Particle deformation and microstructure evolution during cold spray of individual Al-Cu alloy powder particles

2019 ◽  
Vol 168 ◽  
pp. 13-23 ◽  
Author(s):  
Tian Liu ◽  
Jeremy D. Leazer ◽  
Luke N. Brewer
2021 ◽  
Author(s):  
Baihua Ren ◽  
Jun Song

Abstract Recently, cold spray (CS) technology has attracted extensive interest as an alternative to thermal spray methods to build a coating, which uses high kinetic energy solid particles to impact and adhere to the substrate. To date, numerous numerical studies have been carried out to investigate the deposition processes and associated mechanisms during multiple particle impact in CS. However, in the commonly used numerical techniques, the individual powder particles are often treated separately from one another, thus fail to properly consider the adhesion mechanisms during deposition. In this study, we propose a new numerical approach on base of peridynamics (PD), which incorporates interfacial interactions as a part of constitutive model to capture deformation, bonding and rebound of impacting particles in one unified framework. Two models are proposed to characterize the adhesive contacts: a) a long-range Lenard-Johns type potential that reproduce the mode I fracture energy by suitable calibrations, and b) a force - stretch relation of interface directly derived from the bulk materials mode I fracture simulations. The particle deformation behavior modeled by the peridynamic method compares well with the benchmark finite element method results, which indicates the applicability of the peridynamic model for CS simulation. Furthermore, it is shown that the adhesive contact models can accurately describe interfacial bonding between the powder particles and substrate.


Author(s):  
Naresh N. Thadhani ◽  
Thad Vreeland ◽  
Thomas J. Ahrens

A spherically-shaped, microcrystalline Ni-Ti alloy powder having fairly nonhomogeneous particle size distribution and chemical composition was consolidated with shock input energy of 316 kJ/kg. In the process of consolidation, shock energy is preferentially input at particle surfaces, resulting in melting of near-surface material and interparticle welding. The Ni-Ti powder particles were 2-60 μm in diameter (Fig. 1). About 30-40% of the powder particles were Ni-65wt% and balance were Ni-45wt%Ti (estimated by EMPA).Upon shock compaction, the two phase Ni-Ti powder particles were bonded together by the interparticle melt which rapidly solidified, usually to amorphous material. Fig. 2 is an optical micrograph (in plane of shock) of the consolidated Ni-Ti alloy powder, showing the particles with different etching contrast.


Author(s):  
Bahareh Marzbanrad ◽  
Mohammad Hadi Razmpoosh ◽  
Ehsan Toyserkani ◽  
Hamid Jahed

2007 ◽  
Vol 29-30 ◽  
pp. 143-146 ◽  
Author(s):  
Aamir Mukhtar ◽  
De Liang Zhang ◽  
C. Kong ◽  
P. R. Munroe

Cu-(2.5 or 5.0vol.%)Al2O3 nanocomposite balls and granules and Cu-(2.5vol.% or 5.0vol.%)Pb alloy powder were prepared by high energy mechanical milling (HEMM) of mixtures of Cu and either Al2O3 or Pb powders. It was observed that with the increase of the content of Al2O3 nanoparticles from 2.5vol.% to 5vol.% in the powder mixture, the product of HEMM changed from hollow balls into granules and the average grain size and microhardness changed from approximately 130nm and 185HV to 100nm and 224HV, respectively. On the other hand, HEMM of Cu–(2.5 or 5.0vol.%) Pb powder mixtures under the same milling conditions failed to consolidate the powder in-situ. Instead, it led to formation of nanostructured fine powders with an average grain size of less than 50nm. Energy dispersive X-ray mapping showed homogenous distribution of Pb in the powder particles in Cu–5vol.%Pb alloy powder produced after 12 hours of milling. With the increase of the Pb content from 2.5 to 5.0 vol.%, the average microhardness of the Cu-Pb alloy powder particles increases from 270 to 285 HV. The mechanisms of the effects are briefly discussed.


2019 ◽  
Vol 51 (2) ◽  
pp. 209-221 ◽  
Author(s):  
Milica Spasojevic ◽  
Dusan Markovic ◽  
Miroslav Spasojevic ◽  
Zoran Vukovic ◽  
Aleksa Maricic ◽  
...  

Ni-Fe-W-Cu alloy powders were obtained by electrodeposition from an ammonium citrate bath at current densities ranging between 70 and 600 mA cm-2. As the deposition current density increased, the contents of Fe and W in the alloy increased, and those of Ni and Cu decreased. The total cathodic polarization curve was recorded, and partial polarization curves for Ni, Fe and W deposition and hydrogen evolution were determined. The current efficiency of alloy deposition was measured. The powders contained an amorphous matrix and FCC nanocrystals of the solid solution of Fe, W and Cu in Ni. At high current densities, small-sized nanocrystals exhibiting high internal microstrain values were formed. Powder particles were dendrite- and cauliflower-shaped. The dendrites had a large number of secondary branches and higher-order branches containing interconnected globules. The density of branches was higher in particles formed at high current densities. The powders formed at high current densities exhibited higher magnetization. Annealing at temperatures up to 460?C resulted in structural relaxation, accompanied by an increase in magnetization. At temperatures above 460?C, amorphous matrix crystallization and FCC crystal growth took place, accompanied by a decrease in magnetization.


2019 ◽  
Vol 813 ◽  
pp. 110-115
Author(s):  
Olga Matts ◽  
Hussein Hammoud ◽  
Alexey Sova ◽  
Zineb Bensaid ◽  
Guillaume Kermouche ◽  
...  

In this work an influence of cold spray nozzle displacement parameters on the properties of copper-silicon carbide cold spray deposits is considered. In particular the influence of nozzle traverse speed and distance between deposited tracks on the coating porosity and behavior during compressive tests was analyzed. It was shown that cold spraying at low nozzle traverse speed leads to formation of thick tracks with quasi-triangular cross-section. As a consequence, the particle impact angle on the sides of spraying track increases that. Thus, the particle deformation at impact on the track periphery becomes insufficient and local porosity value rises. Increase of nozzle traverse speed allows increasing coating density and mechanical properties due to amelioration of particle deformation conditions. Compressive tests revealed significant anisotropy of mechanical properties of copper-silicon carbide cold spray deposits. In particular, compressive strength measured in vertical direction (perpendicular to the substrate) was significantly higher than one measured in horizontal plane (parallel to substrate). This anisotropy could be explained by the orientation of particle deformation pattern during impact.


1994 ◽  
Vol 38 ◽  
pp. 763-767
Author(s):  
J. D. Makinson ◽  
R. J. De Angelis ◽  
S. C. Axtell

Abstract The mechanical alloying process continually deforms, cold welds, and breaks apart metal powder particles. During the process of mechanical alloying elemental crystalline powders can produce an amorphous alloyed powder. Consolidation of these powders by powder metallurgy techniques can produce amorphous bulk metals. Two Alloys 62.24 Zr-10.89 Ti-9.71 Ni-13.14 Cu-4.02 B and 64.84 Zr-11.35 Ti-11.12 Nt-13.69 Cu weight percent were mechanically alloyed for 45 hours by a SPEX 800 high energy ball-mill. The changes in structure were monitored by X-ray diffraction after every 5 hours of milling. Both powder compositions became amorphous after 15 hours of milling. New compounds began to form during milling to 35 hours. Milling for longer times produced no further structure changes. The milled samples were annealed at 950°C for 1 hour which produced a complex set of crystalline materials. The crystalline phases containing boron have larger lattice parameters and less tendency for grain growth.


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