scholarly journals A grain size distribution model for non-catalytic gassolid reactions

Author(s):  
A.B.M. Heesink ◽  
W. Prins ◽  
W.P.M. van Swaaij
Geoderma ◽  
2021 ◽  
Vol 404 ◽  
pp. 115294
Author(s):  
Filip Stanić ◽  
Ioulia Tchiguirinskaia ◽  
Pierre-Antoine Versini ◽  
Yu-Jun Cui ◽  
Pierre Delage ◽  
...  

Author(s):  
Jilong Xu ◽  
Wendong Wang ◽  
Bing Ma ◽  
Yuliang Su ◽  
Han Wang ◽  
...  

AbstractShale is a complex porous medium composed of organic matter (OM) and inorganic minerals (iOM). Because of its widespread nanopores, using Darcy’s law is challenging. In this work, a two-fluid system model is established to calculate the oil flow rate in a single nanopore. Then, a spatial distribution model of shale components is constructed with a modified quartet structure generation set algorithm. The stochastic apparent permeability (AP) model of shale oil is finally established by combining the two models. The proposed model can consider the effects of various geological controls: the content and grain size distribution of shale components, pore size distribution, pore types and nanoconfined effects (slip length and spatially varying viscosity). The results show that slip length in OM nanopores is far greater than that in iOM. However, when the total organic content is less than 0.3 ~ 0.4, the effect of the OM slip on AP increases first and then decreases with the decrease in mean pore size, resulting in that the flow enhancement in shale is much smaller than that in a single nanopore. The porosity distribution and grain size distribution are also key factors affecting AP. If we ignore the difference of porosity between shale components, the error of permeability estimation is more than 200%. Similarly, the relative error can reach 20% if the effect of grain size distribution is ignored. Our model can help understand oil transport in shale strata and provide parameter characterization for numerical simulation.


1970 ◽  
Vol 2 (2) ◽  
pp. K69-K73 ◽  
Author(s):  
M. Reinbold ◽  
H. Hoffmann

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2849
Author(s):  
Marcin Jan Dośpiał

This paper presents domain and structure studies of bonded magnets made from nanocrystalline Nd-(Fe, Co)-B powder. The structure studies were investigated using scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), Mössbauer spectroscopy and X-ray diffractometry. On the basis of performed qualitative and quantitative phase composition studies, it was found that investigated alloy was mainly composed of Nd2(Fe-Co)14B hard magnetic phase (98 vol%) and a small amount of Nd1.1Fe4B4 paramagnetic phase (2 vol%). The best fit of grain size distribution was achieved for the lognormal function. The mean grain size determined from transmission electron microscopy (TEM) images on the basis of grain size distribution and diffraction pattern using the Bragg equation was about ≈130 nm. HRTEM images showed that over-stoichiometric Nd was mainly distributed on the grain boundaries as a thin amorphous border of 2 nm in width. The domain structure was investigated using a scanning electron microscope and metallographic light microscope, respectively, by Bitter and Kerr methods, and by magnetic force microscopy. Domain structure studies revealed that the observed domain structure had a labyrinth shape, which is typically observed in magnets, where strong exchange interactions between grains are present. The analysis of the domain structure in different states of magnetization revealed the dynamics of the reversal magnetization process.


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