Acute toxicity of combinations of sodium dichromate, sodium arsenate and copper sulphate in the rat

Author(s):  
R.W. Mason ◽  
I.R. Edwards
1935 ◽  
Vol 13c (2) ◽  
pp. 101-114 ◽  
Author(s):  
J. D. Newton ◽  
A. D. Paul

Further experiments at Edmonton to determine the effects on soils and on subsequent crop growth of copper sulphate, sodium chlorate, and sodium dichromate, are reported, together with new experiments with ammonium thiocyanate. The field plot experiments were limited to Edmonton black soil, but three typical Alberta soils, including Edmonton soil, were used in the laboratory experiments. Copper sulphate applied to a series of fallow plots in 1931 did not affect the yields of wheat on these plots significantly in 1932, or the yields of wheat, oats, rye and flax on these plots in 1933. The soil was not appreciably injured, even temporarily, by the copper sulphate. Sodium chlorate was applied to one series of fallow plots in 1930, and to another series in 1931. The effect of the heaviest applications (1300 lb. per acre) lasted for three years in one series, but serious injury to crops from such heavy applications did not last for more than two years in either series. Sodium dichromate was applied to a series of fallow plots and a series of wheat plots in 1932. It reduced the wheat yields very much in 1932, but did not reduce crop yields the following year in either series, as it decomposed and lost its toxicity in the soil rather quickly. Ammonium thiocyanate was applied to a series of fallow plots and a series of wheat plots in 1932, and it reduced the wheat yields even more than sodium dichromate in 1932. It retarded nitrification and did not decompose and lose its toxicity completely during the season of application, but even in the cases of the heavier applications (650 and 1300 lb. per acre) the toxic effect disappeared early in the following season. The total and straw yields of crops sown on these plots were generally increased by the lighter applications (160 and 325 lb. per acre) in 1933, but the grain yields were generally reduced by the heavier applications (650 and 1300 lb. per acre). Growth of certain annual weeds was considerably stimulated by this nitrogenous weed killer in 1933 and 1934, in the plots to which the heavier applications had been made. Laboratory experiments showed that the thiocyanate may be leached out of a soil with water; that it decomposes fairly rapidly in soils under favorable conditions of moisture and temperature and more rapidly in fertile soil rich in organic matter than in poorer soil; and that nitrification in soils is depressed for a time by the ammonium thiocyanate.


2012 ◽  
Vol 7 (1) ◽  
pp. 6-9
Author(s):  
Hamed Nekoubin ◽  
Esmail Gharedaash ◽  
Mohammad Reza Imanpour ◽  
Alireza Asgharimog ◽  
Mohammad Larijani

1933 ◽  
Vol 8 (1) ◽  
pp. 73-100 ◽  
Author(s):  
W. E. Bowser ◽  
J. D. Newton

Experiments were conducted to determine the residual effect of sulphuric acid, copper sulphate, sodium chlorate, barium chlorate and sodium dichromate on three typical Alberta soils. No problem of residual effect was found with the two leaf sprays, sulphuric acid and copper sulphate. Sodium chlorate will remain toxic over a period of about two years, depending mainly on the organic matter content of the soil and the amount of leaching that takes place. The distance that the chlorate will leach down into the subsoil will depend on the amount of rainfall and the character of the soil. As soon as the chlorate is leached out or is reduced the soil returns to its normal productive power. Sodium dichromate decomposes very rapidly in the soil. It has a depressing effect on nitrification and on the activity of the soil micro-organisms. However, there is practically no residual effect from the use of sodium dichromate on soils of medium to high organic matter content.


Author(s):  
R. E. Herfert ◽  
N. T. McDevitt

Durability of adhesive bonded joints in moisture and salt spray environments is essential to USAF aircraft. Structural bonding technology for aerospace applications has depended for many years on the preparation of aluminum surfaces by a sulfuric acid/sodium dichromate (FPL etch) treatment. Recently, specific thin film anodizing techniques, phosphoric acid, and chromic acid anodizing have been developed which not only provide good initial bond strengths but vastly improved environmental durability. These thin anodic films are in contrast to the commonly used thick anodic films such as the sulfuric acid or "hard" sulfuric acid anodic films which are highly corrosion resistant in themselves, but which do not provide good initial bond strengths, particularly in low temperature peel.The objective of this study was to determine the characteristics of anodic films on aluminum alloys that make them corrosion resistant. The chemical composition, physical morphology and structure, and mechanical properties of the thin oxide films were to be defined and correlated with the environmental stability of these surfaces in humidity and salt spray. It is anticipated that anodic film characteristics and corrosion resistance will vary with the anodizing processing conditions.


Author(s):  
Elsie M. B. Sorensen

The detoxification capacity of the liver is well documented for a variety of substances including ethanol, organic pesticides, drugs, and metals. The piscean liver, although less enzymatically active than the mammalian counterpart (1), contains endoplasmic reticulum with an impressive repertoire of oxidizing, reducing, and conjugating abilities (2). Histopathologic changes are kncwn to occur in fish hepatocytes following in vivo exposure to arsenic (3); however, ultrastructural changes have not been reported. This study involved the morphometric analysis of intracellular changes in fish parynchymal hepatocytes and correlation with arsenic concentration in the liver.Green sunfish (Lepomis cyanellus, R.) were exposed to 0, 30, or 60 ppm arsenic (as sodium arsenate) at 20°C for 1, 2, or 3 week intervals before removal of livers for quantification of the arsenic burden (using neutron activation analysis) and morphometric analysis of ultrastructural alterations. Livers were cut into 1 mm cubes for fixation, dehydration, and embedding.


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