A pilot-scale experimental system of filling gasoline into a tank was built to investigate gasoline vapor-air mass transfer in the tank gas space and the vapor evaporation loss from the tank in different operating conditions. The results showed that the higher the location of filling pipe exit inside the tank, the quicker the speed of the filling gasoline, and the higher the initial vapor concentration in the tank gas space, then the more severe the vapor-air convective transport and the larger the gasoline evaporation loss rates.