Comparing the effects of microcrystalline cellulose and cellulose nanowhiskers extracted from oil palm empty fruit bunch on mechanical and thermal properties of polylactic acid composites

Author(s):  
M.K. Mohamad Haafiz ◽  
A. Hassan ◽  
H.P.S. Abdul Khalil ◽  
Md. Sohrab Hossain
2020 ◽  
Vol 32 (2) ◽  
pp. 158-167
Author(s):  
Nur Afifah Nordin ◽  
Nor Mas Mira Abd Rahman ◽  
Aziz Hassan

Oil palm empty fruit bunch (EFB) is one of the potential natural fibre that can be used as an alternative to synthetic fibre. EFB was heat-treated at 180°C using vacuum oven for 1 h, extrusion compounded with high-density polyethylene at 10%, 20% and 30% weight fraction. The composites were injection moulded into dumb-bell (ASTM D-638) and bar-shaped specimens (ASTM E-23). The composites were exposed to different environments which are soil burial and indoor environment for 3 months. The effects of conditioning on mechanical and thermal properties were studied relative to the dry as moulded samples as a standard. It was found that the mechanical and thermal properties of composites under soil burial conditions were reduced. Tensile modulus of 30% untreated fibre loading reduced from 1.56 GPa for dry to 1.03 GPa for soil burial conditions, respectively. The same reduction was also found in the flexural modulus. However, the value of treated fibre composites was found slightly higher compared to untreated fibre composites. The treated fibre composites showed more resistance towards the environment condition. Composites made from heat-treated EFB show improved thermal stability, expected due to better compatibility between fibres and matrices, thus lowering the moisture intake, despite the conditions of the samples. However, indoor exposure has no significant effect on the thermal and mechanical properties of composites.


Molecules ◽  
2012 ◽  
Vol 17 (2) ◽  
pp. 1969-1991 ◽  
Author(s):  
Samira Siyamak ◽  
Nor Azowa Ibrahim ◽  
Sanaz Abdolmohammadi ◽  
Wan Md Zin Bin Wan Yunus ◽  
Mohamad Zaki AB Rahman

BioResources ◽  
2017 ◽  
Vol 12 (3) ◽  
Author(s):  
Nasrullah Razali ◽  
Md. Sohrab Hossain ◽  
Owolabi Abdulwahab Taiwo ◽  
Mazlan Ibrahim ◽  
Nur Wahidah Mohd Nadzri ◽  
...  

2016 ◽  
Vol 85 ◽  
pp. 370-378 ◽  
Author(s):  
M.K. Mohamad Haafiz ◽  
Azman Hassan ◽  
H.P.S. Abdul Khalil ◽  
M.R. Nurul Fazita ◽  
Md. Saiful Islam ◽  
...  

2015 ◽  
Vol 30 (7) ◽  
pp. 986-1002 ◽  
Author(s):  
MR Islam ◽  
A Gupta ◽  
M Rivai ◽  
MDH Beg

Composites were prepared from recycled polypropylene (RPP), oil palm empty fruit bunch (EFB) and/or glass fibre (GF) using extrusion and injection moulding techniques. Two types of maleic anhydride-grafted polypropylene such as Polybond 3200 and Fusabond P 613 were used to improve the interfacial adhesion between fibres and matrix. The EFB: GF ratio was fixed as 70:30 and fibre loading was considered as 40 wt%. Microwave was used to treat the EFB fibre, which was soaked in a fixed mass concentration (12.5%) of alkali solution at different temperatures (70, 80 and 90°C) for a fixed period of time (60 min) and for different times (60, 90 and 120 min) at a fixed temperature (90°C). A magnetron controller was developed to control the time and temperature accurately for the treatment of fibre. Various characterization techniques such as density, melt flow index, tensile, Izod impact, flexural, field-emission scanning electron microscopy and water uptake testing were performed for the composites. Besides, thermogravimetric analysis and differential scanning calorimetry were also used to evaluate the thermal and crystalline properties of the composites, respectively. Result analyses revealed that microwave-treated fibre-based composites showed improved mechanical and thermal properties. EFB fibres treated at 90°C for 90 min were found to be suitable for better reinforcement into the composite in terms of mechanical, thermal and crystalline properties. Moreover, onset degradation temperature and water absorption properties were also found to be changed apparently due to treatment.


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