Mass and Heat Transfer Limitations and Other Aspects of the Use of Large-Scale Catalytic Reactors

2019 ◽  
pp. 187-213
Author(s):  
Julian R.H. Ross
Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1599
Author(s):  
Riccardo Tesser ◽  
Elio Santacesaria

The tremendous progress in the computing power of modern computers has in the last 20 years favored the use of numerical methods for solving complex problems in the field of chemical kinetics and of reactor simulations considering also the effect of mass and heat transfer. Many classical textbooks dealing with the topic have, therefore, become quite obsolete. The present work is a review of the role that heat and mass transfer have in the kinetic studies of gas–solid catalytic reactions. The scope was to collect in a relatively short document the necessary knowledge for a correct simulation of gas–solid catalytic reactors. The first part of the review deals with the most reliable approach to the description of the heat and mass transfer outside and inside a single catalytic particle. Some different examples of calculations allow for an easier understanding of the described methods. The second part of the review is related to the heat and mass transfer in packed bed reactors, considering the macroscopic gradients that derive from the solution of mass and energy balances on the whole reactor. Moreover, in this second part, some examples of calculations, applied to chemical reactions of industrial interest, are reported for a better understanding of the systems studied.


2013 ◽  
Vol 216 ◽  
pp. 117-120
Author(s):  
Ronnie Andersson ◽  
Bengt Andersson

1992 ◽  
Vol 114 (4) ◽  
pp. 847-857 ◽  
Author(s):  
J. H. Wagner ◽  
B. V. Johnson ◽  
R. A. Graziani ◽  
F. C. Yeh

Experiments were conducted to determine the effects of buoyancy and Coriolis forces on heat transfer in turbine blade internal coolant passages. The experiments were conducted with a large-scale, multipass, heat transfer model with both radially inward and outward flow. Trip strips on the leading and trailing surfaces of the radial coolant passages were used to produce the rough walls. An analysis of the governing flow equations showed that four parameters influence the heat transfer in rotating passages: coolant-to-wall temperature ratio, Rossby number, Reynolds number, and radius-to-passage hydraulic diameter ratio. The first three of these four parameters were varied over ranges that are typical of advanced gas turbine engine operating conditions. Results were correlated and compared to previous results from stationary and rotating similar models with trip strips. The heat transfer coefficients on surfaces, where the heat transfer increased with rotation and buoyancy, varied by as much as a factor of four. Maximum values of the heat transfer coefficients with high rotation were only slightly above the highest levels obtained with the smooth wall model. The heat transfer coefficients on surfaces where the heat transfer decreased with rotation, varied by as much as a factor of three due to rotation and buoyancy. It was concluded that both Coriolis and buoyancy effects must be considered in turbine blade cooling designs with trip strips and that the effects of rotation were markedly different depending upon the flow direction.


Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 507
Author(s):  
Chrysovalantis C. Templis ◽  
Nikos G. Papayannakos

Mass and heat transfer coefficients (MTC and HTC) in automotive exhaust catalytic monolith channels are estimated and correlated for a wide range of gas velocities and prevailing conditions of small up to real size converters. The coefficient estimation is based on a two dimensional computational fluid dynamic (2-D CFD) model developed in Comsol Multiphysics, taking into account catalytic rates of a real catalytic converter. The effect of channel size and reaction rates on mass and heat transfer coefficients and the applicability of the proposed correlations at different conditions are discussed. The correlations proposed predict very satisfactorily the mass and heat transfer coefficients calculated from the 2-D CFD model along the channel length. The use of a one dimensional (1-D) simplified model that couples a plug flow reactor (PFR) with mass transport and heat transport effects using the mass and heat transfer correlations of this study is proved to be appropriate for the simulation of the monolith channel operation.


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