Metal-organic frameworks: preparation and application in electrocatalytic CO2 reduction reaction

2021 ◽  
pp. 331-347
Author(s):  
Rajasekaran Elakkiya ◽  
Govindhan Maduraiveeran
Keyword(s):  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Metal Organic ◽  
Co2 Reduction Reaction

scholarly journals Two-dimensional materials and metal-organic frameworks for the CO2 reduction reaction

2020 ◽  
Vol 5 ◽  
pp. 100038 ◽  
Author(s):  
Mahider Asmare Tekalgne ◽  
H.H. Do ◽  
A. Hasani ◽  
Q. Van Le ◽  
H.W. Jang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Two Dimensional ◽  
Two Dimensional Materials ◽  
Metal Organic ◽  
Co2 Reduction Reaction

Two‐dimensional Metal‐organic Frameworks for Electrochemical CO2 Reduction Reaction

ChemCatChem ◽  
2021 ◽  
Author(s):  
Tingting Zhan ◽  
Yingbing Zou ◽  
Ying Yang ◽  
Xiuling Ma ◽  
Zhangjing Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Two Dimensional ◽  
Electrochemical Co2 Reduction ◽  
Metal Organic ◽  
Co2 Reduction Reaction

Metal-organic frameworks derived carbon supported Cu-In bimetallic nanoparticles for highly selective CO2 electroreduction to CO

2021 ◽  
Author(s):  
Xia Ma ◽  
Jianjian Tian ◽  
Min Wang ◽  
Xixiong Jin ◽  
Meng Shen ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Bimetallic Catalysts ◽  
Bimetallic Nanoparticles ◽  
Metal Organic Frameworks ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Co2 Electroreduction ◽  
Metal Organic ◽  
Co2 Reduction Reaction

Cu-based materials are promising electrocatalysts for CO2 reduction reaction (CO2RR). However, they still suffer intense hydrogen evolution, low selectivity and efficiency for CO2RR. In this work, Cu-In bimetallic catalysts for...

Atomic regulation of metal-organic framework derived carbon-based single-atom catalysts for electrochemical CO2 reduction reaction

2021 ◽  
Author(s):  
Danni Zhou ◽  
Xinyuan Li ◽  
Huishan Shang ◽  
Fengjuan Qin ◽  
Wenxing Chen
Keyword(s):  
Active Sites ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Single Atom ◽  
Electrochemical Co2 Reduction ◽  
Metal Organic ◽  
Co2 Reduction Reaction ◽  
Organic Framework

Metal-organic framework (MOF) derived single-atom catalysts (SACs), featured unique active sites and adjustable topological structures, exhibit high electrocatalytic performance on carbon dioxide reduction reactions (CO2RR). By modulating elements and atomic...

Enhancing Selectivity through Decrypting the Uncoordinated Zirconium Sites in MOF Electrocatalysts

2021 ◽  
Author(s):  
Xiang-Da Zhang ◽  
Ling-Rui Huang ◽  
Jian-Xiang Wu ◽  
Zhi-Yuan Gu
Keyword(s):  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Metal Organic ◽  
Co2 Reduction Reaction ◽  
Organic Framework

Zirconium (Zr)-based porphyrinic metal-organic framework (PCN-223-M) were employed as the electrocatalysts to explore the effect of uncoordinated Zr sites on the performance of CO2 reduction reaction (CO2RR). PCN-223-AA with the...

scholarly journals Electrochemical Reduction of CO2: A Review of Cobalt Based Catalysts for Carbon Dioxide Conversion to Fuels

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2029
Author(s):  
Muhammad Usman ◽  
Muhammad Humayun ◽  
Mustapha D. Garba ◽  
Latif Ullah ◽  
Zonish Zeb ◽  
...  
Keyword(s):  
Co2 Reduction ◽  
Reduction Reaction ◽  
Single Atom ◽  
Future Perspectives ◽  
Electrochemical Co2 Reduction ◽  
Harmful Emissions ◽  
Metal Organic ◽  
High Overpotentials ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

Electrochemical CO2 reduction reaction (CO2RR) provides a promising approach to curbing harmful emissions contributing to global warming. However, several challenges hinder the commercialization of this technology, including high overpotentials, electrode instability, and low Faradic efficiencies of desirable products. Several materials have been developed to overcome these challenges. This mini-review discusses the recent performance of various cobalt (Co) electrocatalysts, including Co-single atom, Co-multi metals, Co-complexes, Co-based metal–organic frameworks (MOFs), Co-based covalent organic frameworks (COFs), Co-nitrides, and Co-oxides. These materials are reviewed with respect to their stability of facilitating CO2 conversion to valuable products, and a summary of the current literature is highlighted, along with future perspectives for the development of efficient CO2RR.

Graphene Supported Tungsten Carbide as Catalyst for Electrochemical Reduction of CO2

2019 ◽  
Author(s):  
Sahithi Ananthaneni ◽  
Rees Rankin
Keyword(s):  
Tungsten Carbide ◽  
Electrochemical Reduction ◽  
Low Cost ◽  
Co2 Reduction ◽  
Platinum Group Metal ◽  
Reduction Reaction ◽  
Metal Carbides ◽  
Depth Study ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction

<div>Electrochemical reduction of CO2 to useful chemical and fuels in an energy efficient way is currently an expensive and inefficient process. Recently, low-cost transition metal-carbides (TMCs) are proven to exhibit similar electronic structure similarities to Platinum-Group-Metal (PGM) catalysts and hence can be good substitutes for some important reduction reactions. In this work, we test graphenesupported WC (Tungsten Carbide) nanocluster as an electrocatalyst for the CO2 reduction reaction. Specifically, we perform DFT studies to understand various possible reaction mechanisms and determine the lowest thermodynamic energy landscape of CO2 reduction to various products such as CO, HCOOH, CH3OH, and CH4. This in-depth study of reaction energetics could lead to improvements and develop more efficient electrocatalysts for CO2 reduction.<br></div>

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