Isao Mochida ◽  
Shunsuke Yatsunami ◽  
Yuji Kawabuchi ◽  
Yusuke Nakayama

2018 ◽  
Vol 43 ◽  
pp. 01001 ◽  
Author(s):  
Siew-Pei Lee ◽  
N. Mellon ◽  
Azmi M. Shariff ◽  
Jean-Marc Leveque

Development of covalent organic polymer (COP) is a potential new class of adsorbent for CO2 separation from natural gas mainly due to their good hydrothermal stability, chemical tuning flexibility and low cost. CO2 and methane adsorption on COP-1 was studied under atmospheric condition (101.3 kPa, 298 K). COP-1 was synthesized via catalyst-free polycondensation of cyanuric chloride and piperazine. The properties of COP-1 were characterized using several analytical methods such as Fourier Transform Infra-Red (FTIR), N2 adsorption and desorption measurement and Field Transmission Electron Microscopy in coupled of Energy Dispersive X-ray Spectroscopy (FESEM-EDS). Reversible CO2 adsorption isotherm on COP-1 reflects low heat of adsorption which is beneficial to energy minimization in adsorbent regeneration process. Furthermore, moderate specific surface area COP-1 (88.5 m2/g) shows about nine times CO2 uptake higher than methane. The highly selective adsorption performance provides a promising insight in application of COP adsorbent for CO2 removal in natural gas field.


2016 ◽  
Vol 138 (9) ◽  
pp. 3022-3030 ◽  
Author(s):  
Maw Lin Foo ◽  
Ryotaro Matsuda ◽  
Yuh Hijikata ◽  
Rajamani Krishna ◽  
Hiroshi Sato ◽  
...  

2021 ◽  
Author(s):  
Anand Kumar Singh ◽  
Aysha Alobeidli ◽  
Venugopal Bakthavachsalam

Abstract Natural gas coming from the well contains hydrocarbons, CO2, H2S, and water together with many other impurities. Molecular sieve treatment of the gas is required to make it suitable for the various applications. The several process and parameters considerations contribute to the reliable and optimized operation of molecular sieve natural gas treaters. The journey of this molecular sieve treater optimization commenced by conducting a thorough systematic study of all existing treater performance by considering various operating critical parameter. The technical feasibility studies were completed covering all the aspects like evaluating current performance of treater, conducting simulation for future capacity, licensor endorsement, conducting breakthrough test. Finally, study outcomes were implemented through management change process. The main benefits of optimization of molecular sieve treater process are to extend the service life of molecular sieve which enable us to increase the turnaround cycle of NGL trains. Significant reduction in CAPEX and OPEX cost were realized by reducing new fresh molecular sieve procurement, reducing disposal of molecular sieve waste material and expense of shutdown, achieving 100% HSE. This paper presents the typical operation issues and challenges in molecular sieve treatment process, best practices adopted for maximizing of existing assets considering the current and design scenarios, and performance improvement, which result to extend molecular sieve life, increase of NGL shutdown cycle and flaring reduction in trains.


2019 ◽  
Vol 2 (1) ◽  
pp. 51-58
Author(s):  
Said Al Rabadi

This study describes and evaluates the performance of producing a pure Helium fraction from Helium extraction facility designed for cryogenic natural gas plants. A generic concept for obtaining a Helium pure fraction, which has relatively lower capital and operating costs should be provided. In order to achieve this objective, a new concept for obtaining a Helium pure fraction from a crude Helium fraction, is proposed based on simulations run under diverse process conditions regarding crude Helium gas’ temperature, pressure and composition. This concept is characterized by; reducing the plant safety requirements due to the extensive separation of combustible components, and compact layout of Helium extraction plant. Further re-purification is included in the subsequent Helium liquefaction step through selective adsorption, hence then increasing the purity of the Helium product and reducing the plant energy consumption required for liquefying Helium-rich fraction and the valuable Helium boil-off routed from the storage facility. The Nitrogen-rich fraction is routed to Nitrogen liquefaction installation. Liquid Nitrogen is generated within Helium recovery facility for liquid Helium shielding and container cooling. Surplus gaseous Nitrogen either can be liquefied and used within cryogenic natural gas plant as process coolant or be vented to atmosphere.


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